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US4272618A Expired / Lapsed US ⏱️ 0.0 years remaining

Heat stable reaction injection molded elastomers

Assignee: Huntsman Corp
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Filing: 1979-04-30
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Granted: 1981-06-09
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Expires: 1999-04-30
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Abstract

Abstract The invention is a reaction injection molded polyurethane of improved properties comprising the cured reaction product of a high molecular weight polyhydric polyether, a low molecular weight active hydrogen containing compound of at least two functionality and a polyisocyanate. The reaction product is cured by subjecting it to an ambient temperature of from about 290°-425° F. for a time sufficient to achieve an improvement in properties. The invention is also a method for making such polyurethanes.

Inventors

  • 👤 Richard J. G. Dominguez
  • 👤 Doris M. Rice

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 14:49
CPC Classifications
C; C08; C08J; C08J3/00; C08J3/24; C08J3/244; B; B29; B29C; B29C67/00; B29C67/24; B29C67/246; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/65; C08G18/66; C08G18/6603; C08G18/82; B29C44/00; B29K; B29K2075/00; C08J2375/00; C08J2375/04; Y; Y10; Y10S; Y10S521/00; Y10S521/914; Y10S521/918

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 113 words
A reaction injection molded polyurethane elastomer having significantly improved properties comprising a cured reaction product of polyhydric polyethers of above about 500 molecular weight, a chain-extender and an aromatic polyisocyanate, said curing comprising subjecting said reaction product to an ambient temperature of from about 290° F. to 425° F. for a length of time sufficient to achieve an improvement in properties and wherein the polyisocyanate and chain-extender are chosen from products which yield an isocyanate chain-extender reaction product with a glass transition temperature of above about 325° F. and wherein the polyol is chosen from those products which do not significantly adversely affect the glass transition temperature of the isocyanate chain-extender reaction product.
Claim 2
Dependent Claim 113 words
A reaction injection molded polyurethane elastomer having significantly improved properties comprising a cured reaction product of polyhydric polyethers of above about 500 molecular weight, a chain-extender and an aromatic polyisocyanate, said curing comprising subjecting said reaction product to an ambient temperature of from about 290° F. to 425° F. for a length of time sufficient to achieve an improvement in properties and wherein the polyisocyanate and chain-extender are chosen from products which yield an isocyanate chain-extender reaction product with a glass transition temperature of above about 325° F. and wherein the polyol is chosen from those products which do not significantly adversely affect the glass transition temperature of the isocyanate chain-extender reaction product.
Claim 3
Dependent Claim 11 words
The polyurethane of claim 1 wherein said chain-extender comprises ethylene glycol.
Claim 4
Dependent Claim 13 words
A polyurethane product of claim 1 wherein said aromatic polyisocyanate is 4,4'-diphenylmethane diisocyanate.
Claim 5
Dependent Claim 33 words
The polyurethane of claim 1 wherein said polyol is a diol or triol having an equivalent weight of from about 1000 to about 3000 and contains at least about 50% primary hydroxyl groups.
Claim 6
Dependent Claim 18 words
The polyurethane of claim 1 wherein said polyol is a polyether polyol of above about 4000 molecular weight.
Claim 7
Dependent Claim 113 words
A reaction injection molded polyurethane elastomer having significantly improved properties comprising a cured reaction product of polyhydric polyethers of above about 500 molecular weight, a chain-extender and an aromatic polyisocyanate, said curing comprising subjecting said reaction product to an ambient temperature of from about 310° F. to 350° F. for a length of time sufficient to achieve an improvement in properites and wherein the polyisocyanate and chain-extender are chosen from products which yield an isocyanate chain-extender reaction product with a glass transition temperature of above about 325° F. and wherein the polyol is chosen from those products which do not significantly adversely affect the glass transition temperature of the isocyanate chain-extender reaction product.
Claim 8
Dependent Claim 113 words
A reaction injection molded polyurethane elastomer having significantly improved properties comprising a cured reaction product of polyhydric polyethers of above about 500 molecular weight, a chain-extender and an aromatic polyisocyanate, said curing comprising subjecting said reaction product to an ambient temperature of from about 310° F. to 350° F. for a length of time sufficient to achieve an improvement in properites and wherein the polyisocyanate and chain-extender are chosen from products which yield an isocyanate chain-extender reaction product with a glass transition temperature of above about 325° F. and wherein the polyol is chosen from those products which do not significantly adversely affect the glass transition temperature of the isocyanate chain-extender reaction product.
Claim 9
Dependent Claim 11 words
The polyurethane of claim 6 wherein said chain-extender comprises ethylene glycol.
Claim 10
Dependent Claim 13 words
A polyurethane product of claim 6 wherein said aromatic polyisocyanate is 4,4'-diphenylmethane diisocyanate.
Claim 11
Dependent Claim 33 words
The polyurethane of claim 6 wherein said polyol is a diol or triol having an equivalent weight of from about 1000 to about 3000 and contains at least about 50% primary hydroxyl groups.
Claim 12
Dependent Claim 18 words
The polyurethane of claim 6 wherein said polyol is a polyether polyol of above about 4000 molecular weight.

References Cited (Backward Citations)

GB1004924A Cited
US3362979A Cited
US3394164A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-06-08 1984-12-08 1985-06-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-06-08 1988-12-08 1989-06-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-06-08 1992-12-08 1993-06-09 $7700.00 Window Closed / Lapsed

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