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Patent US4430276A successfully refreshed from Google Patents.
US4430276A
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Method of making stable UO2 fuel pellets
Assignee: Westinghouse Electric Corp
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Filing: 1981-10-02
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Granted: 1984-02-07
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Expires: 2001-10-02
Abstract
Abstract A method is disclosed for producing a dimensionally stable UO 2 fuel pellet of large grain mole %, and relatively large pore size. A dopant containing an element selected from the group consisting of aluminum, calcium, magnesium, titanium, zirconium, vanadium, niobium, and mixtures thereof is added to a highly sinterable UO 2 powder, which is a UO 2 powder that is sinterable to at least 97% theoretical density at 1600° C. in one hour, and the UO 2 powder can then be formed into fuel pellets. Alternatively, the dopant can be added at a step in the process of producing ammonium diuranate. The ammonium diuranate is collected with about 0.05 to about 1.7 mole%, based on UO 2 , of a compound containing said element. That mixture is then calcined to produce UO 2 and the UO 2 is formed into a fuel pellet. The addition of the dopant can also be made at the hydrolysis stage in the manufacture of UO 2 by a dry conversion process.
Inventors
- 👤 Kenneth C. Radford
- 👤 James M. Pope
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 08:20
CPC Classifications
G; G21; G21C; G21C3/00; G21C3/42; G21C3/58; G21C3/62; G21C3/623; Y; Y02; Y02E; Y02E30/00; Y02E30/30
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
103 words
In a method where a UO 2 powder which is sinterable to at least 97% theoretical density at 1600° C. in H 2 in one hour is produced from an aqueous solution of UO 2 F 2 , an improvement which enhances the dimensional stability of a fuel pellet made from UO 2 powder, comprising adding a water soluble dopant forming compound containing an element selected from the group consisting of aluminum, calcium, magnesium, titanium, zirconium, vanadium, niobium, and mixtures thereof, to said solution in an amount such that said UO 2 powder contains about 0.05 to about 1.7 mole% of said dopant.
Claim 2
Dependent Claim
103 words
In a method where a UO 2 powder which is sinterable to at least 97% theoretical density at 1600° C. in H 2 in one hour is produced from an aqueous solution of UO 2 F 2 , an improvement which enhances the dimensional stability of a fuel pellet made from UO 2 powder, comprising adding a water soluble dopant forming compound containing an element selected from the group consisting of aluminum, calcium, magnesium, titanium, zirconium, vanadium, niobium, and mixtures thereof, to said solution in an amount such that said UO 2 powder contains about 0.05 to about 1.7 mole% of said dopant.
Claim 3
Dependent Claim
32 words
A method according to claim 1 wherein said ammonium diuranate and said dopant forming compound are precipitated by the addition of ammonium hydroxide to said solution of UO 2 F 2 .
Claim 4
Dependent Claim
12 words
A method according to claim 2 wherein said dopant is a nitrate.
Claim 5
Dependent Claim
25 words
A method according to claim 1 wherein said element is selected from the group consisting of titanium, niobium, and a mixture of calcium and titanium.
Claim 6
Dependent Claim
43 words
A method according to claim 1 wherein said UO 2 is formed into a fuel pellet by grinding, pressing to about 40 to about 65% theoretical density, and sintering at about 1400° to about 1800° C. for about 1 to about 10 hours.
Claim 7
Dependent Claim
103 words
In a method where a UO 2 powder which is sinterable to at least 97% theoretical density at 1600° C. in H 2 in one hour is produced from water into which is added UF 6 gas, an improvement which enhances the dimensional stability of a fuel pellet made from said UO 2 powder, comprising adding a water soluble dopant forming compound containing an element selected from the group consisting of aluminum, calcium, magnesium, titanium, zirconium, vanadium, niobium, and mixtures thereof, to said water in an amount such that said UO 2 powder contains about 0.05 to about 1.7 mole% of said dopant.
Claim 8
Dependent Claim
103 words
In a method where a UO 2 powder which is sinterable to at least 97% theoretical density at 1600° C. in H 2 in one hour is produced from water into which is added UF 6 gas, an improvement which enhances the dimensional stability of a fuel pellet made from said UO 2 powder, comprising adding a water soluble dopant forming compound containing an element selected from the group consisting of aluminum, calcium, magnesium, titanium, zirconium, vanadium, niobium, and mixtures thereof, to said water in an amount such that said UO 2 powder contains about 0.05 to about 1.7 mole% of said dopant.
Claim 9
Dependent Claim
12 words
A method according to claim 6 wherein said dopant is a nitrate.
Claim 10
Dependent Claim
25 words
A method according to claim 6 wherein said element is selected from the group consisting of titanium, niobium, and a mixture of calcium and titanium.
Claim 11
Dependent Claim
43 words
A method according to claim 6 wherein said UO 2 is formed into a fuel pellet by grinding, pressing to about 40 to about 65% theoretical density and sintering at about 1400° to about 1800° C. for about 1 to about 10 hours.
Claim 12
Dependent Claim
101 words
In a method where a UO 2 powder which is sinterable to at least 97% theoretical density at 1600° C. in H 2 in one hour is produced from an aqueous solution of uranyl nitrate, an improvement which enhances the dimensional stability of a fuel pellet made from said UO 2 powder, comprising adding a water soluble dopant forming compound containing an element selected from the group consisting of aluminum, calcium, magnesium, titanium, zirconium, vanadium, niobium, and mixtures thereof, to said solution in an amount such that said UO 2 powder contains about 0.05 to about 1.7 mole% of said dopant.
Claim 13
Dependent Claim
101 words
In a method where a UO 2 powder which is sinterable to at least 97% theoretical density at 1600° C. in H 2 in one hour is produced from an aqueous solution of uranyl nitrate, an improvement which enhances the dimensional stability of a fuel pellet made from said UO 2 powder, comprising adding a water soluble dopant forming compound containing an element selected from the group consisting of aluminum, calcium, magnesium, titanium, zirconium, vanadium, niobium, and mixtures thereof, to said solution in an amount such that said UO 2 powder contains about 0.05 to about 1.7 mole% of said dopant.
Claim 14
Dependent Claim
12 words
A method according to claim 10 wherein said dopant is a nitrate.
Claim 15
Dependent Claim
25 words
A method according to claim 10 wherein said element is selected from the group consisting of titanium, niobium, and a mixture of calcium and titanium.
Claim 16
Dependent Claim
43 words
A method according to claim 10 wherein said UO 2 is formed into a fuel pellet by grinding, pressing to about 40 to about 65% theoretical density and sintering at about 1400° to about 1800° C. for about 1 to about 10 hours.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-02-06 | 1987-08-08 | 1988-02-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-02-06 | 1991-08-08 | 1992-02-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-02-06 | 1995-08-08 | 1996-02-07 | $7700.00 | Window Closed / Lapsed |