Polyester urea capable of forming an anisotropic melt phase

Claim 2

A melt processable wholly aromatic polyester urea capable of forming an anisotropic melt phase at a temperature below approximately 400° C. consisting essentially of the recurring moieties I, II, and III wherein: I is ##STR13## wherein the hydrogen atoms of the aromatic rings optionally may be replaced with substitution selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, phenyl, and mixtures of the foregoing, II is ##STR14## where Y is selected from the group consisting of hydrogen, an alkyl group of 1 to 4 carbon atoms, phenyl, and mixtures of the foregoing, and III is a dioxyaryl moiety of the formula --O--Ar--O--, where Ar is a divalent radical comprising at least one aromatic ring, and wherein the hydrogen atoms of the aromatic rings optionally may be replaced with substitution selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, phenyl, and mixtures of the foregoing, and wherein said polyester urea comprises approximately 5 to 90 mole percent of moiety I, approximately 5 to 47.5 mole percent of moiety II, and approximately 5 to 47.5 mole percent of moiety III.

Claim 3

A melt processable wholly aromatic polyester urea according to claim 1 which is capable of forming an anisotropic melt phase at a temperature below approximately 370° C.

Claim 4

A melt processable wholly aromatic polyester urea according to claim 1 which is capable of undergoing melt processing at a temperature in the range of approximately 300° to 390° C.

Claim 5

A melt processable wholly aromatic polyester urea according to claim 1 which exhibits an inherent viscosity of at least 0.5 when dissolved in a concentration of 0.1 percent by weight in pentafluorophenol at 60° C.

Claim 6

A melt processable wholly aromatic polyester urea according to claim 1 which exhibits an inherent viscosity of at least 1.0 when dissolved in a concentration of 0.1 percent by weight in pentafluorophenol at 60° C.

Claim 7

A melt processable wholly aromatic polyester urea according to claim 1 wherein the aromatic rings of moieties I and III are substantially free of ring substitution.

Claim 8

A melt processable wholly aromatic polyester urea according to claim 1 wherein moiety II is ##STR15##

Claim 9

A melt processable wholly aromatic polyester urea according to claim 1 wherein moiety III is symmetrically disposed.

Claim 10

A melt processable wholly aromatic polyester urea according to claim 1 wherein the dioxyaryl moiety III is ##STR16##

Claim 11

A melt processable wholly aromatic polyester urea according to claim 1 which additionally includes up to 50 mole percent of p-oxybenzoyl moiety.

Claim 12

A fiber which has been melt spun from the melt processable wholly aromatic polyester urea of claim 1.

Claim 13

A film which has been melt extruded from the melt processable wholly aromatic polyester urea of claim 1.

Claim 14

A molded article comprising the melt processable wholly aromatic polyester urea of claim 1.

Claim 15

A molding compound comprising the melt processable wholly aromatic polyester urea of claim 1 which incorporates approximately 1 to 60 percent by weight of a solid filler and/or reinforcing agent.

Claim 16

A melt processable wholly aromatic polyester urea capable of forming an anisotropic melt phase at a temperature below approximately 400° C. consisting essentially of the recurring moieties I, II, and III wherein: I is ##STR17## wherein the hydrogen atoms of the aromatic rings optionally may be replaced with substitution selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, phenyl, and mixtures of the foregoing, II is ##STR18## where Y is selected from the group consisting of hydrogen, an alkyl group of 1 to 4 carbon atoms, phenyl, and mixtures of the foregoing, and III is a symmetrical dioxyaryl moiety of the formula --O--Ar--O--, where Ar is a divalent radical comprising at least one aromatic ring, and wherein the hydrogen atoms of the aromatic rings optionally may be replaced with substitution selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, phenyl, and mixtures of the foregoing, and wherein said polyester urea comprises approximately 20 to 80 mole percent of moiety I, approximately 10 to 40 mole percent of moiety II, and approximately 10 to 40 mole percent of moiety III.

Claim 17

A melt processable wholly aromatic polyester urea capable of forming an anisotropic melt phase at a temperature below approximately 400° C. consisting essentially of the recurring moieties I, II, and III wherein: I is ##STR17## wherein the hydrogen atoms of the aromatic rings optionally may be replaced with substitution selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, phenyl, and mixtures of the foregoing, II is ##STR18## where Y is selected from the group consisting of hydrogen, an alkyl group of 1 to 4 carbon atoms, phenyl, and mixtures of the foregoing, and III is a symmetrical dioxyaryl moiety of the formula --O--Ar--O--, where Ar is a divalent radical comprising at least one aromatic ring, and wherein the hydrogen atoms of the aromatic rings optionally may be replaced with substitution selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, phenyl, and mixtures of the foregoing, and wherein said polyester urea comprises approximately 20 to 80 mole percent of moiety I, approximately 10 to 40 mole percent of moiety II, and approximately 10 to 40 mole percent of moiety III.

Claim 18

A melt processable wholly aromatic polyester urea according to claim 15 which is capable of forming an anisotropic melt phase at a temperature below approximately 370° C.

Claim 19

A melt processable wholly aromatic polyester urea according to claim 15 which is capable of undergoing melt processing at a temperature in the range of approximately 320° to 390° C.

Claim 20

A melt processable wholly aromatic polyester urea according to claim 15 which exhibits an inherent viscosity of at least 0.5 when dissolved in a concentration of 0.1 percent by weight in pentafluorophenol at 60° C.

Claim 21

A melt processable wholly aromatic polyester urea according to claim 15 which exhibits an inherent viscosity of at least 1.0 when dissolved in a concentration of 0.1 percent by weight in pentafluorophenol at 60° C.

Claim 22

A melt processable wholly aromatic polyester urea according to claim 15 wherein the aromatic rings of moieties I and III are substantially free of ring substitution.

Claim 23

A melt processable wholly aromatic polyester urea according to claim 15 wherein moiety II is ##STR19##

Claim 24

A melt processable wholly aromatic polyester urea according to claim 15 wherein the symmetrical dioxyaryl moiety III is selected from the group consisting of ##STR20## and mixtures of the foregoing.

Claim 25

A melt processable wholly aromatic polyester urea according to claim 15 wherein the symmetrical dioxyaryl moiety III is ##STR21##

Claim 26

A melt processable wholly aromatic polyester urea according to claim 15 wherein moiety I is present in a concentration of approximately 40 to 80 mole percent, moiety II is present in a concentration of approximately 10 to 30 mole percent, and moiety III is present in a concentration of approximately 10 to 30 mole percent.

Claim 27

A melt processable wholly aromatic polyester urea capable of forming an anisotropic melt phase at a temperature below approximately 350° C. consisting essentially of the recurring moieties I, II, and III which are free of aromatic ring substitution wherein: ##STR22## wherein said polyester urea comprises approximately 40 to 80 mole percent of moiety I, approximately 10 to 30 mole percent of moiety II, and approximately 10 to 30 mole percent of moiety III.

Claim 28

A melt processable wholly aromatic polyester urea capable of forming an anisotropic melt phase at a temperature below approximately 350° C. consisting essentially of the recurring moieties I, II, and III which are free of aromatic ring substitution wherein: ##STR22## wherein said polyester urea comprises approximately 40 to 80 mole percent of moiety I, approximately 10 to 30 mole percent of moiety II, and approximately 10 to 30 mole percent of moiety III.

Claim 29

A melt processable wholly aromatic polyester urea according to claim 25 wherein moiety I is present in a concentration of approximately 70 mole percent, moiety II is present in a concentration of approximately 15 mole percent, and moiety III is present in a concentration of approximately 15 mole percent.