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US3850665A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for forming a metal oxide coating on a substrate and resulting products

Assignee: AGC Glass Europe SA
•
Filing: 1972-07-06
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Granted: 1974-11-26
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Expires: 1992-07-06
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Abstract

Abstract A metal oxide coating is formed on a vitreous or non-vitreous substrate by applying to a substrate a composition comprising an acetyl acetonate coprecipitate of two or more metals. The substrate and composition are simultaneously or subsequently heated to convert the coprecipitate on the substrate to leave a metal oxide coating which is at least partly composed of an oxidic compound containing two or more metals.

Inventors

  • 👤 R Posset
  • 👤 E Plumat

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 14:58
CPC Classifications
C; C03; C03C; C03C17/00; C03C17/22; C03C17/23; C03C17/25; B; B60; B60J; B60J1/00; B60J1/002; C03C2217/00; C03C2217/20; C03C2217/21; C03C2217/229; C03C2217/23; C03C2218/00; C03C2218/10; C03C2218/11; C03C2218/112

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 84 words
IN A PROCESS FOR FORMING A METAL OXIDE ON A SUBSTRAE COMPRISING APPLYING AT LEAST ONE METAL COMPOUND TO THE SUBSTRATE AND THERMALLY CONVERTING SAID COMPOUND TO A METAL OXIDE COATING THE IMPROVEMENT WHEREIN THE METAL COMPOUNDS IS AN ACETYL ACETONATE COPRECIPITATE OF TWO OR MORE METALS DISSOLVED IN A SOLVENT, AND SAID SOLENT BEING SELECTED FROM THE GROUP CONSISTING OF AN APROTONIC SOLVENT A SUBSTITUTED OR UNSUBSTITUTED MONOCARBOXYLIC ACID, AN AMINE OR DIAMINE SOLVENT AND MIXTURES OF TWO OR MORE OF SAID SOLVENTS.
Claim 2
Dependent Claim 84 words
IN A PROCESS FOR FORMING A METAL OXIDE ON A SUBSTRAE COMPRISING APPLYING AT LEAST ONE METAL COMPOUND TO THE SUBSTRATE AND THERMALLY CONVERTING SAID COMPOUND TO A METAL OXIDE COATING THE IMPROVEMENT WHEREIN THE METAL COMPOUNDS IS AN ACETYL ACETONATE COPRECIPITATE OF TWO OR MORE METALS DISSOLVED IN A SOLVENT, AND SAID SOLENT BEING SELECTED FROM THE GROUP CONSISTING OF AN APROTONIC SOLVENT A SUBSTITUTED OR UNSUBSTITUTED MONOCARBOXYLIC ACID, AN AMINE OR DIAMINE SOLVENT AND MIXTURES OF TWO OR MORE OF SAID SOLVENTS.
Claim 3
Dependent Claim 18 words
In a process according to claim 1 wherein the step of thermally converting includes heating the coated substrate.
Claim 4
Dependent Claim 29 words
In a process according to claim 1 wherein the substrate is pre-heated to a sufficiently high temperature to provide the heat required to effect the conversion of the coprecipitate.
Claim 5
Dependent Claim 32 words
In a process according to claim 3 wherein the substrate is pre-heated to bring the temperature of the surface to be coated to a value within the range of 300* to 700*C.
Claim 6
Dependent Claim 15 words
In a process according to claim 1 wherein the solution is applied in droplet form.
Claim 7
Dependent Claim 28 words
In a process according to claim 1 wherein the solvent comprises an aprotonic solvent having a dielectric constant greater than 15 and a dipolar moment greater than 3D.
Claim 8
Dependent Claim 12 words
In a process according to claim 6 wherein the solvent comprises dimethylformamide.
Claim 9
Dependent Claim 17 words
In a process according to claim 1 wherein a substituted or unsubstituted monocarboxylic acid solvent is used.
Claim 10
Dependent Claim 27 words
In a process according to claim 1 wherein the solvent comprises an alkyl or alkylene amine or diamine in which the amino group or groups are unsubstituted.
Claim 11
Dependent Claim 18 words
In a process according to claim 1 wherein an alkyl or alkylene amine or diamine solvent is used.
Claim 12
Dependent Claim 34 words
In a process according to claim 1 wherein the coprecipitate is an acetyl acetonate coprecipitate of two or more metals represented in the group: Fe, Ni, Co, Zn, V, Cu, Cr, Zr or Mn.
Claim 13
Dependent Claim 38 words
In a process according to claim 1 wherein the coprecipitate is an acetyl acetonate coprecipitate of two or more metals represented in the group: Fe, Ni, Co, Zn, V, Cu, Zr, Cr, Mn, Bi, Y, W or In.
Claim 14
Dependent Claim 16 words
In a process according to claim 1 and wherein the substrate is at least partly vitreous.
Claim 15
Dependent Claim 25 words
In a process according to claim 13 wherein the composition is selected and applied so that the formed metal oxide coating is a light-transmitting coating.
Claim 16
Dependent Claim 24 words
In a process according to claim 14 wherein the formed metal oxide coating has a thickness in the range of 200 to 1,200 A.
Claim 17
Dependent Claim 13 words
In a process according to claim 1 wherein the substrate is flat glass.
Claim 18
Dependent Claim 26 words
In a process according to claim 16 wherein the glass is at a temperature in the range of 450* to 650* at the time of coating.
Claim 19
Dependent Claim 13 words
An article of manufacture made in accordance with the process of claim 1.
Claim 20
Dependent Claim 16 words
An article of manufacture according to claim 18 wherein the substrate is vitreous or partly vitreous.

References Cited (Backward Citations)

US2859131A Cited
DE1035872B Cited
US2976285A Cited
US3410710A Cited
US3107177A Cited
US3411934A Cited
US3652246A Cited
US3711322A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-11-25 1978-05-27 1978-11-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-11-25 1982-05-27 1982-11-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-11-25 1986-05-27 1986-11-26 $7700.00 Window Closed / Lapsed

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