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US4219461A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyester of 6-hydroxy-2-naphthoic acid, para-hydroxy benzoic acid, aromatic diol, and aromatic diacid capable of readily undergoing melt processing

Assignee: Celanese Corp
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Filing: 1979-04-23
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Granted: 1980-08-26
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Expires: 1999-04-23
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Abstract

Abstract A novel polyester is provided which has been found to exhibit an optically anisotropic melt phase at a temperature which enables it readily to undergo melt processing to form quality fibers, molded articles, etc. The polyester of the present invention contains substantial concentrations of recurring 6-oxy-2-naphthoyl and p-oxybenzoyl moieties in addition to moieties derived from at least one aromatic diol and at least one aromatic diacid in the proportions indicated. The hydrogen atoms present upon the aromatic rings of these moieties optionally may be at least partially substituted (as described). The wholly aromatic polyester is capable of forming the desired anisotropic melt at a temperature below approximately 320° C., and in a particularly preferred embodiment at a temperature below approximately 300° C.

Inventors

  • 👤 Gordon W. Calundann

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 09:50
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/02; C08G63/60; C08G63/605

Claims Analysis

Total Claims: 45
Claim 1
Independent Claim 185 words
A melt processable wholly aromatic polyester capable of forming an anisotropic melt phase at a temperature below approximately 320° C. consisting essentially of the recurring moieties I, II, III, and IV which may include substitution of at least some of the hydrogen atoms present upon an aromatic ring wherein: ##STR13## III is a symmetrical dioxy aryl moiety of the formula --O--Ar--O-- where Ar is a divalent radical comprising at least one aromatic ring, and IV is symmetrical a dicarboxy aryl moiety of the formula ##STR14## where Ar' is a divalent radical comprising at least one aromatic ring, with said optional substitution if present being selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, and mixtures of the foregoing, and wherein said polyester comprises approximately 20 to 40 mole percent of moiety I, approximately 10 up to 50 mole percent of moiety II, in excess of 5 up to approximately 30 mole percent of moiety III, and in excess of 5 up to approximately 30 mole percent of moiety IV.
Claim 2
Dependent Claim 185 words
A melt processable wholly aromatic polyester capable of forming an anisotropic melt phase at a temperature below approximately 320° C. consisting essentially of the recurring moieties I, II, III, and IV which may include substitution of at least some of the hydrogen atoms present upon an aromatic ring wherein: ##STR13## III is a symmetrical dioxy aryl moiety of the formula --O--Ar--O-- where Ar is a divalent radical comprising at least one aromatic ring, and IV is symmetrical a dicarboxy aryl moiety of the formula ##STR14## where Ar' is a divalent radical comprising at least one aromatic ring, with said optional substitution if present being selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, and mixtures of the foregoing, and wherein said polyester comprises approximately 20 to 40 mole percent of moiety I, approximately 10 up to 50 mole percent of moiety II, in excess of 5 up to approximately 30 mole percent of moiety III, and in excess of 5 up to approximately 30 mole percent of moiety IV.
Claim 3
Dependent Claim 26 words
A melt processable wholly aromatic polyester according to claim 1 which is capable of forming an anisotropic melt phase at a temperature below approximately 300° C.
Claim 4
Dependent Claim 29 words
A melt processable wholly aromatic polyester according to claim 1 which is capable of exhibiting a differential scanning calorimeter melting temperature in the range of 270° to 280° C.
Claim 5
Dependent Claim 29 words
A melt processable wholly aromatic polyester according to claim 1 which is capable of undergoing melt processing at a temperature in the range of approximately 280° to 300° C.
Claim 6
Dependent Claim 51 words
A melt processable wholly aromatic polyester according to claim 1 which consists essentially of approximately 20 to 30 mole percent of moiety I, approximately 25 to 40 mole percent of moiety II, approximately 15 to 25 mole percent of moiety III, and approximately 15 to 25 mole percent of moiety IV.
Claim 7
Dependent Claim 19 words
A melt processable wholly aromatic polyester according to claim 1 wherein each moiety is substantially free of ring substitution.
Claim 8
Dependent Claim 30 words
