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US4465494A
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Microemulsion of water in a liquid fuel
Assignee: Societe National Elf Aquitaine
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Filing: 1982-02-10
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Granted: 1984-08-14
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Expires: 2002-02-10
Abstract
Abstract The present invention relates to a process for the preparation of a microemulsion of water or water and another additive, especially alcohol or amine, in a liquid fuel, in the presence of a surface active agent. Such microemulsions are intended to be used as fuel in an engine or a burner.
Inventors
- 👤 Maurice Bourrel
- 👤 Alain Sanchez
- 👤 Jean-Claude Soula
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 21:15
CPC Classifications
C; C10; C10L; C10L1/00; C10L1/32; C10L1/328; Y; Y10; Y10S; Y10S516/00; Y10S516/01; Y10S516/06
Claims Analysis
Total Claims: 28
Claim 1
Independent Claim
144 words
In a process for the preparation of a microemulsion by mixing water and a liquid fuel in the presence of a surface active agent, the improvement which comprises said agent being an alkyl phenoxy-alkanoate of ammonium, a metal or an organic base of the formula ##STR4## in which R 1 is hydrogen, R 2 is a linear or branched C 6 to C 18 alkyl radical, n is an integer from 1 to 6 and M is Na, K, Li, NH 4 or RNH 3 wherein R is a hydrocarbon or hydroxy-substituted hydrocarbon radical, in an amount of 0.5 to 10 percent, and a cosurfactant which is a C 1 to C 8 alcohol or an amine in an amount of 1 to 27 percent, and the amount of water is 1 to 10% and the balance of said microemulsion is said liquid fuel.
Claim 2
Dependent Claim
144 words
In a process for the preparation of a microemulsion by mixing water and a liquid fuel in the presence of a surface active agent, the improvement which comprises said agent being an alkyl phenoxy-alkanoate of ammonium, a metal or an organic base of the formula ##STR4## in which R 1 is hydrogen, R 2 is a linear or branched C 6 to C 18 alkyl radical, n is an integer from 1 to 6 and M is Na, K, Li, NH 4 or RNH 3 wherein R is a hydrocarbon or hydroxy-substituted hydrocarbon radical, in an amount of 0.5 to 10 percent, and a cosurfactant which is a C 1 to C 8 alcohol or an amine in an amount of 1 to 27 percent, and the amount of water is 1 to 10% and the balance of said microemulsion is said liquid fuel.
Claim 3
Dependent Claim
15 words
Process according to claim 1, wherein n is an integer equal to 1 or 2.
Claim 4
Dependent Claim
18 words
A process according to claim 1, wherein 1 to 27% an alcohol co-surfactant is employed with said agent.
Claim 5
Dependent Claim
12 words
A process according to claim 1, wherein said amine is a benzylamine.
Claim 6
Dependent Claim
22 words
A process according to claim 1 in which the alkyl phenoxy-alkanoate is sodium p-lauryl phenoxyacetate, monoethanolamine p-lauryl phenoxyacetate or sodium p-nonyl phenoxyacetate.
Claim 7
Dependent Claim
18 words
A process according to claim 1 wherein the amount of the surface active agent is 1 to 6%.
Claim 8
Dependent Claim
126 words
Microemulsion of water and a liquid fuel containing a surface active agent, wherein the said surface active agent is an alkyl-phenoxy-alkanoate of ammonium, a metal or an amine of the formula ##STR5## in which R 1 is hydrogen, R 2 is a linear or branched C 6 to C 18 alkyl radical, n is an integer from 1 to 6 and M is Na, K, Li, NH 4 or RNH 3 wherein R is a hydrocarbon or hydroxy-substituted hydrocarbon radical, in an amount of 0.5 to 10 percent, also containing 1 to 27 percent of a C 1 to C 8 alcohol or an amine, and wherein the amount of water is 1 to 10 percent and the balance of said microemulsion is said liquid fuel.
Claim 9
Dependent Claim
126 words
Microemulsion of water and a liquid fuel containing a surface active agent, wherein the said surface active agent is an alkyl-phenoxy-alkanoate of ammonium, a metal or an amine of the formula ##STR5## in which R 1 is hydrogen, R 2 is a linear or branched C 6 to C 18 alkyl radical, n is an integer from 1 to 6 and M is Na, K, Li, NH 4 or RNH 3 wherein R is a hydrocarbon or hydroxy-substituted hydrocarbon radical, in an amount of 0.5 to 10 percent, also containing 1 to 27 percent of a C 1 to C 8 alcohol or an amine, and wherein the amount of water is 1 to 10 percent and the balance of said microemulsion is said liquid fuel.
Claim 10
Dependent Claim
15 words
Microemulsion according to claim 7, wherein said microemulsion contains 1 to 6% surface active agent.
Claim 11
Dependent Claim
15 words
Microemulsion according to claim 7 wherein n is an integer equal to 1 or 2.
