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US4440705A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for the preparation of cellular and non-cellular polyurethane elastomers

Assignee: BASF SE
•
Filing: 1982-07-01
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Granted: 1984-04-03
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Expires: 2002-07-01
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Abstract

Abstract A process for the preparation of optionally cellular and non-cellular polyurethane elastomers, preferably by reaction injection molding, organic polyisocyanates, polyether polyols based on polyoxyalkylene polyether polyols with terminal hydroxyethylene groups and an ethoxylation degree of 1 to 13, having a content of primary hydroxyl groups at the corresponding degree of ethoxylation as the value of curve A to 100 percent with curve A describing the dependency of the primary hydroxyl group content upon the degree of ethoxylation are reacted with chain extenders and/or cross-linking agents in the presence of catalysts as well as optionally blowing agents, auxiliaries and additives.

Inventors

  • 👤 Dietmar Nissen
  • 👤 Wolfgang Straehle
  • 👤 Matthias Marx

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 07:34
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/48; C08G18/4833; C08G18/4837; C08G18/4841; C08G18/487; C08G18/65; C08G18/66; C08G18/6666; C08G18/667; C08G2120/00; Y; Y10; Y10S; Y10S521/00; Y10S521/914

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 193 words
A process for the preparation of cellular or non-cellular polyurethane elastomers by reacting organic polyisocyanates, polyether polyols, chain extenders and/or cross-linking agents in the presence of catalysts as well as blowing agents, auxiliaries and additives, wherein polyoxyalkylene polyether polyols with terminal hydroxyethylene groups are used as the polyether polyols said polyether polyols prepared by reacting initiator compounds having molecular weights of 18 to 342 and containing from 2 to 8 Zerewitinoff active hydrogen atoms in the presence of alkaline catalysts selected from the group consisting of alkali metal alkoxides, alkali metal hydroxides and alkaline earth metal hydroxides comprising (a) initially reacting alkylene oxides containing more than 2 carbon atoms in the presence of from 0.01 to 0.25 mole of said catalyst per equivalent of said initiator compound, (b) further reacting the alkylene oxides containing more than 2 carbon atoms in the presence of from 0.10 to 1.0 mole of said catalyst per equivalent of said initiator compound, (c) further reacting the alkylene oxide adduct of step (b) with ethylene oxide at a maximum concentration of 30 weight percent based on the weight of the crude polyether polyol, and (d) removing the alkaline catalyst.
Claim 2
Dependent Claim 193 words
A process for the preparation of cellular or non-cellular polyurethane elastomers by reacting organic polyisocyanates, polyether polyols, chain extenders and/or cross-linking agents in the presence of catalysts as well as blowing agents, auxiliaries and additives, wherein polyoxyalkylene polyether polyols with terminal hydroxyethylene groups are used as the polyether polyols said polyether polyols prepared by reacting initiator compounds having molecular weights of 18 to 342 and containing from 2 to 8 Zerewitinoff active hydrogen atoms in the presence of alkaline catalysts selected from the group consisting of alkali metal alkoxides, alkali metal hydroxides and alkaline earth metal hydroxides comprising (a) initially reacting alkylene oxides containing more than 2 carbon atoms in the presence of from 0.01 to 0.25 mole of said catalyst per equivalent of said initiator compound, (b) further reacting the alkylene oxides containing more than 2 carbon atoms in the presence of from 0.10 to 1.0 mole of said catalyst per equivalent of said initiator compound, (c) further reacting the alkylene oxide adduct of step (b) with ethylene oxide at a maximum concentration of 30 weight percent based on the weight of the crude polyether polyol, and (d) removing the alkaline catalyst.
Claim 3
Dependent Claim 17 words
The process of claim 1, wherein the polyoxyalkylene polyether polyols have ethoxylation degrees of 2 to 8.
Claim 4
Dependent Claim 27 words
The process of claim 1, wherein the components for the manufacture of the cellular and non-cellular polyurethane elastomers are prepared in accordance with the reaction molding technique.

References Cited (Backward Citations)

US3887505A Cited
US4272618A Cited
US4243760A Cited
US4273884A Cited
US4365025A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-04-03 1987-10-03 1988-04-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-04-03 1991-10-03 1992-04-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-04-03 1995-10-03 1996-04-03 $7700.00 Window Closed / Lapsed

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