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US4448868A Expired / Lapsed US ⏱️ 0.0 years remaining

Electrophotographic photoreceptor with hydrazone derivative

Assignee: Konica Minolta Inc
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Filing: 1983-02-04
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Granted: 1984-05-15
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Expires: 2003-02-04
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Abstract

Abstract An electrophotographic photoreceptor having formed on an electrically conductive support a light-sensitive layer containing a hydrazone derivative of formula (I) as a photoconductive material is disclosed: ##STR1## wherein Z is a divalent hydrocarbon group necessary to form in conjunction with a nitrogen atom a 5- or 6-membered nitrogen-containing heterocyclic ring condensed to the benzene ring; R 1 is an aryl group or a heterocyclic group; R 2 is a hydrogen atom, an alkyl group or an aryl group; X is a hydrogen atom, a halogen atom, an alkyl group, a substituted amino group, an alkoxy group or a cyano group; and n is an integer of 0 or 1. This hydrazone derivative exhibits great carrier transporting ability when it is incorporated in the light-sensitive layer.

Inventors

  • 👤 Shinichi Suzuki
  • 👤 Kiyoshi Sawada
  • 👤 Akira Kinoshita
  • 👤 Osamu Sasaki
  • 👤 Satoshi Goto

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 15:46
CPC Classifications
G; G03; G03G; G03G5/00; G03G5/02; G03G5/04; G03G5/06; G03G5/0622; G03G5/0624; G03G5/0635; G03G5/0637; G03G5/0627; G03G5/0629; G03G5/0644; G03G5/0661

