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Microemulsion of water in a liquid fuel

Assignee: Societe National Elf Aquitaine
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Filing: 1982-02-10
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Granted: 1984-08-14
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Expires: 2002-02-10
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Abstract

Abstract The present invention relates to a process for the preparation of a microemulsion of water or water and another additive, especially alcohol or amine, in a liquid fuel, in the presence of a surface active agent. Such microemulsions are intended to be used as fuel in an engine or a burner.

Inventors

  • 👤 Maurice Bourrel
  • 👤 Alain Sanchez
  • 👤 Jean-Claude Soula

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 21:15
CPC Classifications
C; C10; C10L; C10L1/00; C10L1/32; C10L1/328; Y; Y10; Y10S; Y10S516/00; Y10S516/01; Y10S516/06

Claims Analysis

Total Claims: 28
Claim 1
Independent Claim 144 words
In a process for the preparation of a microemulsion by mixing water and a liquid fuel in the presence of a surface active agent, the improvement which comprises said agent being an alkyl phenoxy-alkanoate of ammonium, a metal or an organic base of the formula ##STR4## in which R 1 is hydrogen, R 2 is a linear or branched C 6 to C 18 alkyl radical, n is an integer from 1 to 6 and M is Na, K, Li, NH 4 or RNH 3 wherein R is a hydrocarbon or hydroxy-substituted hydrocarbon radical, in an amount of 0.5 to 10 percent, and a cosurfactant which is a C 1 to C 8 alcohol or an amine in an amount of 1 to 27 percent, and the amount of water is 1 to 10% and the balance of said microemulsion is said liquid fuel.
Claim 2
Dependent Claim 144 words
In a process for the preparation of a microemulsion by mixing water and a liquid fuel in the presence of a surface active agent, the improvement which comprises said agent being an alkyl phenoxy-alkanoate of ammonium, a metal or an organic base of the formula ##STR4## in which R 1 is hydrogen, R 2 is a linear or branched C 6 to C 18 alkyl radical, n is an integer from 1 to 6 and M is Na, K, Li, NH 4 or RNH 3 wherein R is a hydrocarbon or hydroxy-substituted hydrocarbon radical, in an amount of 0.5 to 10 percent, and a cosurfactant which is a C 1 to C 8 alcohol or an amine in an amount of 1 to 27 percent, and the amount of water is 1 to 10% and the balance of said microemulsion is said liquid fuel.
Claim 3
Dependent Claim 15 words
Process according to claim 1, wherein n is an integer equal to 1 or 2.
Claim 4
Dependent Claim 18 words
A process according to claim 1, wherein 1 to 27% an alcohol co-surfactant is employed with said agent.
Claim 5
Dependent Claim 12 words
A process according to claim 1, wherein said amine is a benzylamine.
Claim 6
Dependent Claim 22 words
A process according to claim 1 in which the alkyl phenoxy-alkanoate is sodium p-lauryl phenoxyacetate, monoethanolamine p-lauryl phenoxyacetate or sodium p-nonyl phenoxyacetate.
Claim 7
Dependent Claim 18 words
A process according to claim 1 wherein the amount of the surface active agent is 1 to 6%.
Claim 8
Dependent Claim 126 words
Microemulsion of water and a liquid fuel containing a surface active agent, wherein the said surface active agent is an alkyl-phenoxy-alkanoate of ammonium, a metal or an amine of the formula ##STR5## in which R 1 is hydrogen, R 2 is a linear or branched C 6 to C 18 alkyl radical, n is an integer from 1 to 6 and M is Na, K, Li, NH 4 or RNH 3 wherein R is a hydrocarbon or hydroxy-substituted hydrocarbon radical, in an amount of 0.5 to 10 percent, also containing 1 to 27 percent of a C 1 to C 8 alcohol or an amine, and wherein the amount of water is 1 to 10 percent and the balance of said microemulsion is said liquid fuel.
Claim 9
Dependent Claim 126 words
Microemulsion of water and a liquid fuel containing a surface active agent, wherein the said surface active agent is an alkyl-phenoxy-alkanoate of ammonium, a metal or an amine of the formula ##STR5## in which R 1 is hydrogen, R 2 is a linear or branched C 6 to C 18 alkyl radical, n is an integer from 1 to 6 and M is Na, K, Li, NH 4 or RNH 3 wherein R is a hydrocarbon or hydroxy-substituted hydrocarbon radical, in an amount of 0.5 to 10 percent, also containing 1 to 27 percent of a C 1 to C 8 alcohol or an amine, and wherein the amount of water is 1 to 10 percent and the balance of said microemulsion is said liquid fuel.
Claim 10
Dependent Claim 15 words
Microemulsion according to claim 7, wherein said microemulsion contains 1 to 6% surface active agent.
Claim 11
Dependent Claim 15 words
Microemulsion according to claim 7 wherein n is an integer equal to 1 or 2.
Claim 12
Dependent Claim 20 words
