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US4434147A Expired / Lapsed US ⏱️ 0.0 years remaining

Simultaneous sulfur oxide and nitrogen oxide control in FCC units using cracking catalyst fines with ammonia injection

Assignee: Chevron USA Inc
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Filing: 1982-06-10
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Granted: 1984-02-28
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Expires: 2002-06-10
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Abstract

Abstract Sulfur oxide and nitrogen oxide control by use of a sulfur sorbent and sulfur dioxide oxidation promoter in the regenerator and downstream removal of nitrogen oxides by selective catalytic reduction using ammonia injection and trapped cracking catalyst fines.

Inventors

  • 👤 William L. Dimpfl
  • 👤 William A. Blanton

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 17:48
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/74; B01D53/86; B01D53/8621; B01D53/8625; C; C10; C10G; C10G11/00; C10G11/02; C10G11/04; C10G11/05; C10G11/14; C10G11/18; C10G11/182

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 164 words
A process for lowering the amount of nitrogen oxides in a flue gas from a regenerator of a fluid catalytic cracking unit in which the circulating inventory of the unit contains at least a particulate cracking catalyst containing at least 20% alumina, a sulfur oxide sorbent, and a sulfur dioxide oxidation promoter, including the steps of: (a) lowering the temperature of the flue gas to at least about 850° F.; (b) mixing sufficient ammonia or an ammonia generating compound with the flue gas to achieve the desired reduction of said nitrogen oxide; (c) passing the flue gas in the presence of oxygen through means for collecting and supporting cracking catalyst fines entrained in the flue gas; and (d) controlling the temperature of the flue gas as it passes through said collecting and supporting means to between about 350° F. and about 850° F., whereby the nitrogen oxide in flue gas is reduced as it contacts the supported catalyst in the collecting and supporting means.
Claim 2
Dependent Claim 164 words
A process for lowering the amount of nitrogen oxides in a flue gas from a regenerator of a fluid catalytic cracking unit in which the circulating inventory of the unit contains at least a particulate cracking catalyst containing at least 20% alumina, a sulfur oxide sorbent, and a sulfur dioxide oxidation promoter, including the steps of: (a) lowering the temperature of the flue gas to at least about 850° F.; (b) mixing sufficient ammonia or an ammonia generating compound with the flue gas to achieve the desired reduction of said nitrogen oxide; (c) passing the flue gas in the presence of oxygen through means for collecting and supporting cracking catalyst fines entrained in the flue gas; and (d) controlling the temperature of the flue gas as it passes through said collecting and supporting means to between about 350° F. and about 850° F., whereby the nitrogen oxide in flue gas is reduced as it contacts the supported catalyst in the collecting and supporting means.
Claim 3
Dependent Claim 21 words
The process of claim 1 wherein the temperature of the flue gas is controlled to between 400° F. and 700° F.
Claim 4
Dependent Claim 24 words
The process of claim 1 wherein the contact efficiency between the flue gas and the collecting and supporting means is at least 2 sec/cm.
Claim 5
Dependent Claim 19 words
The process of claim 3 wherein the contact efficiency is in the range of from 3 to 11 sec/cm.
Claim 6
Dependent Claim 15 words
The process of claim 1 wherein the collecting and contacting means is an electrostatic precipitator.
Claim 7
Dependent Claim 13 words
The process of claim 1 wherein the sulfur dioxide oxidation promoter is platinum.
Claim 8
Dependent Claim 22 words
The process of claim 1 wherein the cracking catalyst contains at least 40% alumina and the sulfur oxide sorbent is reactive alumina.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-02-27 1987-08-29 1988-02-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-02-27 1991-08-29 1992-02-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-02-27 1995-08-29 1996-02-28 $7700.00 Window Closed / Lapsed

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