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US4471145A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for syngas conversions to liquid hydrocarbon products utilizing zeolite Beta

Assignee: Mobil Oil AS
•
Filing: 1983-09-26
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Granted: 1984-09-11
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Expires: 2003-09-26
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Abstract

Abstract The liquid carrier in a Fischer-Tropsch synthesis slurry reactor system is periodically or continually separated and subjected to cracking and isomerization in the presence of suitable catalysts. The treated carrier is returned to the reactor system and the accumulation of high viscosity paraffin in the reactor slurry is minimized. Suitable catalysts include a mixture of cracking and isomerization catalysts. Zeolite Beta is the novel constituent of the catalyst system.

Inventors

  • 👤 Yung-Feng Chu
  • 👤 Tai-Sheng Chou
  • 👤 Arthur W. Chester

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 08:24
CPC Classifications
C; C10; C10G; C10G11/00; C10G11/02; C10G11/04; C10G11/05; C07; C07C; C07C1/00; C07C1/02; C07C1/04; C07C1/0485; C10G2300/00; C10G2300/10; C10G2300/1022; Y; Y10; Y10S; Y10S208/00; Y10S208/95

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 213 words
Aprocess for converting synthesis gas to liquid hydrocarbons having a boiling range within that of gasoline and distillate comprising the steps of: (a) charging said synthesis gas to a Fischer-Tropsch synthesis conversion zone comprising a catalyst providing CO reducing characteristics in a single form or a combination of catalyst particles in direct contact with a suspending liquid medium; (b) separating at least a fraction of said suspending liquid medium containing dissolved heavier hydrocarbons from said catalyst particles; (c) contacting said separated suspending medium containing heavier hydrocarbons in a cracking zone with a cracking and isomerization catalyst comprising zeolite Beta under conditions effective to crack and isomerize at least a portion of said heavier hydrocarbons to lighter hydrocarbons; (d) separating the resultant product stream of (c) into two streams; (e) removing an effluent stream from said conversion zone of (a) to a second reaction zone containing a crystalline zeolite catalyst; (f) returning one of said streams of (d) to said effluent stream from zone (a); (g) returning the remaining stream of (d) to said conversion zone of (a); and (h) contacting said effluent stream from said conversion zone of (a) with a crystalline zeolite to convert the product of said Fischer-Tropsch synthesis gas conversion to hydrocarbons boiling within the range of distillate and gasoline.
Claim 2
Dependent Claim 213 words
Aprocess for converting synthesis gas to liquid hydrocarbons having a boiling range within that of gasoline and distillate comprising the steps of: (a) charging said synthesis gas to a Fischer-Tropsch synthesis conversion zone comprising a catalyst providing CO reducing characteristics in a single form or a combination of catalyst particles in direct contact with a suspending liquid medium; (b) separating at least a fraction of said suspending liquid medium containing dissolved heavier hydrocarbons from said catalyst particles; (c) contacting said separated suspending medium containing heavier hydrocarbons in a cracking zone with a cracking and isomerization catalyst comprising zeolite Beta under conditions effective to crack and isomerize at least a portion of said heavier hydrocarbons to lighter hydrocarbons; (d) separating the resultant product stream of (c) into two streams; (e) removing an effluent stream from said conversion zone of (a) to a second reaction zone containing a crystalline zeolite catalyst; (f) returning one of said streams of (d) to said effluent stream from zone (a); (g) returning the remaining stream of (d) to said conversion zone of (a); and (h) contacting said effluent stream from said conversion zone of (a) with a crystalline zeolite to convert the product of said Fischer-Tropsch synthesis gas conversion to hydrocarbons boiling within the range of distillate and gasoline.
Claim 3
Dependent Claim 23 words
The process of claim 1 wherein said zeolite Beta has deposited thereon a metal selected from the group consisting of platinum and palladium.
Claim 4
Dependent Claim 18 words
The process of claim 1 wherein the cracking zone of (c) is contiguous to said slurry reactor zone.
Claim 5
Dependent Claim 18 words
The process of claim 1 wherein the cracking zone of (c) is separated from said Fischer-Tropsch reaction zone.
Claim 6
Dependent Claim 28 words
The process of claim 1 wherein the contacting of said suspending medium with zeolite Beta is conducted at a temperature between about 400° F. and about 800° F.
Claim 7
Dependent Claim 24 words
The process of claim 1 wherein the contacting of said suspending medium is conducted at a pressure between about 0 and about 1000 psig.
Claim 8
Dependent Claim 27 words
The process of claim 1 wherein the contacting of said suspending medium is conducted at a liquid hourly space velocity of between about 0.1 and about 20.
Claim 9
Dependent Claim 18 words
The process of claim 1 wherein said isomerization catalyst is a Group VIII metal deposited on zeolite Beta.

References Cited (Backward Citations)

US4041095A Cited
US4159995A Cited
US4279830A Cited
US4252736A Cited
US4423265A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-09-11 1988-03-12 1988-09-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-09-11 1992-03-12 1992-09-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-09-11 1996-03-12 1996-09-11 $7700.00 Window Closed / Lapsed

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