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US4463215A Expired / Lapsed US ⏱️ 0.0 years remaining

Cadmium sulphide solar cell

Assignee: Prutec Ltd
•
Filing: 1983-03-07
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Granted: 1984-07-31
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Expires: 2003-03-07
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Abstract

Abstract The invention relates to the manufacture of cadmium sulphide solar cells. A cell is formed of a glass substrate 10, a front contact 12 made, for example, of tin oxide, a cadmium sulphide layer 14 and a copper sulphide layer 16. the junction between the layers 14 and 16 is photovoltaic. In order to form a rear contact 18 on the copper sulphide layer, the invention proposes vapor depositing a mixed layer of copper and copper oxide onto the sulphide layer. The invention also describes a method of heat treatment following the formation of the rear contact in order to optimise the electrical performance of the cell.

Inventors

  • 👤 Peter J. Bassett
  • 👤 Augustinus W. Verheijen

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 17:42
CPC Classifications
H; H10; H10F; H10F10/00; H10F10/10; H10F10/16; H10F10/169; H10F71/00; H10F77/00; H10F77/20; H10F77/206; H10F77/211; Y; Y02; Y02E; Y02E10/00; Y02E10/50

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 54 words
A method of establishing electrical contact with the copper sulphide layer of a cadmium sulphide-copper sulphide solar cell, in which a mixture of copper and cuprous containing copper oxide in a layer thicker than said copper sulphide layer is co-deposited onto the copper sulphide layer to make ohmic contact with the copper sulphide layer.
Claim 2
Independent Claim 54 words
A method of establishing electrical contact with the copper sulphide layer of a cadmium sulphide-copper sulphide solar cell, in which a mixture of copper and cuprous containing copper oxide in a layer thicker than said copper sulphide layer is co-deposited onto the copper sulphide layer to make ohmic contact with the copper sulphide layer.
Claim 3
Dependent Claim 89 words
In a method of manufacturing a cadmium sulphide solar cell, comprising the steps of: forming a front contact by coating a transparent substrate with an electrically conductive transparent material; forming over the front contact a layer of cadmium sulphide; forming a copper sulphide layer over the cadmium sulphide layer to produce a photovoltaic junction; and forming a rear contact on the copper sulphide layer; the improvement wherein the rear contact is formed by co-depositing onto the copper sulphide layer a mixed layer of copper and cuprous containing copper oxide.
Claim 4
Dependent Claim 89 words
In a method of manufacturing a cadmium sulphide solar cell, comprising the steps of: forming a front contact by coating a transparent substrate with an electrically conductive transparent material; forming over the front contact a layer of cadmium sulphide; forming a copper sulphide layer over the cadmium sulphide layer to produce a photovoltaic junction; and forming a rear contact on the copper sulphide layer; the improvement wherein the rear contact is formed by co-depositing onto the copper sulphide layer a mixed layer of copper and cuprous containing copper oxide.
Claim 5
Dependent Claim 42 words
The method set forth in claim 2, in which, following deposition of the copper and copper oxide layer, the cell is subjected to a heat treatment to cause migration of copper ions in order to improve the electrical performance of the cell.
Claim 6
Dependent Claim 26 words
The method set forth in claim 3, wherein the heat treatment comprises heating the cell at a temperature of 150° C. for ten minutes in air.
Claim 7
Dependent Claim 19 words
The method set forth in claim 2, wherein following the formation of the rear contact, the cell is encapsulated.
Claim 8
Dependent Claim 16 words
The method set forth in claim 2, wherein the copper oxide consists essentially of cuprous oxide.
Claim 9
Dependent Claim 29 words
The method set forth in claim 2, wherein ohmic contact is established with said mixed layer by bonding a copper output electrode thereto by means of a solder layer.
Claim 10
Dependent Claim 25 words
The method set forth in claim 7, wherein said output electrode forms part of a film deposited grid connecting a plurality of said solar cells.
Claim 11
Dependent Claim 12 words
A cadmium sulphide solar cell manufactured by the method of claim 2.
Claim 12
Dependent Claim 12 words
A cadmium sulphide solar cell manufactured by the method of claim 3.
Claim 13
Dependent Claim 12 words
A cadmium sulphide solar cell manufactured by the method of claim 4.
Claim 14
Dependent Claim 12 words
A cadmium sulphide solar cell manufactured by the method of claim 5.
Claim 15
Dependent Claim 12 words
A cadmium sulphide solar cell manufactured by the method of claim 6.
Claim 16
Dependent Claim 12 words
A cadmium sulphide solar cell manufactured by the method of claim 7.
Claim 17
Dependent Claim 17 words
A panel comprising a plurality of cadmium sulphide solar cells manufactured by the method of claim 8.

References Cited (Backward Citations)

US4104420A Cited
US4283590A Cited
US4239553A Cited
US4267398A Cited
US4318938A Cited
US4251286A Cited
US4260428A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-07-31 1988-01-30 1988-07-31 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-07-31 1992-01-30 1992-07-31 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-07-31 1996-01-30 1996-07-31 $7700.00 Window Closed / Lapsed

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