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US4451264A Expired / Lapsed US ⏱️ 0.0 years remaining

Surface coloring of polyvinyl resins

Assignee: Formulabs Industrial Inks Inc
•
Filing: 1982-09-27
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Granted: 1984-05-29
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Expires: 2002-09-27
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Abstract

Abstract This invention is directed to inks (coloring solutions) for polyvinyl resin surfaces, particularly PVC wire insulation color coding, where the ink consists essentially of a Color Index Solvent dye dissolved in a liquid halogenated hydrocarbon solvent having 1-2 carbon atoms. A preferred solvent is dichloromethane.

Inventors

  • 👤 Donald C. Ulry
  • 👤 Charles G. Cosner
  • 👤 Thomas D. Ryan

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 03:59
CPC Classifications
D; D06; D06P; D06P1/00; D06P1/90; D06P1/92; D06P1/922; D06P1/924; Y; Y10; Y10S; Y10S8/00; Y10S8/938

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 76 words
A process for the coloring of water insoluble, organic solvent resistant, electrical insulator polyvinyl resins which process comprises: (A) contacting a surface area of said polyvinyl resin with a liquid, nonflammable, halogenated hydrocarbon solvent having 1-2 carbon atoms where halogen is chlorine, fluorine or both, and a solvent dye dissolved in said solvent; (B) at about room temperature for a time sufficient to color said surface area; and (C) removing residual solvent from said surface area.
Claim 2
Dependent Claim 76 words
A process for the coloring of water insoluble, organic solvent resistant, electrical insulator polyvinyl resins which process comprises: (A) contacting a surface area of said polyvinyl resin with a liquid, nonflammable, halogenated hydrocarbon solvent having 1-2 carbon atoms where halogen is chlorine, fluorine or both, and a solvent dye dissolved in said solvent; (B) at about room temperature for a time sufficient to color said surface area; and (C) removing residual solvent from said surface area.
Claim 3
Dependent Claim 78 words
The process of claim 1 wherein said polyvinyl resin is selected from the class consisting of: polyvinyl chloride, polyvinyl dichloride, polyvinyl fluoride, polyvinyl acetate, polyvinyl propionate, polyvinyl butyrate, polyvinyl acetal, polyvinyl butyral, polyvinyl formal, polyvinylidene chloride, polyvinylidene fluoride; the copolymers of vinyl chloride, vinyl fluoride, vinyl acetate, vinyl propionate, vinyl butyrate, vinylidene chloride, vinylidene fluoride, acrylate and acrylonitrile monomers; and graft polymers of polyvinyl chloride, polyvinyl acetate, polyvinylidene chloride with ethylene vinyl acetate or ethylene propylene diene monomers.
Claim 4
Dependent Claim 28 words
The process of claim 1 wherein said polyvinyl resin is selected from the group consisting of: polyvinyl chloride, polyvinyl dichloride, polyvinyl fluoride, polyvinyl(chloride-acetate), poly(vinylchloride-vinylidene chloride), and poly(vinyl chloride-methylmethacrylate).
Claim 5
Dependent Claim 10 words
The process of claim 1 wherein said chloromethane is dichloromethane.
Claim 6
Dependent Claim 25 words
The process of claim 1 wherein said solvent dye is selected from the class consisting of anthraquinone, azine, azo, phthalocyanine, triarylmethane, diphenylmethane, styryl, and xanthene.
Claim 7
Dependent Claim 21 words
The process of claim 6 wherein said anthraquinone dye is 1,4-bis(R-amino)anthraquinone where R is alkyl having 1-6 carbon atoms or aryl.
Claim 8
Dependent Claim 65 words
A process for the coloring of electrical insulator quality polyvinyl resins, which process comprises: (A) contacting a surface area of said polyvinyl resin with an ink consisting of (a) dichloromethane solvent and (b) dye dissolved in said solvent; (B) at about room temperature for a time sufficient to color said surface area; and (C) removing residual solvent from said surface area at about room temperature.
Claim 9
Dependent Claim 65 words
A process for the coloring of electrical insulator quality polyvinyl resins, which process comprises: (A) contacting a surface area of said polyvinyl resin with an ink consisting of (a) dichloromethane solvent and (b) dye dissolved in said solvent; (B) at about room temperature for a time sufficient to color said surface area; and (C) removing residual solvent from said surface area at about room temperature.
Claim 10
Dependent Claim 11 words
The process of claim 7 wherein said resin is polyvinyl chloride.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-05-29 1987-11-28 1988-05-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-05-29 1991-11-28 1992-05-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-05-29 1995-11-28 1996-05-29 $7700.00 Window Closed / Lapsed

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