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Two-phase thermal storage means and method

Assignee: General Electric Co
•
Filing: 1982-03-01
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Granted: 1984-05-08
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Expires: 2002-03-01
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Abstract

Abstract Latent heat is stored in a liquid storage material having a variable phase-dependent density from which material heat is subsequently removed by heat transfer with an immiscible liquid interfaced with the storage material, such that storage material at the interface is solidified resulting in the separation thereof from the interface by buoyancy forces.

Inventors

  • 👤 Russell S. Miller
  • 👤 Peter W. Dietz
  • 👤 Christopher Bray

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 18:14
CPC Classifications
F; F28; F28D; F28D20/00; F28D20/02; F28D20/025; Y; Y02; Y02E; Y02E60/00; Y02E60/14; Y10; Y10S; Y10S126/00; Y10S126/91

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 208 words
A two phase thermal storage method comprising the steps of: providing a temperature-sensitive phase transformation storage material having a phase-dependent variable density; contacting an immiscible heat transfer liquid with said storage material; storing heat in the liquid phase of said storage material by heating said heat transfer liquid to a temperature above the temperature of storage material contacting said heat transfer liquid whereby heat stored in said storage material is increased; and removing said stored heat by cooling said heat transfer liquid to a temperature below the liquid-to-solid phase-transformation temperature of said storage material whereby at least a portion of said storage material is solidified at the interface with said heat transfer fluid, and removing solidified storage material from said interface by bouyancy forces; wherein said heat transfer liquid may be cooled by circulating a quantity of heat transfer liquid from the interface with said storage material through a heat exchange relationship with a coolant and returning said quantity of liquid to said interface, and further wherein said heat transfer liquid may be heated by circulating a quantity of the heat transfer liquid from the interface with said storage material through heat exchange relationship with a source of heat and returning said quantity of liquid to said interface.
Claim 2
Dependent Claim 208 words
A two phase thermal storage method comprising the steps of: providing a temperature-sensitive phase transformation storage material having a phase-dependent variable density; contacting an immiscible heat transfer liquid with said storage material; storing heat in the liquid phase of said storage material by heating said heat transfer liquid to a temperature above the temperature of storage material contacting said heat transfer liquid whereby heat stored in said storage material is increased; and removing said stored heat by cooling said heat transfer liquid to a temperature below the liquid-to-solid phase-transformation temperature of said storage material whereby at least a portion of said storage material is solidified at the interface with said heat transfer fluid, and removing solidified storage material from said interface by bouyancy forces; wherein said heat transfer liquid may be cooled by circulating a quantity of heat transfer liquid from the interface with said storage material through a heat exchange relationship with a coolant and returning said quantity of liquid to said interface, and further wherein said heat transfer liquid may be heated by circulating a quantity of the heat transfer liquid from the interface with said storage material through heat exchange relationship with a source of heat and returning said quantity of liquid to said interface.
Claim 3
Dependent Claim 37 words
A thermal storage method as in claim 1 in which density of said storage material increases upon solidification, wherein said solidified storage material is removed downward from said interface through relatively less dense liquid phase storage material.
Claim 4
Dependent Claim 37 words
A thermal storage method as in claim 1 in which the density of said storage material decreases upon solidification, wherein said solidified storage material is removed upward from said interface through relatively denser liquid phase storage material.
Claim 5
Dependent Claim 27 words
A thermal storage method as in claim 3 wherein said storage material is water and said heat transfer liquid is a mixture of kerosene and refrigerant R-113.
Claim 6
Dependent Claim 26 words
A thermal storage method as in claim 3 wherein said storage material is paraffin (C 12 -C 14 ) and said heat transfer liquid is water.
Claim 7
Dependent Claim 21 words
