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US4470831A Expired / Lapsed US ⏱️ 0.0 years remaining

Permselective membrane

Assignee: Toray Industries Inc
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Filing: 1982-07-20
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Granted: 1984-09-11
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Expires: 2002-07-20
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Abstract

Abstract A gas permselective membrane comprising a porous support having fine pores continuous in the thickness direction and a layer of a polymer laminated on the surface of said porous support, said polymer comprising a copolymer of (a) and (b), where (a) represents silarylene-siloxane structural units represented by the following general formula ##STR1## wherein R stands for an alkyl group having 1 to 10 carbon atoms, a phenyl group, a nucleus-substituted phenyl group having 6 to 20 carbon atoms, or a substituted alkyl group having 1 to 10 carbon atoms, Ar stands for ##STR2## and m is a number of from 5 to 8000, and wherein (b) represents diorganosiloxane structural units represented by the following general formula ##STR3## wherein R 1 and R 2 each independently stand for an alkyl group having 1 to 10 carbon atoms, a phenyl group, a nucleus-substituted phenyl group having 6 to 20 carbon atoms, a substituted alkyl group having 1 to 10 carbon atoms, a vinyl group, or an alkyl group, and n is a number of from 1 to 2000, with the proviso that n/m is in the range of 0<n/m≦50, wherein the average pore size of said porous membrane is 0.001 to 1 μm and the thickness of said polymer layer is 0.01 to 1 μm. This permselective membrane has a high oxygen-separating capacity and is excellent in respect to pressure resistance and resistance to pinhole formation and, therefore, is valuable for obtaining from air oxygen-rich air-containing oxygen at a high concentration and at a low cost.

Inventors

  • 👤 Masakazu Hirose

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 18:55
CPC Classifications
B; B01; B01D; B01D71/00; B01D71/06; B01D71/70; B01D69/00; B01D69/12; B01D69/1213; C; C08; C08L; C08L83/00; C08L83/14; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2913; Y10T428/2933; Y10T428/2962; Y10T428/31504; Y10T428/31652; Y10T428/31663

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 214 words
A gas permselective membrane which comprises a porous support having fine pores continuous in the thickness direction and a layer of a polymer laminated on the surface of said porous support, said polymer comprising a copolymer of (A) and (B), where (A) represents silarylene-siloxane structural units represented by the following general formula ##STR18## wherein R stands for an alkyl group having 1 to 10 carbon atoms, a phenyl group, a nucleus-substituted phenyl group having 6 to 20 carbon atoms, or a substituted alkyl group having 1 to 10 carbon atoms, Ar stands for ##STR19## and m is a number of from 5 to 8000, and wherein (B) represents diorganosiloxane structural units represented by the following general formula ##STR20## wherein R 1 and R 2 each independently stand for an alkyl group having 1 to 10 carbon atoms, a phenyl group, a nucleus-substituted phenyl group having 6 to 20 carbon atoms, a substituted alkyl group having 1 to 10 carbon atoms, a vinyl group, or an allyl group, and n is a number of from 1 to 2000, with the proviso that n/m is in the range of 0<n/m≦50, wherein the average pore size of said porous membrane is 0.001 to 1 μm and the thickness of said polymer layer is 0.01 to 1 μm.
Claim 2
Dependent Claim 214 words
A gas permselective membrane which comprises a porous support having fine pores continuous in the thickness direction and a layer of a polymer laminated on the surface of said porous support, said polymer comprising a copolymer of (A) and (B), where (A) represents silarylene-siloxane structural units represented by the following general formula ##STR18## wherein R stands for an alkyl group having 1 to 10 carbon atoms, a phenyl group, a nucleus-substituted phenyl group having 6 to 20 carbon atoms, or a substituted alkyl group having 1 to 10 carbon atoms, Ar stands for ##STR19## and m is a number of from 5 to 8000, and wherein (B) represents diorganosiloxane structural units represented by the following general formula ##STR20## wherein R 1 and R 2 each independently stand for an alkyl group having 1 to 10 carbon atoms, a phenyl group, a nucleus-substituted phenyl group having 6 to 20 carbon atoms, a substituted alkyl group having 1 to 10 carbon atoms, a vinyl group, or an allyl group, and n is a number of from 1 to 2000, with the proviso that n/m is in the range of 0<n/m≦50, wherein the average pore size of said porous membrane is 0.001 to 1 μm and the thickness of said polymer layer is 0.01 to 1 μm.
Claim 3
Dependent Claim 23 words
A gas permselective membrane as set forth in claim 1, wherein Ar is a ##STR21## and R is a group --CH 3 .
Claim 4
Dependent Claim 23 words
A gas permselective membrane as set forth in claim 1, wherein R 1 and R 2 stand for a group --CH 3 .
Claim 5
Dependent Claim 25 words
A gas permselective membrane as set forth in claim 1, wherein R 1 is a group --CH 3 , and R 2 is a ##STR22##
Claim 6
Dependent Claim 35 words
A gas permselective membrane as set forth in claim 1, wherein Ar is a ##STR23## R is a group --CH 3 , and R 1 and R 2 stand for a group --CH 3 .
Claim 7
Dependent Claim 36 words
A gas permselective membrane as set forth in claim 1, wherein Ar is a ##STR24## R is a group --CH 3 , R 1 is a group --CH 3 , and R 2 is a ##STR25##
Claim 8
Dependent Claim 35 words
A gas permselective membrane as set forth in claim 1, wherein m is a number of from 5 to 1000, n is a number of 1 to 2000, and n/m is the range of 1/100≦n/m≦50.
Claim 9
Dependent Claim 37 words
A gas permselective membrane as set forth in claim 1, wherein m is a number of from 5 to 500, n is a number of from 1 to 500, and n/m is in the range of 1/100≦n/m≦20.
Claim 10
Dependent Claim 27 words
A gas permselective membrane as set forth in claim 1, wherein the porous support is composed of a polysulfone resin, a polyether sulfone resin, or cellulose acetate.
Claim 11
Dependent Claim 24 words
A gas permselective membrane as set forth in claim 9, wherein the average pore size of the porous support is 0.005 to 0.05 μm.
Claim 12
Dependent Claim 24 words
A gas permselective membrane as set forth in claim 1, wherein the average pore size of the porous membrane is 0.005 to 0.05 μm.
Claim 13
Dependent Claim 22 words
A gas permselective membrane as set forth in claim 1, wherein the thickness of the polymer layer is 0.05 to 0.7 μm.
Claim 14
Dependent Claim 22 words
A gas permselective membrane as set forth in claim 1, wherein the thickness of the polymer layer is 0.1 to 0.5 μm.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-09-11 1988-03-12 1988-09-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-09-11 1992-03-12 1992-09-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-09-11 1996-03-12 1996-09-11 $7700.00 Window Closed / Lapsed

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