US4075283A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Selective removal of nitrogen oxides from waste gases containing sulfur oxides
Assignee: Sumitomo Chemical Co Ltd
•
Filing: 1974-07-25
•
Granted: 1978-02-21
•
Expires: 1994-07-25
Abstract
Abstract A process for the selective removal of nitrogen oxides from waste gases containing sulfur oxides as well as nitrogen oxides, which comprises contacting the waste gases with a catalyst comprising active metal oxides consisting of vanadium oxide and at least one of molybdenum oxide and tungsten oxide as a catalytically active component and alpha -alumina having a specific surface area of 0.3 to 12 m2/g and a pore volume of 0.1 cm3/g or more as a carrier wherein the atomic ratio of the vanadium, molybdenum, tungsten and aluminum contained in the carrier alumina is V12-x-yMoxWyAlz WHEREIN 0</=X</=8, 0</=Y</=5, 0.3</=X + Y</=8 AND 40</=Z</=480, IN THE PRESENCE OF AMMONIA OF 0.3 TO 4 MOL ON THE BASIS OF 1 MOL OF NITROGEN OXIDES CONTAINED IN THE WASTE GASES AT A TEMPERATURE OF 150 DEG TO 700 DEG C.
Inventors
- 👤 Tatsuo Shiraishi
- 👤 Shinkichi Shimizu
- 👤 Tadashi Shindo
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 22:39
CPC Classifications
B; B01; B01J; B01J23/00; B01J23/16; B01J23/24; B01D; B01D53/00; B01D53/34; B01D53/74; B01D53/86; B01D53/8621; B01D53/8625; B01D53/8628
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
219 words
A process for the selective removal of nitrogen oxides from waste gases containing 20 ppm or more in gas volume of sulfur oxides a portion of which is sulfur trioxide and 1,500 ppm or less of nitrogen oxides, which comprisescontacting said waste gases with ammonia in the amount of 0.3 to 4 moles of ammonia per 1 mole of nitrogen oxides contained in said waste gases in the presence of a catalyst consisting essentially of metal oxides consisting of vanadium oxide and at least one member selected from the group consisting of molybdenum oxide and tungsten oxide as the active component for the reduction of nitrogen oxides with ammonia and α-alumina having a specific surface area of 0.3 to 12 m 2 /g and a pore volume of 0.1 cm 3 /g or more as a carrier wherein the atomic ratio of the vanadium, molybdenum, tungsten and aluminum contained in the carrier alumina is: V.sub.12-x-y MO.sub.x W.sub.y Al.sub.z wherein 0 ≦ x ≦ 8, 0 ≦ y ≦ 5, 0.3 ≦ x + y ≦ 8 and 40 ≦ z ≦ 480, at a temperature of 150° to 700° C. and at a space velocity of 2,000 to 100,000 hr -1 , said catalyst having the property of resisting deterioration by the sulfur oxides contained in said waste gases.
Claim 2
Dependent Claim
219 words
A process for the selective removal of nitrogen oxides from waste gases containing 20 ppm or more in gas volume of sulfur oxides a portion of which is sulfur trioxide and 1,500 ppm or less of nitrogen oxides, which comprisescontacting said waste gases with ammonia in the amount of 0.3 to 4 moles of ammonia per 1 mole of nitrogen oxides contained in said waste gases in the presence of a catalyst consisting essentially of metal oxides consisting of vanadium oxide and at least one member selected from the group consisting of molybdenum oxide and tungsten oxide as the active component for the reduction of nitrogen oxides with ammonia and α-alumina having a specific surface area of 0.3 to 12 m 2 /g and a pore volume of 0.1 cm 3 /g or more as a carrier wherein the atomic ratio of the vanadium, molybdenum, tungsten and aluminum contained in the carrier alumina is: V.sub.12-x-y MO.sub.x W.sub.y Al.sub.z wherein 0 ≦ x ≦ 8, 0 ≦ y ≦ 5, 0.3 ≦ x + y ≦ 8 and 40 ≦ z ≦ 480, at a temperature of 150° to 700° C. and at a space velocity of 2,000 to 100,000 hr -1 , said catalyst having the property of resisting deterioration by the sulfur oxides contained in said waste gases.
Claim 3
Dependent Claim
40 words
The process according to claim 1, wherein the atomic ratio of the vanadium, molybdenum, tungsten and aluminum is 0 ≦ x ≦ 5, 0 ≦ y ≦ 3, 1 ≦x + y ≦ 5 and 60 ≦ z ≦ 360.
