Patent US2927583A successfully refreshed from Google Patents.
US4426431A
Expired / Lapsed
US
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Radiation-curable compositions for restorative and/or protective treatment of photographic elements
Assignee: Eastman Kodak Co
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Filing: 1982-09-22
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Granted: 1984-01-17
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Expires: 2002-09-22
Abstract
Abstract Radiation-curable compositions useful for restorative and/or protective treatment of photographic elements are comprised of a polymerizable epoxy compound, a cationic initiator for initiating polymerization of the epoxy compound, a polymerizable acrylic compound, a haloalkylated aromatic ketone which serves as a free-radical initiator for initiating polymerization of the acrylic compound, and a polymerizable organofunctional silane. Photographic elements, such as still films, motion picture films, paper prints, microfiche, and the like, are provided with a protective overcoat layer which is permanently bonded to the element, and serves to protect it from abrasion and scratches, by coating the element with the radiation-curable composition and irradiating the coating to bond it to the element and cure it to form a transparent, flexible, scratch-resistant, cross-linked polymeric layer. The protective overcoat layer can be applied to the image-bearing side of the element or to the support side of the element or to both sides. The radiation-curable composition can also be used as a restorative composition in the treatment of photographic elements which have scratches, abrasion marks, and the like, which impair the appearance or projection capabilities of the element. In use as a restorative composition, the radiation-curable composition can be applied locally in the region of the defects only, to effectively eliminate them and restore the element to a substantially defect-free condition, or it can be applied over the entire surface of the element to both eliminate the defects and form a protective overcoat layer that is capable of providing protection against subsequent scratching or abrasion.
Inventors
- 👤 Louis P. Harasta
- 👤 Gerald M. Leszyk
- 👤 Edward D. Morrison
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 05:32
CPC Classifications
G; G03; G03C; G03C11/00; G03C11/08; C; C09; C09D; C09D4/00; C09D4/06; Y; Y10; Y10S; Y10S430/00; Y10S430/139; Y10S430/162; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31511; Y10T428/31652; Y10T428/31663
Claims Analysis
Total Claims: 59
Claim 1
Independent Claim
51 words
A radiation-curable coating composition comprising: (1) a polymerizable epoxy compound, (2) a cationic initiator for initiating polymerization of said epoxy compound, (3) a polymerizable acrylic compound, (4) a free-radical initiator for initiating polymerization of said acrylic compound, said free-radical initiator comprising a haloalkylated aromatic ketone, and (5) a polymerizable organofunctional silane.
Claim 2
Dependent Claim
51 words
A radiation-curable coating composition comprising: (1) a polymerizable epoxy compound, (2) a cationic initiator for initiating polymerization of said epoxy compound, (3) a polymerizable acrylic compound, (4) a free-radical initiator for initiating polymerization of said acrylic compound, said free-radical initiator comprising a haloalkylated aromatic ketone, and (5) a polymerizable organofunctional silane.
Claim 3
Dependent Claim
21 words
A radiation-curable coating composition as claimed in claim 1 wherein said epoxy compound is an aliphatic or cycloaliphatic multifunctional epoxy compound.
Claim 4
Dependent Claim
21 words
A radiation-curable coating composition as claimed in claim 1 wherein said epoxy compound is a polyglycidyl ether of an aliphatic polyol.
Claim 5
Dependent Claim
17 words
A radiation-curable coating composition as claimed in claim 1 wherein said epoxy compound is an epoxycyclohexylalkyl dicarboxylate.
Claim 6
Dependent Claim
20 words
A radiation-curable coating composition as claimed in claim 1 wherein said epoxy compound contains one or more cyclopentane oxide groups.
Claim 7
Dependent Claim
18 words
A radiation-curable coating composition as claimed in claim 1 wherein said cationic initiator is an aromatic onium salt.
Claim 8
Dependent Claim
23 words
A radiation-curable coating composition as claimed in claim 1 wherein said cationic initiator is an aromatic onium salt of a Group VIa element.
Claim 9
Dependent Claim
17 words
A radiation-curable coating composition as claimed in claim 1 wherein said cationic initiator is a sulfonium salt.
