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Lubricating oil ashless dispersant and lubricating oils containing same

Assignee: Ethyl Corp
•
Filing: 1982-02-19
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Granted: 1984-04-03
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Expires: 2002-02-19
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Abstract

Abstract A lubricating oil dispersant is made by grafting an alkyl methacrylate or acrylate and maleic anhydride onto a Bright Stock mineral oil backbone using a free radical generating catalyst and then reacting the product with an amine to form amide or imide groups.

Inventors

  • 👤 Jackson C. Chen
  • 👤 Marguerite S. Baylerian
  • 👤 Bryan T. Davis
  • 👤 Ellis B. Rifkin

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 09:34
CPC Classifications
C; C10; C10M; C10M159/00; C10M159/12; C10M129/00; C10M129/02; C10M129/26; C10M129/28; C10M129/30; C10M129/34; C10M129/68; C10M129/70; C10M133/00; C10M133/02; C10M159/02; C10M159/04; C10M2203/00; C10M2203/10; C10M2203/102; C10M2203/104; C10M2203/106; C10M2203/108; C10M2207/00; C10M2207/10; C10M2207/12; C10M2207/121; C10M2207/123; C10M2207/28; C10M2207/281; C10M2207/284; C10M2215/00; C10M2215/02; C10M2215/04; C10M2215/22; C10M2215/221; C10M2215/225; C10M2215/226; C10M2215/24; C10M2215/26; C10M2215/30; C10M2217/00; C10M2217/02; C10M2217/024; C10M2217/028; C10M2217/04; C10M2217/046; C10M2217/06; C10M2227/00

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 157 words
An ashless dispersant suitable for use in lubricating oil, said dispersant being made by a process comprising (1) heating a mixture of reactants consisting essentially of 100 parts by weight of a Bright Stock mineral oil, about 1-25 parts by weight of a C 1-20 alkyl acrylate or methacrylate and about 1-25 parts by weight of maleic anhydride in the presence of a free radical-generating catalyst at a temperature high enough to form free radicals up to about 250° C. to form a succinic grafted intermediate, and (2) reacting said intermediate with an amine containing 1-30 carbon atoms and 1-6 amine groups, at least one of said amine groups being a primary or secondary amine group, the amount of said amine being sufficient to provide at least one primary or secondary amine group for each grafted succinic group at a temperature high enough to cause the formation of succinamide or succinimide groups up to about 250° C.
Claim 2
Dependent Claim 157 words
An ashless dispersant suitable for use in lubricating oil, said dispersant being made by a process comprising (1) heating a mixture of reactants consisting essentially of 100 parts by weight of a Bright Stock mineral oil, about 1-25 parts by weight of a C 1-20 alkyl acrylate or methacrylate and about 1-25 parts by weight of maleic anhydride in the presence of a free radical-generating catalyst at a temperature high enough to form free radicals up to about 250° C. to form a succinic grafted intermediate, and (2) reacting said intermediate with an amine containing 1-30 carbon atoms and 1-6 amine groups, at least one of said amine groups being a primary or secondary amine group, the amount of said amine being sufficient to provide at least one primary or secondary amine group for each grafted succinic group at a temperature high enough to cause the formation of succinamide or succinimide groups up to about 250° C.
Claim 3
Dependent Claim 19 words
An ashless dispersant of claim 1 wherein said acrylate or methacrylate is a C 1 -C 20 alkyl methacrylate.
Claim 4
Dependent Claim 15 words
An ashless dispersant of claim 2 wherein said free radical generating catalyst is a peroxide.
Claim 5
Dependent Claim 13 words
An ashless dispersant of claim 2 wherein said alkyl methacrylate is methyl methacrylate.
Claim 6
Dependent Claim 36 words
An ashless dispersant of claim 1 wherein said amine is an alkylenepolyamine having the formula H.sub.2 N--R--NH).sub.n H wherein R is a divalent hydrocarbon group containing 2-3 carbon atoms and n is an integer from 1-10.
Claim 7
Dependent Claim 15 words
An ashless dispersant of claim 5 wherein said acrylate is a C 1-20 alkyl methacrylate.
Claim 8
Dependent Claim 15 words
An ashless dispersant of claim 6 wherein said C 1-20 alkyl methacrylate is methyl methacrylate.
Claim 9
Dependent Claim 14 words
An ashless dispersant of claim 7 wherein said free radical-generating catalyst is a peroxide.
Claim 10
Dependent Claim 12 words
An ashless dispersant of claim 8 wherein said peroxide is di-tert-butyl peroxide.
Claim 11
Dependent Claim 23 words
A composition comprising a major amount of an oil of lubricating viscosity and a dispersing amount of an ashless dispersant of claim 1.
Claim 12
Dependent Claim 16 words
A composition of claim 10 wherein said acrylate or methacrylate is a C 1-20 alkyl methacrylate.
Claim 13
Dependent Claim 36 words
A composition of claim 11 wherein said amine is an alkylene polyamine having the structure H.sub.2 N--R--NH).sub.n H wherein R is a divalent hydrocarbon group containing 2-3 carbon atoms and n is an integer from 1-10.
Claim 14
Dependent Claim 12 words
A composition of claim 12 wherein said alkyl methacrylate is methyl methacrylate.
Claim 15
Dependent Claim 13 words
A composition of claim 13 wherein said free radical-generating catalyst is a peroxide.
Claim 16
Dependent Claim 11 words
A composition of claim 14 wherein said peroxide is di-tert-butyl peroxide.
Claim 17
Dependent Claim 31 words
An ashless dispersant of claim 1 wherein in said process there are about 1-15 parts by weight of a C 1 10 alkyl acrylate or methacrylate in said mixture of reactants.
Claim 18
Dependent Claim 22 words
An ashless dispersant of claim 1 wherein in said process the weight ratio of Bright Stock:maleic anhydride:alkyl methacrylate or acrylate is 100:7-20:5-15.
Claim 19
Dependent Claim 28 words
An ashless dispersant of claim 2 wherein in said process said alkyl methacrylate is methyl methacrylate and the weight ratio of Bright Stock:maleic anhydride:methyl methacrylate is about 100:10-15:5-10.
Claim 20
Dependent Claim 34 words
An ashless dispersant of claim 5 wherein in said process said alkylenepolyamine is a mixture of ethylene polyamines in which n ranges from 3 to 7 and has an average value of about 4-6.
Claim 21
Dependent Claim 53 words
A composition of claim 10 wherein said amine in said process is a mixture of ethylene polyamines having the structure H.sub.2 N--R--NH).sub.n H wherein R is a divalent hydrocarbon group containing 2 carbon atoms and n is an integer that ranges from 3 to 7 and has an average value of about 4-6.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-04-03 1987-10-03 1988-04-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-04-03 1991-10-03 1992-04-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-04-03 1995-10-03 1996-04-03 $7700.00 Window Closed / Lapsed

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