Claim 4
Dependent Claim
37 words
The process according to claim 1, wherein the specific surface area is in the range of 0.6 to 10 m 2 /g and the pore volume is in the range of 0.2 to 0.8 cm 3 /g.
Claim 5
Dependent Claim
28 words
The process according to claim 1, wherein the amount of the ammonia is in the range of 0.7 to 3 moles per 1 mole of the nitrogen oxides.
Claim 6
Dependent Claim
29 words
The process according to claim 1, wherein the contact of the gases with the catalyst is carried out at a temperature in the range of 200° to 400° C.
Claim 7
Dependent Claim
21 words
The process according to claim 1, wherein the space velocity is in the range of 4,000 to 30,000 hr -1 .
Claim 8
Dependent Claim
213 words
A process for the selective removal of nitrogen oxides from waste gases containing 20 ppm or more in gas volume of sulfur oxides and 1,500 ppm or less of nitrogen oxides, which comprises contacting said waste gases with ammonia in the amount of 0.3 to 4 moles of ammonia per 1 mole of nitrogen oxides contained in said waste gases in the presence of a catalyst consisting essentially of metal oxides consisting of vanadium oxide and at least one member selected from the group consisting of molybdenum oxide and tungsten oxide as the active component for the reduction of nitrogen oxides with ammonia and α-alumina having a specific surface area of 0.3 to 12 m 2 /g and a pore volume of 0.1 cm 3 /g or more as a carrier wherein the atomic ratio of the vanadium, molybdenum, tungsten and aluminum contained in the carrier alumina is: V.sub.12-x-y MO.sub.x W.sub.y Al.sub.z wherein 0 < x ≦ 8, 0 < y ≦ 5, 0.3 ≦ x + y ≦ 8 and 40 ≦ z ≦ 480, at a temperature of 150° to 700° C, and at a space velocity of 2,000 to 100,000 hr -1 , said catalyst having the property of resisting deterioration by the sulfur oxides contained in said waste gases.
Claim 9
Dependent Claim
213 words
A process for the selective removal of nitrogen oxides from waste gases containing 20 ppm or more in gas volume of sulfur oxides and 1,500 ppm or less of nitrogen oxides, which comprises contacting said waste gases with ammonia in the amount of 0.3 to 4 moles of ammonia per 1 mole of nitrogen oxides contained in said waste gases in the presence of a catalyst consisting essentially of metal oxides consisting of vanadium oxide and at least one member selected from the group consisting of molybdenum oxide and tungsten oxide as the active component for the reduction of nitrogen oxides with ammonia and α-alumina having a specific surface area of 0.3 to 12 m 2 /g and a pore volume of 0.1 cm 3 /g or more as a carrier wherein the atomic ratio of the vanadium, molybdenum, tungsten and aluminum contained in the carrier alumina is: V.sub.12-x-y MO.sub.x W.sub.y Al.sub.z wherein 0 < x ≦ 8, 0 < y ≦ 5, 0.3 ≦ x + y ≦ 8 and 40 ≦ z ≦ 480, at a temperature of 150° to 700° C, and at a space velocity of 2,000 to 100,000 hr -1 , said catalyst having the property of resisting deterioration by the sulfur oxides contained in said waste gases.
Claim 10
Dependent Claim
33 words
The process according to claim 1, wherein the specific surface area of said alumina is 0.6 to 10 m 2 /g and the pore volume thereof is 0.2 to 0.8 cm 3 /g.
Claim 11
Dependent Claim
26 words
The process according to claim 1, wherein the amount of the ammonia employed is from 0.7 to 3 moles per 1 mole of the nitrogen oxides.
Claim 12
Dependent Claim
27 words
The process according to claim 1, wherein the contact of the gases with the catalyst is carried out at a temperature of from 200° to 400° C.
Claim 13
Dependent Claim
21 words
The process according to claim 1, wherein the space velocity is in the range from 4,000 to 30,000 hr -1 .
References Cited (Backward Citations)
US3005831A
Cited
US2885409A
Cited
US3328115A
Cited
US3397154A
Cited
US3279884A
Cited
US3701718A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-02-20 | 1981-08-22 | 1982-02-21 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-02-20 | 1985-08-22 | 1986-02-21 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-02-20 | 1989-08-22 | 1990-02-21 | $7700.00 | Window Closed / Lapsed |