US4433073A
Expired / Lapsed
US
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Olefinic polymer composition containing inorganic filler
Assignee: Mitsubishi Chemical Corp
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Filing: 1981-07-13
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Granted: 1984-02-21
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Expires: 2001-07-13
Abstract
Abstract A high impact olefinic polymer composition comprising a continuous matrix of a thermoplastic olefinic polymer, a dispersed phase of an impact absorbing polymer or its composite dispersed in the matrix, and an inorganic filler having a smaller particle diameter than the dispersed phase and filled in said polymer or its composite constituting the dispersed phase.
Inventors
- 👤 Hironari Sano
- 👤 Hiroshi Yui
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 07:28
CPC Classifications
C; C08; C08L; C08L21/00; C08L23/00; C08L23/02
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
500 words
A high impact olefinic polymer composition comprising (1) a continuous matrix of a crystalline olefinic polymer which is selected from a crystalline homopolymer of ethylene or propylene, and a crystalline copolymer consisting essentially of a major proportion of at least one monomer selected from the group consisting of ethylene and propylene with a minor proportion of another ethylenically unsaturated monomer, (2) a dispersed phase of an impact absorbing rubbery polymer component or its composite dispersed in the matrix, (3) a finely divided inorganic filler having a particle diameter less than 2 microns and smaller than that of the dispersed phase, said inorganic filler being filled substantially entirely in said dispersed phase, (4) said dispersed phase being selected from the group of the following types I-IV: I. a dispersed phase consisting of (A') a reactive derivative of a crystalline olefinic polymer which cannot be uniformly mixed with the olefinic polymer forming the matrix, or (B) a composition composed of a crystalline olefinic polymer (A) and the reactive derivative of the crystalline olefinic polymer (A'), said (A') or (B) being surrounded by (C) an impact absorbing rubbery polymer, and said inorganic filler (3) being filled in said (A) or (B); II. a dispersed phase consisting of (C') a reactive derivative of an impact absorbing rubbery polymer (C), or (D) a composition composed of the rubbery polymer (C) and the reactive derivative of the rubbery polymer (C'), and said inorganic filler (3) being filled in the component (C') or (D), III. a dispersed phase consisting of (A) a crystalline olefinic polymer which cannot be uniformly mixed with the olefinic polymer forming the matrix, said (A) being surrounded by either (C') a reactive derivative of an impact absorbing rubbery polymer or (D) a composition composed of the rubbery polymer (C) and the reactive derivative of the rubbery polymer (C'), and said inorganic filler (3) being filled in said component (C') or (D), and IV. a dispersed phase consisting of (A') a reactive derivative of a crystalline olefinic polymer which cannot be uniformly mixed with olefinic polymer forming the matrix, or (B) a composition composed of a crystalline olefinic polymer (A) and the reactive derivative of the crystalline olefinic polymer (A'), said (A') or (B) being surrounded by either (C') a reactive derivative of an impact absorbing rubbery polymer, or (D) a composition composed of the rubbery polymer (C) and the reactive derivative of the rubbery polymer (C') and said inorganic filler (3) being filled in both (A') or (B) and (C') or (D), and (5) said impact absorbing rubbery polymer (C) being an ethylene/propylene copolymer rubber, an ethylene/propylene/nonconjugated diene terpolymer, an ethylene/butene copolymer rubber, a styrene/conjugated diene copolymer, or a polydiolefin, and (6) said reactive derivative of an impact absorbing rubbery polymer having hydrophillic groups introduced in the impact absorbing rubbery polymer, and (7) said reactive derivative of a crystalline olefinic polymer having hydrophillic groups introduced in the crystalline olefinic polymer which cannot be uniformly mixed with the crystalline olefinic polymer forming the matrix.