A melt processable wholly aromatic polyester according to claim 1 wherein said symmetrical dioxy aryl moiety III is selected from the group consisting of: ##STR15## and mixtures of the foregoing.
Claim 9
Dependent Claim 30 words
A melt processable wholly aromatic polyester according to claim 1 wherein said symmetrical dicarboxy aryl moiety IV is selected from the group consisting of: ##STR16## and mixtures of the foregoing.
Claim 10
Dependent Claim 34 words
A melt processable wholly aromatic polyester according to claim 1 which exhibits an inherent viscosity of at least 2.5 when dissolved in a concentration of 0.1 percent by weight in pentafluorophenol at 60° C.
Claim 11
Dependent Claim 34 words
A melt processable wholly aromatic polyester according to claim 1 which exhibits an inherent viscosity of at least 3.5 when dissolved in a concentration of 0.1 percent by weight in pentafluorophenol at 60° C.
Claim 12
Dependent Claim 34 words
A melt processable wholly aromatic polyester according to claim 1 which exhibits an inherent viscosity of 3.5 to 7.5 when dissolved in a concentration of 0.1 percent by weight in pentafluorophenol at 60° C.
Claim 13
Dependent Claim 15 words
A fiber which has been melt spun from the wholly aromatic polyester of claim 1.
Claim 14
Dependent Claim 15 words
A film which has been melt extruded from the wholly aromatic polyester of claim 1.
Claim 15
Dependent Claim 13 words
A molded article comprising the melt processable wholly aromatic polyester of claim 1.
Claim 16
Dependent Claim 29 words
A molding compound comprising the melt processable wholly aromatic polyester of claim 1 which incorporates approximately 1 to 60 percent by weight of a solid filler and/or reinforcing agent.
Claim 17
Dependent Claim 137 words
A melt processable wholly aromatic polyester capable of forming an anisotropic melt phase at a temperature below approximately 320° C. consisting essentially of the recurring moieties I, II, III, and IV which may include substitution of at least some of the hydrogen atoms present upon an aromatic ring wherein: ##STR17## with said optional substitution if present being selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, and mixtures of the foregoing, and wherein said polyester comprises approximately 20 to 40 mole percent of moiety I, approximately 10 to 50 mole percent of moiety II, in excess of 5 up to approximately 30 mole percent of moiety III, and in excess of 5 up to approximately 30 mole percent of moiety IV.
Claim 18
Dependent Claim 137 words
A melt processable wholly aromatic polyester capable of forming an anisotropic melt phase at a temperature below approximately 320° C. consisting essentially of the recurring moieties I, II, III, and IV which may include substitution of at least some of the hydrogen atoms present upon an aromatic ring wherein: ##STR17## with said optional substitution if present being selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, and mixtures of the foregoing, and wherein said polyester comprises approximately 20 to 40 mole percent of moiety I, approximately 10 to 50 mole percent of moiety II, in excess of 5 up to approximately 30 mole percent of moiety III, and in excess of 5 up to approximately 30 mole percent of moiety IV.
Claim 19
Dependent Claim 26 words
A melt processable wholly aromatic polyester according to claim 16 which is capable of forming an anisotropic melt phase at a temperature below approximately 300° C.
Claim 20
Dependent Claim 29 words
A melt processable wholly aromatic polyester according to claim 16 which is capable of exhibiting a differential scanning calorimeter melting temperature in the range of 270° to 280° C.
Claim 21
Dependent Claim 29 words
A melt processable wholly aromatic polyester according to claim 16 which is capable of undergoing melt processing at a temperature in the range of approximately 280° to 300° C.
Claim 22
Dependent Claim 51 words
A melt processable wholly aromatic polyester according to claim 16 which consists essentially of approximately 20 to 30 mole percent of moiety I, approximately 25 to 40 mole percent of moiety II, approximately 15 to 25 mole percent of moiety III, and approximately 15 to 25 mole percent of moiety IV.
Claim 23
Dependent Claim 19 words
A melt processable wholly aromatic polyester according to claim 16 wherein each moiety is substantially free of ring substitution.
Claim 24
Dependent Claim 34 words
A melt processable wholly aromatic polyester according to claim 16 which exhibits an inherent viscosity of at least 2.5 when dissolved in a concentration of 0.1 percent by weight of pentafluorophenol at 60° C.
Claim 25
Dependent Claim 34 words
A melt processable wholly aromatic polyester according to claim 16 which exhibits an inherent viscosity of at least 3.5 when dissolved in a concentration of 0.1 percent by weight in pentafluorophenol at 60° C.
Claim 26
Dependent Claim 34 words
