US4227567A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Intermediate temperature, heat storage and retrieval system
Assignee: Kohler Co
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Filing: 1978-12-21
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Granted: 1980-10-14
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Expires: 1998-12-21
Abstract
Abstract Energy is stored by heating a salt to a temperature above its latent heat of fusion to convert the salt to a liquid state. Heat is retrieved by moving a heat transfer fluid that is immiscible with the salt and has a density less than that of the salt over the top surface of the liquid salt at such a velocity that the upper layer of the salt is emulsified with the heat transfer fluid to crystallize the salt in the upper layer. Heat is thereby exothermally surrendered to the heat transfer fluid and the crystallized salt gravitates from said top surface, thereby maintaining the top surface in a liquid state. It is preferred to move the heat transfer fluid over the top surface of the salt in either a vortex pattern, or an outward radial pattern. The heat transfer liquid is a liquid selected from the group consisting essentially of THERMINOL, CALORIA SANTOWAX, and di-butyl phthalate.
Inventors
- 👤 Norman D. Greene
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 05:26
CPC Classifications
F; F28; F28D; F28D20/00; F28D20/02; F28D20/025; Y; Y02; Y02E; Y02E60/00; Y02E60/14
Claims Analysis
Total Claims: 20
Claim 1
Independent Claim
129 words
The method of storing energy and retrieving such stored energy as heat, that includes (a) providing a liquid system that consists essentially of a salt melt lower region, an upper region of additive liquid which is immiscible with the salt melt, said liquid selected from the group which consists essentially of THERMINOL, CALORIA, SANTOWAX, and di-butyl phthalate, and an emulsion of said melt and additive liquid intermediate said upper and lower regions, (b) effecting latent heat transfer from the melt to the additive liquid within the emulsion, and transferring heat from the additive liquid, (c) maintaining active flowing movement of the emulsion to enhance said latent heat transfer, and which results in formation of salt crystals, and (d) gravitating said crystals downwardly in the melt away from the emulsion.
Claim 2
Independent Claim
129 words
The method of storing energy and retrieving such stored energy as heat, that includes (a) providing a liquid system that consists essentially of a salt melt lower region, an upper region of additive liquid which is immiscible with the salt melt, said liquid selected from the group which consists essentially of THERMINOL, CALORIA, SANTOWAX, and di-butyl phthalate, and an emulsion of said melt and additive liquid intermediate said upper and lower regions, (b) effecting latent heat transfer from the melt to the additive liquid within the emulsion, and transferring heat from the additive liquid, (c) maintaining active flowing movement of the emulsion to enhance said latent heat transfer, and which results in formation of salt crystals, and (d) gravitating said crystals downwardly in the melt away from the emulsion.
Claim 3
Dependent Claim
23 words
The method of claim 1 wherein said THERMINOL is selected from the group that consists of THERMINOL 55, THERMINOL 66, and THERMINOL 88.
Claim 4
Dependent Claim
23 words
The method of claim 1 wherein the salt is selected from the group consisting essentially of potassium hydroxide, sodium hydroxide and sodium nitrate.
Claim 5
Dependent Claim
27 words
The method of claim 1 wherein said (c) step is carried out under turbulent flow conditions in the emulsion, but which allow said step (d) crystal gravitation.
Claim 6
Dependent Claim
29 words
The method of claim 4 wherein an agitator is provided to project into the system, and including the step of operating the agitator to effect formation of the emulsion.
Claim 7
Dependent Claim
20 words
The method of claim 1 wherein said (c) step is carried out to form vortex means in the system liquid.
Claim 8
Dependent Claim
19 words
The method of claim 1 wherein said (a) step includes transferring heat into the salt to form the melt.
Claim 9
Dependent Claim
25 words
The method of claim 7 wherein said transfer of heat into the salt includes flowing hot fluid into heat transfer relation with the salt crystals.
Claim 10
Dependent Claim
28 words
The method of claim 1 wherein said heat transfer from the additive liquid is effected by flowing the additive liquid through a heat exchanger remote from the melt.
Claim 11
Dependent Claim
33 words
The method of claim 1 wherein said heat transfer from the additive liquid is effected by flowing a heat transfer fluid in heat transfer proximity with the additive liquid, above the emulsion layer.
Claim 12
Independent Claim
147 words
A system for storing energy and retrieving said stored energy as heat, comprising (a) a container, (b) a liquid system in the container, including (i) a salt melt lower region, (ii) an upper region of additive liquid which is immiscible with the salt melt, said liquid selected from the group which consists essentially of THERMINOL, CALORIA, SANTOWAX, and di-butyl phthalate, and (iii) an emulsion of said melt and additive liquid located intermediate the upper and lower regions, (c) means for transferring heat from the additive liquid, (d) means to form and maintain the emulsion in an actively moving state to enhance latent heat transfer from the melt to the additive liquid within the emulsion, which results in formation of salt crystals, (e) there being a zone below said emulsion to which said crystals gravitate, and there being means to transfer heat to the crystals in said zone.
Claim 13
Independent Claim
147 words
A system for storing energy and retrieving said stored energy as heat, comprising (a) a container, (b) a liquid system in the container, including (i) a salt melt lower region, (ii) an upper region of additive liquid which is immiscible with the salt melt, said liquid selected from the group which consists essentially of THERMINOL, CALORIA, SANTOWAX, and di-butyl phthalate, and (iii) an emulsion of said melt and additive liquid located intermediate the upper and lower regions, (c) means for transferring heat from the additive liquid, (d) means to form and maintain the emulsion in an actively moving state to enhance latent heat transfer from the melt to the additive liquid within the emulsion, which results in formation of salt crystals, (e) there being a zone below said emulsion to which said crystals gravitate, and there being means to transfer heat to the crystals in said zone.
Claim 14
Dependent Claim
23 words
The system of claim 11 wherein said THERMINOL is selected from the group that consists of THERMINOL 55, THERMINOL 66 and THERMINOL 88.
Claim 15
Dependent Claim
24 words
The system of claim 11 wherein the salt is selected from the group that consists essentially of potassium hydroxide, sodium hydroxide and sodium nitrate.
Claim 16
Dependent Claim
35 words
The system of claim 11 including means communicating with the interior of the container for effecting said actively moving state of the emulsion under turbulent flow conditions, but which allows said gravitation of the crystals.
Claim 17
Dependent Claim
34 words
The system of claim 14 wherein said means for effecting said actively moving state of the emulsion layer includes a rotating rotor, and said emulsion layer forms vortex means in response to rotor rotation.
Claim 18
Dependent Claim
20 words
The system of claim 11 wherein said means to transfer heat to the crystals includes ducting containing flowing hot fluid.
Claim 19
Dependent Claim
43 words
The system of claim 11 wherein said means for transferring heat from the additive liquid includes a heat exchanger remote from the melt, and ducting communicating with said additive in the container and with said heat exchanger for circulating the additive liquid therebetween.
Claim 20
Dependent Claim
29 words
The system of claim 11 wherein said means for transferring heat from the additive liquid includes ducting flowing an auxiliary fluid in heat receiving relation with the additive liquid.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-10-14 | 1984-04-14 | 1984-10-14 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-10-14 | 1988-04-14 | 1988-10-14 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-10-14 | 1992-04-14 | 1992-10-14 | $7700.00 | Window Closed / Lapsed |