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US4448524A
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Reflective containment of electromagnetic radiation in matrix isolation thin films
Assignee: AT&T Inc
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Filing: 1981-09-11
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Granted: 1984-05-15
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Expires: 2001-09-11
Abstract
Abstract Efficient transmission of light through a matrix isolation thin film is obtained despite the fact that the index configuration of the thin film is not appropriate for classical waveguides. The light is transmitted through the film approximately parallel to the substrate, thereby permitting analysis of the thin film, stimulation of reaction within the thin film, or use of the thin film as an optical memory.
Inventors
- 👤 Louis E. Brus
- 👤 Ronald Rossetti
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 19:26
CPC Classifications
G; G01; G01N; G01N21/00; G01N21/17; G01N21/59; G01N21/55; G01N21/552; G01N21/84; G01N21/8422
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
195 words
A method comprising directing a stream of a guest-host gaseous mixture to a cold substrate upon which the mixture freezes to yield a film of the frozen gaseous mixture on the substrate; directing a beam of electromagnetic energy through the frozen film; the improvement comprising the substrate is selected from the group consisting of dielectrics having a refractive index greater than that of the frozen gaseous film, and metals, and in that the electromagnetic energy is propagated through the film along a direction substantially parallel to the substrate and wherein, prior to directing the stream of the gaseous mixture to the cold substrate upon which it freezes, a slotted structure is placed on at least one end of the substrate, a passageway, parallel to the substrate surface, being formed, and bounded, by the slot in the said structure and the substrate, the said gaseous mixture, upon freezing, forming a thin film face, which covers at least part of the passageway exit, which face is perpendicular to the substrate, such that light, directed through the passageway entrance, which is opposite to that of the thin film face, passes through the passageway and enters the thin film.
Claim 2
Independent Claim
195 words
A method comprising directing a stream of a guest-host gaseous mixture to a cold substrate upon which the mixture freezes to yield a film of the frozen gaseous mixture on the substrate; directing a beam of electromagnetic energy through the frozen film; the improvement comprising the substrate is selected from the group consisting of dielectrics having a refractive index greater than that of the frozen gaseous film, and metals, and in that the electromagnetic energy is propagated through the film along a direction substantially parallel to the substrate and wherein, prior to directing the stream of the gaseous mixture to the cold substrate upon which it freezes, a slotted structure is placed on at least one end of the substrate, a passageway, parallel to the substrate surface, being formed, and bounded, by the slot in the said structure and the substrate, the said gaseous mixture, upon freezing, forming a thin film face, which covers at least part of the passageway exit, which face is perpendicular to the substrate, such that light, directed through the passageway entrance, which is opposite to that of the thin film face, passes through the passageway and enters the thin film.
Claim 3
Dependent Claim
18 words
The method of claim 1 further comprising detecting the electromagnetic energy emitted by or transmitted by the film.
Claim 4
Dependent Claim
29 words
The method of claim 1 wherein the thin film material and the wavelength and intensity of the propagated light are such that a chemical reaction occurs in the film.
Claim 5
Independent Claim
15 words
The method of claims 2 or 3 wherein the beam of electromagnetic energy is coherent.
Claim 6
Dependent Claim
19 words
The method of claim 4 wherein the coherent electromagnetic energy has a wavelength between 1000 Angstroms and 20 microns.
Claim 7
Dependent Claim
31 words
The method of claim 1 wherein the substrate material which the thin film contacts is selected from the group consisting of sapphire, quartz, silicon, germanium, diamond, magnesium fluoride and sodium fluoride.
Claim 8
Dependent Claim
29 words
The method of claim 1 wherein the metal, i.e., material which the thin film contacts is selected from the group consisting of platinum, silver, gold, aluminum, rhodium and nickel.
Claim 9
Dependent Claim
19 words
The method of claim 1 wherein the substrate material which the thin film contacts is a non-metallic reflecting surface.
Claim 10
Independent Claim
21 words
The method of claims 6, 7, or 8 wherein the temperature of the thin film is less than 200 degrees Kelvin.
Claim 11
Dependent Claim
19 words
The method of claim 1 wherein the host material is a liquid or a vapor at 300 degrees Kelvin.
Claim 12
Dependent Claim
13 words
The method of claim 10 wherein the guest-host ratio is less than 1:1.
Claim 13
Dependent Claim
13 words
The method of claim 11 wherein the guest-host ratio is less than 1:10.
Claim 14
Dependent Claim
13 words
The method of claim 12 wherein the guest-host ratio is less than 1:100.
Claim 15
Dependent Claim
18 words
The method of claim 12 or 13 wherein the guest material consists of up to three different constituents.
Claim 16
Dependent Claim
18 words
The method of claim 1 wherein the thickness of the thin film is between 1/2 and 400 microns.
Claim 17
Dependent Claim
42 words
The method of claim 1 wherein the substrate material which the thin film contacts is a dielectric and wherein the beam of electromagnetic energy is transmitted through the thin film at an angle of less than 5 degrees relative to the substrate.
Claim 18
Dependent Claim
40 words
The method of claim 1 wherein the substrate material which the thin film contacts is a metal and wherein the beam of electromagnetic energy transmitted through the thin film at an angle less than 30 degrees relative to the substrate.
Claim 19
Dependent Claim
13 words
The method of claim 1 wherein the thin film comprises an optical memory.
References Cited (Backward Citations)
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-05-15 | 1987-11-14 | 1988-05-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-05-15 | 1991-11-14 | 1992-05-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-05-15 | 1995-11-14 | 1996-05-15 | $7700.00 | Window Closed / Lapsed |