A thermal storage method as in claim 3 wherein said storage material is water and said heat transfer liquid is mercury.
Claim 8
Dependent Claim 26 words
A thermal storage method as in claim 3 wherein said storage material is paraffin (C 22 -C 23 ) and said heat transfer liquid is water.
Claim 9
Dependent Claim 23 words
A thermal storage method as in claim 2 wherein said storage material is sulfur trioxide and said heat transfer liquid is petroleum oil.
Claim 10
Dependent Claim 21 words
A thermal storage method as in claim 2 wherein said storage material is naphtol and said heat transfer liquid is water.
Claim 11
Dependent Claim 165 words
A two-phase thermal storage device comprising a vessel, a temperature-sensitive phase-transformation storage material disposed in said vessel which material changes density upon transformation from a liquid to a solid phase, an immiscible heat transfer liquid interfaced with said storage material in said vessel, a means for selectively cooling said heat transfer liquid to a temperature below the liquid-to-solid phase-transformation temperature of said storage material, and a means for selectively heating said heat transfer liquid, wherein said cooling means comprises first heat exchange apparatus in thermal contact with a coolant and said heating means comprises second heat exchange apparatus in thermal communication with a source of heat, and means for controllably circulating a quantity of said heat transfer fluid from said vessel through said first heat exchange apparatus and through said second heat exchange apparatus, respectively, and returning said quantity of fluid to said vessel, whereby heat is selectively removed from and added to, respectively, said storage material at the interface with said heat transfer liquid.
Claim 12
Dependent Claim 165 words
A two-phase thermal storage device comprising a vessel, a temperature-sensitive phase-transformation storage material disposed in said vessel which material changes density upon transformation from a liquid to a solid phase, an immiscible heat transfer liquid interfaced with said storage material in said vessel, a means for selectively cooling said heat transfer liquid to a temperature below the liquid-to-solid phase-transformation temperature of said storage material, and a means for selectively heating said heat transfer liquid, wherein said cooling means comprises first heat exchange apparatus in thermal contact with a coolant and said heating means comprises second heat exchange apparatus in thermal communication with a source of heat, and means for controllably circulating a quantity of said heat transfer fluid from said vessel through said first heat exchange apparatus and through said second heat exchange apparatus, respectively, and returning said quantity of fluid to said vessel, whereby heat is selectively removed from and added to, respectively, said storage material at the interface with said heat transfer liquid.
Claim 13
Dependent Claim 35 words
A thermal storage device as in claim 10 wherein the storage material has a denser solid phase than a liquid phase, and said heat transfer liquid is less dense than said storage material liquid phase.
Claim 14
Dependent Claim 34 words
A thermal storage device as in claim 10 wherein the storage material has a denser liquid phase than a solid phase, and said heat transfer liquid is denser than said storage material liquid phase.
Claim 15
Dependent Claim 27 words
A thermal storage device as in claim 12 wherein said storage material is water and said heat transfer liquid is a mixture of kerosene and refrigerant R-113.
Claim 16
Dependent Claim 26 words
A thermal storage device as in claim 12 wherein said storage material is paraffin (C 12 -C 14 ) and said heat transfer liquid is water.
Claim 17
Dependent Claim 21 words
A thermal storage device as in claim 12 wherein said storage material is water and said heat transfer liquid is mercury.
Claim 18
Dependent Claim 26 words
A thermal storage device as in claim 12 wherein said storage material is paraffin (C 22 -C 23 ) and said heat transfer liquid is water.
Claim 19
Dependent Claim 23 words
A thermal storage device as in claim 11 wherein said storage material is sulfur trioxide and said heat transfer liquid is petroleum oil.
Claim 20
Dependent Claim 21 words
A thermal storage device as in claim 11 wherein said storage material is naphtol and said heat transfer liquid is water.

References Cited (Backward Citations)

US1969187A Cited
US4227567A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-05-08 1987-11-07 1988-05-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-05-08 1991-11-07 1992-05-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-05-08 1995-11-07 1996-05-08 $7700.00 Window Closed / Lapsed

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