Process for making glass surfaces abrasion-resistant and article produced thereby

Claim 1

The method of forming a protective coating on selected exterior surface portions of a glass container comprising the steps of forming a gaseous stream of a dry, pyrolytically-decomposable treatment gas comprising a highly moisture-reactive first gaseous metal-containing constituent confined to the center of said gaseous stream as viewed in cross-section and a less moisture-reactive second gaseous metal-containing constituent surrounding said first constituent of said gaseous stream as viewed in cross-section to isolate said moisture-reactive first constituent from atmospheric moisture and prevent hydrolysis thereof, introducing said gaseous stream of treatment gas into a treatment chamber through at least one inlet port and exhausting the treatment gas from said treatment chamber through exhaust means thereby creating a positive flow pattern from the at least one inlet port to exhaust means, the said flow pattern being confined substantially to the selected exterior surface portions of the glass container, passing a glass container at a temperature above the decomposition point temperature of the treatment gas constituents through the treatment chamber, maintaining said open mouth portion of said glass container out of contact with the treatment gas constituents during said passage, forming a substantially uniform coating of both constituents in the form of metallic oxides on the selected exterior surface portions of said container within the treatment chamber from the decomposition products of the treatment gas constituents, and removing the said container from the treatment chamber whereby the protruding mouth portion of the container is uncoated and the selected exterior surface portions of the container are protectively coated.

Claim 2

The method of forming a protective coating on selected exterior surface portions of a glass container comprising the steps of forming a gaseous stream of a dry, pyrolytically-decomposable treatment gas comprising a highly moisture-reactive first gaseous metal-containing constituent confined to the center of said gaseous stream as viewed in cross-section and a less moisture-reactive second gaseous metal-containing constituent surrounding said first constituent of said gaseous stream as viewed in cross-section to isolate said moisture-reactive first constituent from atmospheric moisture and prevent hydrolysis thereof, introducing said gaseous stream of treatment gas into a treatment chamber through at least one inlet port and exhausting the treatment gas from said treatment chamber through exhaust means thereby creating a positive flow pattern from the at least one inlet port to exhaust means, the said flow pattern being confined substantially to the selected exterior surface portions of the glass container, passing a glass container at a temperature above the decomposition point temperature of the treatment gas constituents through the treatment chamber, maintaining said open mouth portion of said glass container out of contact with the treatment gas constituents during said passage, forming a substantially uniform coating of both constituents in the form of metallic oxides on the selected exterior surface portions of said container within the treatment chamber from the decomposition products of the treatment gas constituents, and removing the said container from the treatment chamber whereby the protruding mouth portion of the container is uncoated and the selected exterior surface portions of the container are protectively coated.

Claim 10

The method of applying an abrasion resistant coating to hot glass articles comprising the steps of transporting the glass articles upon the surface of a conveyor, directing a dry gaseous stream, comprising, as viewed in cross-section, a decomposable, highly moisture-reactive titanium-compound-containing vapor surrounded by a decomposable, less moisture-reactive tin-compound-containing vapor to isolate said moisture-reactive titanium-compound-containing vapor from atmospheric moisture and prevent hydrolysis thereof, to desired selected exterior surfaces of said glass articles while maintaining said selected exterior surfaces contacted by said vapors above the decomposition point temperatures of the decomposable compounds whereby a substantially uniform protective scratch-resistant combined coating of tin and titanium oxides is formed upon the said exterior surfaces of the glass articles.

Claim 11

The method of applying an abrasion resistant coating to hot glass articles comprising the steps of transporting the glass articles upon the surface of a conveyor, directing a dry gaseous stream, comprising, as viewed in cross-section, a decomposable, highly moisture-reactive titanium-compound-containing vapor surrounded by a decomposable, less moisture-reactive tin-compound-containing vapor to isolate said moisture-reactive titanium-compound-containing vapor from atmospheric moisture and prevent hydrolysis thereof, to desired selected exterior surfaces of said glass articles while maintaining said selected exterior surfaces contacted by said vapors above the decomposition point temperatures of the decomposable compounds whereby a substantially uniform protective scratch-resistant combined coating of tin and titanium oxides is formed upon the said exterior surfaces of the glass articles.