US4157960A
Expired / Lapsed
US
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Method for enhancing membrane separation
Assignee: Permea Inc
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Filing: 1977-11-30
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Granted: 1979-06-12
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Expires: 1997-11-30
Abstract
Abstract The selectivities of fluid separations of membranes having pores, in which the material of the membranes significantly effects the fluid separations, can be enhanced by the storage of the membranes in water. Suitable materials of the membranes for improvement in accordance with this invention are those which are not unduly susceptible to biodegradation. The membranes for improvement in accordance with this invention preferably have structures which are not unduly affected by drying and thus maintain beneficial mechanical and fluid separation properties after drying.
Inventors
- 👤 Richard C. Chang
- 👤 Robert R. Ward
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 20:18
CPC Classifications
B; B01; B01D; B01D67/00; B01D67/0002; B01D67/0009; B01D67/0016; B01D67/0081; B01D67/0097; B01D69/00; B01D69/02; B01D71/00; B01D71/06; B01D71/66; B01D71/68
Claims Analysis
Total Claims: 26
Claim 1
Independent Claim
83 words
A method for enhancing the selectivity for fluid separation of a membrane in which the material of the membrane significantly effects the fluid separation, said membrane having a barrier layer with pores therethrough which adversely affect the selectivity of fluid separation and said membrane being resistant to biodegradation, comprising storing the membrane in an aqueous medium having an essential absence of a bacteriostat for a time sufficient to provide growths of microorganisms and thus enhance the selectivity of fluid separation of the membrane.
Claim 2
Independent Claim
83 words
A method for enhancing the selectivity for fluid separation of a membrane in which the material of the membrane significantly effects the fluid separation, said membrane having a barrier layer with pores therethrough which adversely affect the selectivity of fluid separation and said membrane being resistant to biodegradation, comprising storing the membrane in an aqueous medium having an essential absence of a bacteriostat for a time sufficient to provide growths of microorganisms and thus enhance the selectivity of fluid separation of the membrane.
Claim 3
Dependent Claim
30 words
The method of claim 1 wherein the aqueous medium is at a temperature of about 10° to 40° C. and the membrane is stored for at least about one day.
Claim 4
Dependent Claim
15 words
The method of claim 2 wherein the aqueous medium has been used for storing membranes.
Claim 5
Dependent Claim
11 words
The method of claim 2 wherein the aqueous medium is aerated.
Claim 6
Dependent Claim
21 words
The method of claim 2 wherein the growth of microorganisms on the membrane is arrested after the storage of the membrane.
Claim 7
Dependent Claim
13 words
The method of claim 2 wherein the membrane is dried after the storage.
Claim 8
Dependent Claim
23 words
The method of claim 2 wherein the aqueous medium is inoculated with microorganisms suitable for enhancing the selectivity of separation of the membrane.
Claim 9
Dependent Claim
15 words
The method of claim 7 wherein the aqueous medium has been used for storing membranes.
Claim 10
Dependent Claim
11 words
The method of claim 7 wherein the aqueous medium is aerated.
Claim 11
Dependent Claim
21 words
The method of claim 7 wherein the growth of microorganisms on the membrane is arrested after the storage of the membrane.
Claim 12
Dependent Claim
13 words
The method of claim 7 wherein the membrane is dried after the storage.
Claim 13
Dependent Claim
20 words
The method of claim 2 wherein the membrane is anisotropic and the barrier layer of the anisotropic membrane is thin.
Claim 14
Dependent Claim
21 words
The method of claim 12 wherein the membrane is an anisotropic membrane which is formed by coagulation from a solvent solution.
Claim 15
Dependent Claim
11 words
The method of claim 13 wherein the anisotropic membrane comprises polysulfone.
Claim 16
Dependent Claim
51 words
The method of claim 14 wherein the polysulfone has the repeating structural unit ##STR9## wherein R and R' can be the same or different and are aliphatic or aromatic hydrocarbyl-containing moieties of 1 to about 40 carbon atoms, and the polysulfone has an average molecular weight of at least about 10,000.
Claim 17
Dependent Claim
24 words
The method of claim 15 wherein the solvent for the polymer solution for coagulation comprises at least one of dimethylformamide, dimethylacetamide, dimethylpropionamide, and N-methylpyrrolidone.
Claim 18
Dependent Claim
37 words
The method of claim 16 wherein the membrane exhibits selectivities of fluid separation characteristic of fluid separation by Knudsen diffusion or by a combination of Knudsen diffusion and separation by interaction with the material of the membrane.
Claim 19
Dependent Claim
23 words
The method of claim 16 wherein the aqueous medium is inoculated with microorganisms suitable for enhancing the selectivity of separation of the membrane.
Claim 20
Dependent Claim
15 words
The method of claim 18 wherein the aqueous medium has been used for storing membranes.
Claim 21
Dependent Claim
11 words
The method of claim 18 wherein the aqueous medium is aerated.
Claim 22
Dependent Claim
21 words
The method of claim 18 wherein the growth of microorganisms on the membrane is arrested after the storage of the membrane.
Claim 23
Dependent Claim
13 words
The method of claim 18 wherein the membrane is dried after the storage.
Claim 24
Dependent Claim
10 words
The method of claim 12 wherein the membrane comprises polysulfone.
Claim 25
Dependent Claim
43 words
The method of claim 12 wherein the ratio of total surface area of the membrane to total pore cross-sectional area through the barrier layer is at least about 10 3 :1 and the average pore cross-sectional diameter is less than about 1000 angstroms.
Claim 26
Dependent Claim
37 words
The method of claim 24 wherein the membrane exhibits selectivities of fluid separation characteristic of fluid separation by Knudsen diffusion or by a combination of Knudsen diffusion and separation by interaction with the material of the membrane.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-06-11 | 1982-12-11 | 1983-06-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-06-11 | 1986-12-11 | 1987-06-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-06-11 | 1990-12-11 | 1991-06-12 | $7700.00 | Window Closed / Lapsed |