Claim 2
Dependent Claim
500 words
A high impact olefinic polymer composition comprising (1) a continuous matrix of a crystalline olefinic polymer which is selected from a crystalline homopolymer of ethylene or propylene, and a crystalline copolymer consisting essentially of a major proportion of at least one monomer selected from the group consisting of ethylene and propylene with a minor proportion of another ethylenically unsaturated monomer, (2) a dispersed phase of an impact absorbing rubbery polymer component or its composite dispersed in the matrix, (3) a finely divided inorganic filler having a particle diameter less than 2 microns and smaller than that of the dispersed phase, said inorganic filler being filled substantially entirely in said dispersed phase, (4) said dispersed phase being selected from the group of the following types I-IV: I. a dispersed phase consisting of (A') a reactive derivative of a crystalline olefinic polymer which cannot be uniformly mixed with the olefinic polymer forming the matrix, or (B) a composition composed of a crystalline olefinic polymer (A) and the reactive derivative of the crystalline olefinic polymer (A'), said (A') or (B) being surrounded by (C) an impact absorbing rubbery polymer, and said inorganic filler (3) being filled in said (A) or (B); II. a dispersed phase consisting of (C') a reactive derivative of an impact absorbing rubbery polymer (C), or (D) a composition composed of the rubbery polymer (C) and the reactive derivative of the rubbery polymer (C'), and said inorganic filler (3) being filled in the component (C') or (D), III. a dispersed phase consisting of (A) a crystalline olefinic polymer which cannot be uniformly mixed with the olefinic polymer forming the matrix, said (A) being surrounded by either (C') a reactive derivative of an impact absorbing rubbery polymer or (D) a composition composed of the rubbery polymer (C) and the reactive derivative of the rubbery polymer (C'), and said inorganic filler (3) being filled in said component (C') or (D), and IV. a dispersed phase consisting of (A') a reactive derivative of a crystalline olefinic polymer which cannot be uniformly mixed with olefinic polymer forming the matrix, or (B) a composition composed of a crystalline olefinic polymer (A) and the reactive derivative of the crystalline olefinic polymer (A'), said (A') or (B) being surrounded by either (C') a reactive derivative of an impact absorbing rubbery polymer, or (D) a composition composed of the rubbery polymer (C) and the reactive derivative of the rubbery polymer (C') and said inorganic filler (3) being filled in both (A') or (B) and (C') or (D), and (5) said impact absorbing rubbery polymer (C) being an ethylene/propylene copolymer rubber, an ethylene/propylene/nonconjugated diene terpolymer, an ethylene/butene copolymer rubber, a styrene/conjugated diene copolymer, or a polydiolefin, and (6) said reactive derivative of an impact absorbing rubbery polymer having hydrophillic groups introduced in the impact absorbing rubbery polymer, and (7) said reactive derivative of a crystalline olefinic polymer having hydrophillic groups introduced in the crystalline olefinic polymer which cannot be uniformly mixed with the crystalline olefinic polymer forming the matrix.
Claim 3
Dependent Claim
27 words
The composition of claim 1 wherein the inorganic filler is a finely divided inorganic solid material having an average particle diameter of not more than 1.5 microns.
Claim 4
Dependent Claim
27 words
The composition of claim 1 wherein the inorganic filler is a finely divided inorganic solid material having an average particle diameter of not more than 1 micron.
Claim 5
Dependent Claim
56 words
The composition of claims 2 or 3 wherein the inorganic filler, either by itself or as a result of being treated or coated with another component, has greater affinity for at least one polymer component in the impact absorbing polymer or its composite constituting the dispersed phase than for the thermoplastic olefinic polymer constituting the matrix.
Claim 6
Dependent Claim
85 words
The composition of claim 1 wherein the dispersed phase consists of (A) a crystalline olefinic polymer which cannot be uniformly mixed with the olefinic polymer constituting the matrix, or (B) a composition composed of a reactive derivative of the crystalline olefinic polymer (A) having affinity for both the crystalline olefinic polymer (A) and the inorganic filler, and (C) the inorganic filler filled in (A) or (B), the components (A) or (B) and (C) being surrounded by (D) an impact absorbing monolefinic or diolefinic rubbery polymer.
Claim 7
Dependent Claim
51 words
The composition of claim 1 wherein the dispersed phase consists of (D) an impact absorbing monolefinic or diolefinic rubbery polymer, or (E) a composition composed of the rubbery polymer (D) and a reactive derivative of the rubbery polymer (D), and (C) the inorganic filler filled in the component (D) or (E).
Claim 8
Dependent Claim
76 words
The composition of claim 1 wherein the dispersed phase consists of (A) a crystalline olefinic polymer which cannot be uniformly mixed with the olefinic polymer constituting the matrix, either (D) an impact absorbing monolefinic or diolefinic rubbery polymer or (E) a composition composed of the rubbery polymer (D) and a reactive derivative of the rubbery polymer (D), component (D) or (E) surrounding component (A), and (C) the inorganic filler filled in the component (D) or (E).
Claim 9
Dependent Claim
23 words
The composition of claim 1 wherein the amount of the inorganic filler is 1 to 60% by weight based on the entire composition.
Claim 10
Dependent Claim
23 words
The composition of claim 1 wherein the amount of the inorganic filler is 3 to 45% by weight based on the entire composition.
Claim 11
Dependent Claim
27 words
The composition of claim 1 wherein the amount of the thermoplastic olefinic polymer constituting the matrix is 30 to 98.5% by weight based on the entire composition.
Claim 12
Dependent Claim
40 words
The composition of claim 1 wherein the amount of the polymer component (the dispersed phase excluding the inorganic filler) forming the dispersed phase is 0.5 to 69% by weight, preferably 10 to 40% by weight, based on the entire composition.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-02-20 | 1987-08-22 | 1988-02-21 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-02-20 | 1991-08-22 | 1992-02-21 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-02-20 | 1995-08-22 | 1996-02-21 | $7700.00 | Window Closed / Lapsed |