US4260428A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Photovoltaic cell
Assignee: DELAWARE NEWARK DE A DE NOT-FOR-PROFIT CORP, University of
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Filing: 1980-03-05
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Granted: 1981-04-07
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Expires: 2000-03-05
Abstract
Abstract A photovoltaic cell having improved stability and lifetime comprising a cadmium sulfide film, an overlying copper sulfide film and deposited on the copper sulfide film, a film selected from the group consisting of a film of chromium, a film of chromium having deposited thereon a film of copper, a film of copper having deposited thereon a film of chromium and a film of an admixture of chromium and copper. A method for making such a photovoltaic cell is also disclosed.
Inventors
- 👤 Pradip K. Roy
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 05:47
CPC Classifications
H; H10; H10F; H10F77/00; H10F77/20; H10F77/206; H10F77/211; H10F10/00; H10F10/10; H10F10/16; H10F10/169; Y; Y02; Y02E; Y02E10/00; Y02E10/50
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
107 words
An improved photovoltaic cell comprising: an electrically conductive first electrode a first film of cadmium sulfide in ohmic contact with said electrode; a second film of cuprous sulfide in contact with said cadmium sulfide film and forming a p-n junction therewith; a third film in contact with said cuprous sulfide film and selected from the group consisting of a film comprising chromium, a film comprising chromium having deposited thereon a film comprising copper, a film comprising copper having deposited thereon a film comprising chromium and a film comprising an admixture of chromium and copper and; an electrically conductive second electrode in ohmic contact with said third film.
Claim 2
Dependent Claim
107 words
An improved photovoltaic cell comprising: an electrically conductive first electrode a first film of cadmium sulfide in ohmic contact with said electrode; a second film of cuprous sulfide in contact with said cadmium sulfide film and forming a p-n junction therewith; a third film in contact with said cuprous sulfide film and selected from the group consisting of a film comprising chromium, a film comprising chromium having deposited thereon a film comprising copper, a film comprising copper having deposited thereon a film comprising chromium and a film comprising an admixture of chromium and copper and; an electrically conductive second electrode in ohmic contact with said third film.
Claim 3
Dependent Claim
42 words
The cell of claim 1 wherein said third film is a chromium comprising film ranging from about 8 to about 15 angstroms in thickness and said second electrode is a grid-like electrode which allows radiant energy to pass into said third film
Claim 4
Dependent Claim
59 words
The cell of claim 1 wherein said third film is a film comprising chromium ranging from about 8 to about 15 angstroms in thickness having deposited thereon a film comprising copper ranging from about 50 to about 100 angstroms in thickness and said second electrode is a grid-like electrode which allows radiant energy to pass into said third film.
Claim 5
Dependent Claim
58 words
The cell of claim 1 wherein said third film is a film comprising copper ranging from about 50 to about 100 angstroms in thickness having deposited thereon a film comprising of chromium ranging from about 8 to about 15 angstroms and said second electrode is a grid-like electrode which allows radiant energy to pass through said third film.
Claim 6
Dependent Claim
44 words
The cell of claim 1 wherein said third film is a film comprising chromium admixted with copper ranging from about 50 to about 100 angstroms in thickness and said second electrode is a grid-like electrode which allows radiant energy to pass through said third-film.
Claim 7
Dependent Claim
39 words
The cell of claim 1 wherein said first electrode is stannic oxide, indium oxide or mixtures thereof ranging in thickness from about 10 3 to about 2×10 4 angstroms and is supported on a substrate transparent to radiant energy.
Claim 8
Dependent Claim
10 words
The cell of claim 6 wherein said substrate is glass.
Claim 9
Dependent Claim
114 words
In a method for making a photovoltaic cell comprising: providing an electrically conductive first electrode; applying a first film of cadmium sulfide to said first electrode; applying a second film of cuprous sulfide to said first film and forming a p-n junction therewith and; applying an electrically conductive second electrode thereon; the improvement which comprises applying a third film to said second film before applying said second electrode; said third film being selected from the group consisting of a film comprising chromium, a film comprising chromium having deposited thereon a film comprising copper, a film comprising copper having deposited thereon a film comprising chromium and a film comprising an admixture of chromium and copper.
Claim 10
Dependent Claim
114 words
In a method for making a photovoltaic cell comprising: providing an electrically conductive first electrode; applying a first film of cadmium sulfide to said first electrode; applying a second film of cuprous sulfide to said first film and forming a p-n junction therewith and; applying an electrically conductive second electrode thereon; the improvement which comprises applying a third film to said second film before applying said second electrode; said third film being selected from the group consisting of a film comprising chromium, a film comprising chromium having deposited thereon a film comprising copper, a film comprising copper having deposited thereon a film comprising chromium and a film comprising an admixture of chromium and copper.
Claim 11
Dependent Claim
44 words
The method of claim 8 wherein said third film is a film comprising chromium applied to a thickness ranging from about 8 to about 15 angstroms and said second electrode is a grid-like electrode which allows radiant energy to pass through said third film.
Claim 12
Dependent Claim
63 words
The method of claim 8 wherein said third film is a film comprising chromium applied to a thickness ranging from about 8 to about 15 angstroms having applied thereon a film comprising copper applied to a thickness ranging from about 50 to about 100 angstroms and said second electrode is a grid-like electrode which allows radiant energy to pass through said third film.
Claim 13
Dependent Claim
63 words
The method of claim 8 wherein said third film is a film comprising copper applied to a thickness ranging from about 50 to about 100 angstroms having applied thereon a film comprising chromium applied to a thickness ranging from about 8 to about 15 angstroms and said second electrode is a grid-like electrode which allows radiant energy to pass through said third film.
Claim 14
Dependent Claim
48 words
The method of claim 8 wherein said third film is a film comprising an admixture of chromium and copper applied to a thickness ranging from about 50 to about 100 angstroms and said top electrode is grid-like electrode which allows radiant energy to pass through said third film.
Claim 15
Dependent Claim
56 words
The method of claim 8 wherein said bottom electrode is stannic oxide, indium oxide or mixtures thereof applied to a substrate transparent to radiant energy and to a thickness ranging from about 10 3 to about 2×10 4 angstroms, and said third film is applied to a thickness raging from about 10 to about 25 angstroms.
Claim 16
Independent Claim
22 words
The method of any one of claims 8, 9, 10, 11, 12 or 13 wherein said third film is applied by evaporation.
Claim 17
Independent Claim
21 words
The method of any one of claims 8, 9, 10, 11, 12 or 13 wherein said third film is applied chemically.
Claim 18
Independent Claim
21 words
The method of any one of claims 8, 9, 10, 11, 12 or 13 wherein said third film is applied electrolytically.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-04-06 | 1984-10-06 | 1985-04-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-04-06 | 1988-10-06 | 1989-04-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-04-06 | 1992-10-06 | 1993-04-07 | $7700.00 | Window Closed / Lapsed |