A melt processable wholly aromatic polyester according to claim 16 which exhibits an inherent viscosity of 3.5 to 7.5 when dissolved in a concentration of 0.1 percent by weight in pentafluorophenol at 60° C.
Claim 27
Dependent Claim 15 words
A fiber which has been melt spun from the wholly aromatic polyester of claim 16.
Claim 28
Dependent Claim 15 words
A film which has been melt extruded from the wholly aromatic polyester of claim 16.
Claim 29
Dependent Claim 13 words
A molded article comprising the melt processable wholly aromatic polyester of claim 16.
Claim 30
Dependent Claim 29 words
A molding compound comprising the melt processable wholly aromatic polyester of claim 16 which incorporates approximately 1 to 60 percent by weight of a solid filler and/or reinforcing agent.
Claim 31
Dependent Claim 83 words
A melt processable wholly aromatic polyester capable of forming an anisotropic melt phase at a temperature below approximately 320° C. consisting essentially of the recurring moieties I, II, III, and IV wherein: ##STR18## and wherein said polyester comprises approximately 20 to 40 mole percent of moiety I, approximately 10 to 50 mole percent of moiety II, in excess of 5 up to approximately 30 mole percent of moiety III, and in excess of 5 up to approximately 30 mole percent of moiety IV.
Claim 32
Dependent Claim 83 words
A melt processable wholly aromatic polyester capable of forming an anisotropic melt phase at a temperature below approximately 320° C. consisting essentially of the recurring moieties I, II, III, and IV wherein: ##STR18## and wherein said polyester comprises approximately 20 to 40 mole percent of moiety I, approximately 10 to 50 mole percent of moiety II, in excess of 5 up to approximately 30 mole percent of moiety III, and in excess of 5 up to approximately 30 mole percent of moiety IV.
Claim 33
Dependent Claim 26 words
A melt processable wholly aromatic polyester according to claim 29 which is capable of forming an anisotropic melt phase at a temperature below approximately 300° C.
Claim 34
Dependent Claim 29 words
A melt processable wholly aromatic polyester according to claim 29 which is capable of exhibiting a differential scanning calorimeter melting temperature in the range of 270° to 280° C.
Claim 35
Dependent Claim 29 words
A melt processable wholly aromatic polyester according to claim 29 which is capable of undergoing melt processing at a temperature in the range of approximately 280° to 300° C.
Claim 36
Dependent Claim 51 words
A melt processable wholly aromatic polyester according to claim 29 which consists essentially of approximately 20 to 30 mole percent of moiety I, approximately 25 to 40 mole percent of moiety II, approximately 15 to 25 mole percent of moiety III, and approximately 15 to 25 mole percent of moiety IV.
Claim 37
Dependent Claim 43 words
A melt processable wholly aromatic polyester according to claim 29 which consists essentially of approximately 25 mole percent of moiety I, approximately 35 mole percent of moiety II, approximately 20 mole percent of moiety III, and approximately 20 mole percent of moiety IV.
Claim 38
Dependent Claim 19 words
A melt processable wholly aromatic polyester according to claim 29 wherein each moiety is substantially free of ring substitution.
Claim 39
Dependent Claim 34 words
A melt processable wholly aromatic polyester according to claim 29 which exhibits an inherent viscosity of at least 2.5 when dissolved in a concentration of 0.1 percent by weight in pentafluorophenol at 60° C.
Claim 40
Dependent Claim 34 words
A melt processable wholly aromatic polyester according to claim 29 which exhibits an inherent viscosity of at least 3.5 when dissolved in a concentration of 0.1 percent by weight in pentafluorophenol at 60° C.
Claim 41
Dependent Claim 34 words
A melt processable wholly aromatic polyester according to claim 29 which exhibits an inherent viscosity of 3.5 to 7.5 when dissolved in a concentration of 0.1 percent by weight in pentafluorophenol at 60° C.
Claim 42
Dependent Claim 15 words
A fiber which has been melt spun from the wholly aromatic polyester of claim 29.
Claim 43
Dependent Claim 15 words
A film which has been melt extruded from the wholly aromatic polyester of claim 29.
Claim 44
Dependent Claim 13 words
A molded article comprising the melt processable wholly aromatic polyester of claim 29.
Claim 45
Dependent Claim 29 words
A molding compound comprising the melt processable wholly aromatic polyester of claim 29 which incorporates approximately 1 to 60 percent by weight of a solid filler and/or reinforcing agent.

References Cited (Backward Citations)

US4118372A Cited
US4067852A Cited
US4083829A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-08-26 1984-02-25 1984-08-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-08-26 1988-02-25 1988-08-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-08-26 1992-02-25 1992-08-26 $7700.00 Window Closed / Lapsed

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