Claims Analysis

Total Claims: 31
Claim 1
Independent Claim 103 words
An electrophotographic photoreceptor having formed on an electrically conductive support a light-sensitive layer containing a hydrazone derivative of formula (I): ##STR17## wherein Z is a divalent hydrocarbon group necessary to form in conjunction with a nitrogen atom a 5- or 6-membered nitrogen-containing heterocyclic ring condensed to the benzene ring; R 1 is an aryl group or a heterocyclic group; R 2 is a hydrogen atom, an alkyl group or an aryl group; X is a hydrogen atom, a halogen atom, an alkyl group, a substituted amino group, an alkoxy group or a cyano group; and n is an integer of 0 or 1.
Claim 2
Dependent Claim 103 words
An electrophotographic photoreceptor having formed on an electrically conductive support a light-sensitive layer containing a hydrazone derivative of formula (I): ##STR17## wherein Z is a divalent hydrocarbon group necessary to form in conjunction with a nitrogen atom a 5- or 6-membered nitrogen-containing heterocyclic ring condensed to the benzene ring; R 1 is an aryl group or a heterocyclic group; R 2 is a hydrogen atom, an alkyl group or an aryl group; X is a hydrogen atom, a halogen atom, an alkyl group, a substituted amino group, an alkoxy group or a cyano group; and n is an integer of 0 or 1.
Claim 3
Dependent Claim 39 words
A photoreceptor according to claim 1, wherein said hydrazone derivative is a compound having the following formula (II): ##STR18## wherein R 1 , R 2 , X and n each has the same meaning as defined in formula (I).
Claim 4
Dependent Claim 39 words
A photoreceptor according to claim 1, wherein said hydrazone derivative is a compound having the following formula (III): ##STR19## wherein R 1 , R 2 , X and n each has the same meaning as defined in formula (I).
Claim 5
Dependent Claim 32 words
A photoreceptor according to claim 1, which is of a function-separated type wherein the light-sensitive layer on the electrically conductive support contains both a carrier generating material and a carrier transporting material.
Claim 6
Dependent Claim 23 words
A photoreceptor according to claim 1, wherein said light-sensitive layer is an assembly of a carrier generation layer and a carrier transporting layer.
Claim 7
Dependent Claim 21 words
A photoreceptor according to claim 1, wherein said light-sensitive layer has a carrier generating material dispersed in a carrier transporting layer.
Claim 8
Dependent Claim 100 words
A photoreceptor according to claim 1, wherein R 1 in formula (I) is an aryl group selected from the group consisting of a phenyl, naphthyl and anthryl group, a heterocyclic group selected from the group consisting of a furyl, thienyl, indolyl, benzofuryl, benzothienyl and carbazolyl group, each of said aryl and heterocyclic groups being optionally substituted by a substituent selected from the group consisting of an alkyl group, an alkoxy group, a substituted amino group selected from the group consisting of a dialkylamino, diarylamino and alkylarylamino group, a phenyl group, a naphthyl group, a hydroxyl group and a halogen atom.
Claim 9
Dependent Claim 85 words
A photoreceptor according to claim 1, wherein R 2 in formula (I) is a hydrogen atom, an alkyl group, preferably having 1 to 8 carbon atoms, or an aryl group such as a phenyl or naphthyl group, each of said alkyl and aryl groups being optionally substituted by a substituent selected from the group consisting of an alkyl group, an alkoxy group, a substituted amino group selected from the group consisting of a dialkylamino, diarylamino and alkylarylamino group, a hydroxyl group and a halogen atom.
Claim 10
Dependent Claim 28 words
A photoreceptor according to claim 4, wherein one part by weight of said carrier transporting material is combined with 0.8 to 10 parts by weight of a binder.
Claim 11
Dependent Claim 29 words
A photoreceptor according to claim 6, wherein one part by weight of said carrier generating material is combined with not more than 5 parts by weight of a binder.
Claim 12
Dependent Claim 23 words
A photoreceptor according to claim 5, wherein the carrier generation layer is positioned closes to the support than the carrier transporting layer is.
Claim 13
Dependent Claim 32 words
A photoreceptor according to claim 12, which is of a function-separated type wherein the light-sensitive layer on the electrically conductive support contains both a carrier generating material and a carrier transporting material.
Claim 14
Dependent Claim 32 words
A photoreceptor according to claim 3, which is of a function-separated type wherein the light-sensitive layer on the electrically conductive support contains both a carrier generating material and a carrier transporting material.
Claim 15
Dependent Claim 23 words
A photoreceptor according to claim 2, wherein said light-sensitive layer is an assembly of a carrier generation layer and a carrier transporting layer.
Claim 16
Dependent Claim 23 words
A photoreceptor according to claim 3, wherein said light-sensitive layer is an assembly of a carrier generation layer and a carrier transporting layer.
Claim 17
Dependent Claim 21 words
A photoreceptor according to claim 2, wherein said light-sensitive layer has a carrier generating material dispersed in a carrier transporting layer.
Claim 18
Dependent Claim 21 words
A photoreceptor according to claim 3, wherein said light-sensitive layer has a carrier generating material dispersed in a carrier transporting layer.
Claim 19
Dependent Claim 101 words
A photoreceptor according to claim 2, wherein R 1 in formula (I) is an aryl group selected from the group consisting of a phenyl, naphthyl and anthryl group, or a heterocyclic group selected from the group consisting of a furyl, thienyl, indolyl, benzofuryl, benzothienyl and carbazolyl group, each of said aryl and heterocyclic groups being optionally substituted by a substituent selected from the group consisting of an alkyl group, an alkoxy group, a subsituted amino group selected from the group consisting of a dislkylamino, diarylamino and alkylarylamino group, a phenyl group, a naphthyl group, a hydroxyl group and a halogen atom.
Claim 20
Dependent Claim 101 words
A photoreceptor according to claim 3, wherein R 1 in formula (I) is an aryl group selected from the group consisting of a phenyl, naphthyl and anthryl group, or a heterocyclic group selected from the group consisting of a furyl, thienyl, indolyl, benzofuryl, benzothienyl and carbazolyl group, each of said aryl and heterocyclic groups being optionally substituted by a substituent selected from the group consisting of an alkyl group, an alkoxy group, a substituted amino group selected from the group consisting of a dislkylamino, diarylamino and alkylarylamino group, a phenyl group, a naphthyl group, a hydroxyl group and a halogen atom.
Claim 21
Dependent Claim 89 words
A photoreceptor according to claim 2, wherein R 2 in formula (I) is a hydrogen atom, an alkyl group, preferably having 1 to 8 carbon atoms, or an aryl group selected from the group consisting of a phenyl and naphthyl group, each of said alkyl and aryl groups being optionally substituted by a substituent selected from the group consisting of an alkyl group, an alkoxy group, a substituted amino group selected from the group consisting of a dialkylamino, diarylamino and alkylarylamino group, a hydroxyl group and a halogen atom.
Claim 22
Dependent Claim 89 words
A photoreceptor according to claim 3, wherein R 2 in formula (I) is a hydrogen atom, an alkyl group, preferably having 1 to 8 carbon atoms, or an aryl group selected from the group consisting of a phenyl and naphthyl group, each of said alkyl and aryl groups being optionally substituted by a substituent selected from the group consisting of an alkyl group, an alkoxy group, a substituted amino group selected from the group consisting of a dialkylamino, diarylamino and alkylarylamino group, a hydroxyl group and a halogen atom.
Claim 23
Dependent Claim 28 words
A photoreceptor according to claim 5, wherein one part by weight of said carrier transporting material is combined with 0.8 to 10 parts by weight of a binder.
Claim 24
Dependent Claim 28 words
A photoreceptor according to claim 12, wherein one part by weight of said carrier transporting material is combined with 0.8 to 10 parts by weight of a binder.
Claim 25
Dependent Claim 28 words
A photoreceptor according to claim 13, wherein one part by weight of said carrier transporting material is combined with 0.8 to 10 parts by weight of a binder.
Claim 26
Dependent Claim 28 words
A photoreceptor according to claim 14, wherein one part by weight of said carrier transporting material is combined with 0.8 to 10 parts by weight of a binder.
Claim 27
Dependent Claim 28 words
A photoreceptor according to claim 15, wherein one part by weight of said carrier transporting material is combined with 0.8 to 10 parts by weight of a binder.
Claim 28
Dependent Claim 29 words
A photoreceptor according to claim 16, wherein one part by weight of said carrier generating material is combined with not more than 5 parts by weight of a binder.
Claim 29
Dependent Claim 29 words
A photoreceptor according to claim 17, wherein one part by weight of said carrier generating material is combined with not more than 5 parts by weight of a binder.
Claim 30
Dependent Claim 23 words
A photoreceptor according to claim 14, wherein the carrier generation layer is positioned closes to the support than the carrier transporting layer is.
Claim 31
Dependent Claim 23 words
A photoreceptor according to claim 15, wherein the carrier generation layer is positioned closes to the support than the carrier transporting layer is.

References Cited (Backward Citations)

US4150987A Cited
US4278747A Cited
US4385106A Cited
JPS5758156A Cited
US4391889A Cited
US4399207A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-05-15 1987-11-14 1988-05-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-05-15 1991-11-14 1992-05-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-05-15 1995-11-14 1996-05-15 $7700.00 Window Closed / Lapsed

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