Claim 12
Dependent Claim
20 words
Microemulsion according to claim 7 wherein said surface active agent is sodium p-lauryl phenoxyacetate, monoethanolamine p-lauryl phenoxyacetate or sodium p-nonylphenoxyacetate.
Claim 13
Dependent Claim
151 words
In the application of a microemulsion of water or of water accompanied by an alcohol or an amine, in a liquid fuel, to combustion in an engine or a burner, wherein the microemulsion contains a surface active agent, the improvement which comprises said surface active agent being an alkyl-phenoxy-alkanoate of ammonia, a metal or an organic base of the formula ##STR6## in which R 1 is hydrogen, R 2 is a linear or branched C 6 to C 18 alkyl radical, n is an integer from 1 to 6 and M is Na, K, Li, NH 4 or RNH 3 wherein R is a hydrocarbon or hydroxy-substituted hydrocarbon radical, in an amount of 0.5 to 10 percent, and wherein said microemulsion contains, by weight, 1 to 10% water, and 1 to 27% C 1 to C 8 alcohol or an amine and the balance of said microemulsion is said liquid fuel.
Claim 14
Dependent Claim
151 words
In the application of a microemulsion of water or of water accompanied by an alcohol or an amine, in a liquid fuel, to combustion in an engine or a burner, wherein the microemulsion contains a surface active agent, the improvement which comprises said surface active agent being an alkyl-phenoxy-alkanoate of ammonia, a metal or an organic base of the formula ##STR6## in which R 1 is hydrogen, R 2 is a linear or branched C 6 to C 18 alkyl radical, n is an integer from 1 to 6 and M is Na, K, Li, NH 4 or RNH 3 wherein R is a hydrocarbon or hydroxy-substituted hydrocarbon radical, in an amount of 0.5 to 10 percent, and wherein said microemulsion contains, by weight, 1 to 10% water, and 1 to 27% C 1 to C 8 alcohol or an amine and the balance of said microemulsion is said liquid fuel.
Claim 15
Dependent Claim
15 words
Application according to claim 11 wherein n is an integer equal to 1 or 2.
Claim 16
Dependent Claim
15 words
Application according to claim 11 wherein said microemulsion contains 1 to 6% surface active agent.
Claim 17
Dependent Claim
21 words
Application according to claim 11 wherein said surface active agent is sodium p-lauryl phenoxyacetate, monoethanolamine p-lauryl phenoxyacetate or sodium p-nonyl phenoxyacetate.
Claim 18
Dependent Claim
39 words
A process according to claim 4 in which the amount of benzylamine is 0.8%, the amount of water is 9.6%, the amount of said agent is 0.5 to 10%, and the balance of said microemulsion is said liquid fuel.
Claim 19
Dependent Claim
16 words
A process according to claim 1 in which the cosurfactant is methanol, ethanol, isobutanol or ethyl-2-hexanol.
Claim 20
Dependent Claim
38 words
A process according to claim 16 in which the amount of alcohol is 1.3 to 26.8%, the amount of water is 1 to 9.6%, the amount of said agent is 0.5-10% and the balance is said liquid fuel.
Claim 21
Dependent Claim
12 words
A microemulsion according to claim 7 in which the cosurfactant is benzylamine.
Claim 22
Dependent Claim
39 words
A microemulsion according to claim 18 in which the amount of benzylamine is 0.8%, the amount of water is 9.6%, the amount of said agent is 0.5 to 10% and the balance of said microemulsion is said liquid fuel.
Claim 23
Dependent Claim
16 words
A microemulsion according to claim 7 in which the cosurfactant is methanol, ethanol, isobutanol or ethyl-2-hexanol.
Claim 24
Dependent Claim
38 words
A microemulsion according to claim 20 in which the amount of alcohol is 1.3 to 26.8%, the amount of water is 1 to 9.6%, the amount of said agent is 0.5-10% and the balance is said liquid fuel.
Claim 25
Dependent Claim
11 words
Application according to claim 11 in which the cosurfactant is benzylamine.
Claim 26
Dependent Claim
38 words
Application according to claim 22 in which the amount of benzylamine is 0.8%, the amount of water is 9.6%, the amount of said agent is 0.5 to 10% and the balance of said microemulsion is said liquid fuel.
Claim 27
Dependent Claim
15 words
Application according to claim 11 in which the cosurfactant is methanol, ethanol, isobutanol or ethyl-2-hexanol.
Claim 28
Dependent Claim
37 words
Application according to claim 24 in which the amount of alcohol is 1.3 to 26.8%, the amount of water is 1 to 9.6%, the amount of said agent is 0.5-10% and the balance is said liquid fuel.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-08-14 | 1988-02-13 | 1988-08-14 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-08-14 | 1992-02-13 | 1992-08-14 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-08-14 | 1996-02-13 | 1996-08-14 | $7700.00 | Window Closed / Lapsed |