Microemulsion according to claim 7 wherein said surface active agent is sodium p-lauryl phenoxyacetate, monoethanolamine p-lauryl phenoxyacetate or sodium p-nonylphenoxyacetate.
Claim 13
Dependent Claim 151 words
In the application of a microemulsion of water or of water accompanied by an alcohol or an amine, in a liquid fuel, to combustion in an engine or a burner, wherein the microemulsion contains a surface active agent, the improvement which comprises said surface active agent being an alkyl-phenoxy-alkanoate of ammonia, a metal or an organic base of the formula ##STR6## in which R 1 is hydrogen, R 2 is a linear or branched C 6 to C 18 alkyl radical, n is an integer from 1 to 6 and M is Na, K, Li, NH 4 or RNH 3 wherein R is a hydrocarbon or hydroxy-substituted hydrocarbon radical, in an amount of 0.5 to 10 percent, and wherein said microemulsion contains, by weight, 1 to 10% water, and 1 to 27% C 1 to C 8 alcohol or an amine and the balance of said microemulsion is said liquid fuel.
Claim 14
Dependent Claim 151 words
In the application of a microemulsion of water or of water accompanied by an alcohol or an amine, in a liquid fuel, to combustion in an engine or a burner, wherein the microemulsion contains a surface active agent, the improvement which comprises said surface active agent being an alkyl-phenoxy-alkanoate of ammonia, a metal or an organic base of the formula ##STR6## in which R 1 is hydrogen, R 2 is a linear or branched C 6 to C 18 alkyl radical, n is an integer from 1 to 6 and M is Na, K, Li, NH 4 or RNH 3 wherein R is a hydrocarbon or hydroxy-substituted hydrocarbon radical, in an amount of 0.5 to 10 percent, and wherein said microemulsion contains, by weight, 1 to 10% water, and 1 to 27% C 1 to C 8 alcohol or an amine and the balance of said microemulsion is said liquid fuel.
Claim 15
Dependent Claim 15 words
Application according to claim 11 wherein n is an integer equal to 1 or 2.
Claim 16
Dependent Claim 15 words
Application according to claim 11 wherein said microemulsion contains 1 to 6% surface active agent.
Claim 17
Dependent Claim 21 words
Application according to claim 11 wherein said surface active agent is sodium p-lauryl phenoxyacetate, monoethanolamine p-lauryl phenoxyacetate or sodium p-nonyl phenoxyacetate.
Claim 18
Dependent Claim 39 words
A process according to claim 4 in which the amount of benzylamine is 0.8%, the amount of water is 9.6%, the amount of said agent is 0.5 to 10%, and the balance of said microemulsion is said liquid fuel.
Claim 19
Dependent Claim 16 words
A process according to claim 1 in which the cosurfactant is methanol, ethanol, isobutanol or ethyl-2-hexanol.
Claim 20
Dependent Claim 38 words
A process according to claim 16 in which the amount of alcohol is 1.3 to 26.8%, the amount of water is 1 to 9.6%, the amount of said agent is 0.5-10% and the balance is said liquid fuel.
Claim 21
Dependent Claim 12 words
A microemulsion according to claim 7 in which the cosurfactant is benzylamine.
Claim 22
Dependent Claim 39 words
A microemulsion according to claim 18 in which the amount of benzylamine is 0.8%, the amount of water is 9.6%, the amount of said agent is 0.5 to 10% and the balance of said microemulsion is said liquid fuel.
Claim 23
Dependent Claim 16 words
A microemulsion according to claim 7 in which the cosurfactant is methanol, ethanol, isobutanol or ethyl-2-hexanol.
Claim 24
Dependent Claim 38 words
A microemulsion according to claim 20 in which the amount of alcohol is 1.3 to 26.8%, the amount of water is 1 to 9.6%, the amount of said agent is 0.5-10% and the balance is said liquid fuel.
Claim 25
Dependent Claim 11 words
Application according to claim 11 in which the cosurfactant is benzylamine.
Claim 26
Dependent Claim 38 words
Application according to claim 22 in which the amount of benzylamine is 0.8%, the amount of water is 9.6%, the amount of said agent is 0.5 to 10% and the balance of said microemulsion is said liquid fuel.
Claim 27
Dependent Claim 15 words
Application according to claim 11 in which the cosurfactant is methanol, ethanol, isobutanol or ethyl-2-hexanol.
Claim 28
Dependent Claim 37 words
Application according to claim 24 in which the amount of alcohol is 1.3 to 26.8%, the amount of water is 1 to 9.6%, the amount of said agent is 0.5-10% and the balance is said liquid fuel.

References Cited (Backward Citations)

US2110847A Cited
US2370256A Cited
FR2071297A5 Cited
US3876391A Cited
US4002435A Cited
US4046519A Cited
WO1980000921A1 Cited
EP0012345A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-08-14 1988-02-13 1988-08-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-08-14 1992-02-13 1992-08-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-08-14 1996-02-13 1996-08-14 $7700.00 Window Closed / Lapsed

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