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US4447506A Expired / Lapsed US ⏱️ 0.0 years remaining

Ternary fuel cell catalysts containing platinum, cobalt and chromium

Assignee: RTX Corp
•
Filing: 1983-01-17
•
Granted: 1984-05-08
•
Expires: 2003-01-17
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Abstract

Abstract An improved ternary noble metal-containing, alloy catalyst which has a catalytic activity for the electrochemical reduction of oxygen greater than two and one-half times that of the supported unalloyed noble metal alone. In addition, a disclosure of the method of preparing said catalyst is by intimately contacting two metallic elements with a supported noble metal, then heating this material to form the ternary alloy catalyst. This catalyst has particular utility for the electrochemical reduction of oxygen which makes it particularly useful as a cathode in acid fuel cells. The preferred embodiment of this catalyst is finely divided platinum alloyed with chromium and cobalt supported on an electrically conductive carbon-black support material.

Inventors

  • 👤 Francis J. Luczak
  • 👤 Douglas A. Landsman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 00:26
CPC Classifications
H; H01; H01M; H01M4/00; H01M4/86; H01M4/90; H01M4/92; H01M4/925; H01M4/926; H01M2004/8678; H01M2004/8689; H01M2300/00; H01M2300/0002; H01M2300/0005; H01M2300/0008; Y; Y02; Y02E; Y02E60/00; Y02E60/30; Y02E60/50

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 65 words
A fuel cell having an anode and a cathode with an electrolyte disposed therebetween, wherein the improvement comprises a ternary alloy cathode catalyst of platinum, cobalt, and chromium supported on an electrically conductive carbon-black, said catalyst having a catalytic activity for the electrochemical reduction of oxygen at least two and one-half times that of an unalloyed platinum catalyst supported on the same electrically conductive carbon-black.
Claim 2
Dependent Claim 65 words
A fuel cell having an anode and a cathode with an electrolyte disposed therebetween, wherein the improvement comprises a ternary alloy cathode catalyst of platinum, cobalt, and chromium supported on an electrically conductive carbon-black, said catalyst having a catalytic activity for the electrochemical reduction of oxygen at least two and one-half times that of an unalloyed platinum catalyst supported on the same electrically conductive carbon-black.
Claim 3
Dependent Claim 12 words
The fuel cell of claim 1 wherein the electrolyte is phosphoric acid.
Claim 4
Dependent Claim 46 words
A ternary metal alloy catalyst comprising platinum, chromium and cobalt dispersed on an electrically conductive carbon-black, wherein the catalyst has a catalytic activity for the electrochemical reduction of oxygen of at least two and one-half times that of unalloyed platinum on the same electrically conductive carbon-black.
Claim 5
Dependent Claim 46 words
A ternary metal alloy catalyst comprising platinum, chromium and cobalt dispersed on an electrically conductive carbon-black, wherein the catalyst has a catalytic activity for the electrochemical reduction of oxygen of at least two and one-half times that of unalloyed platinum on the same electrically conductive carbon-black.
Claim 6
Dependent Claim 23 words
The catalyst of claim 3 wherein the chromium is 6-12% by weight, the cobalt is 8-14% by weight and the balance is platinum.

References Cited (Backward Citations)

GB1047933A Cited
US3291753A Cited
US3440103A Cited
US3380934A Cited
US3432362A Cited
US4126934A Cited
US4127468A Cited
US4137373A Cited
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US4316944A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-05-08 1987-11-07 1988-05-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-05-08 1991-11-07 1992-05-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-05-08 1995-11-07 1996-05-08 $7700.00 Window Closed / Lapsed

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