Claim 10
Dependent Claim
18 words
A radiation-curable coating composition as claimed in claim 1 wherein said acrylic compound is a polyfunctional acrylic monomer.
Claim 11
Dependent Claim
93 words
A radiation-curable coating composition as claimed in claim 1 wherein said acrylic compound is a polyfunctional acrylic monomer of the formula: ##STR12## wherein each R 1 is independently selected from the group consisting of a hydrogen atom and an alkyl group of 1 to 2 carbon atoms, and each R 2 is independently selected from the group consisting of an alkyl group of 1 to 6 carbon atoms and a radical of the formula: ##STR13## in which R 3 is a hydrogen atom or an alkyl group of 1 to 2 carbon atoms.
Claim 12
Dependent Claim
18 words
A radiation-curable coating composition as claimed in claim 1 wherein said haloalkylated aromatic ketone is a halomethylated benzophenone.
Claim 13
Dependent Claim
57 words
A radiation-curable coating composition as claimed in claim 1 wherein said haloalkylated aromatic ketone is a halomethylated benzophenone of the formula: ##STR14## where R 1 is CH 2 X, CHX 2 or CX 3 and R 2 is H, CH 3 , CH 2 X, CHX 2 or CX 3 where X is chloro, bromo or iodo.
Claim 14
Dependent Claim
58 words
A radiation-curable coating composition as claimed in claim 1 wherein said haloalkylated aromatic ketone is a 3,4-bis(halomethyl)benzophenone of the formula: ##STR15## wherein R is hydrogen, chloro, methoxycarbonyl, methyl or t-butyl and R 1 and R 2 are the same or different and each is CH 2 X, CHX 2 or CX 3 where X is chloro or bromo.
Claim 15
Dependent Claim
17 words
A radiation-curable coating composition as claimed in claim 1 wherein said haloalkylated aromatic ketone is 4,4'-bis-chloromethyl benzophenone.
Claim 16
Dependent Claim
53 words
A radiation-curable coating composition as claimed in claim 1 wherein said polymerizable organofunctional silane is an epoxy silane of the formula: ##STR16## where m is an integer of from 1 to 6, n is an integer of from 1 to 6, and R is an alkyl radical of 1 to 6 carbon atoms.
Claim 17
Dependent Claim
53 words
A radiation-curable coating composition as claimed in claim 1 wherein said polymerizable organofunctional silane is an epoxy silane of the formula: ##STR17## where m is an integer of from 1 to 6, n is an integer of from 1 to 6, and R is an alkyl radical of 1 to 6 carbon atoms.
Claim 18
Dependent Claim
52 words
A radiation-curable coating composition as claimed in claim 1 wherein said polymerizable organofunctional silane is an acrylated silane of the formula: ##STR18## wherein R 1 is hydrogen or a methyl group, n is an integer of from 1 to 6 and R is an alkyl group of 1 to 6 carbon atoms.
Claim 19
Dependent Claim
14 words
A radiation-curable coating composition as claimed in claim 1 additionally containing a siloxy-containing polycarbinol.
Claim 20
Dependent Claim
46 words
A radiation-curable coating composition as claimed in claim 1 additionally containing a siloxy-containing polycarbinol of the formula: ##STR19## where R is a hydrocarbon radical containing 1 to 10 carbon atoms and x is an integer having a value in the range of from 2 to 100.
Claim 21
Dependent Claim
47 words
A radiation-curable coating composition as claimed in claim 1 additionally containing a siloxy-containing polycarbinol of the formula: ##STR20## where R is a hydrocarbon radical containing 1 to 10 carbon atoms and x and y are integers having a value in the range of from 2 to 100.
Claim 22
Dependent Claim
62 words
A radiation-curable coating composition comprising: (1) a polymerizable epoxy compound, (2) a cationic initiator for initiating polymerization of said epoxy compound, (3) a polymerizable acrylic compound, (4) a free-radical initiator for initiating polymerization of said acrylic compound, said free-radical initiator comprising a haloalkylated aromatic ketone, (5) an epoxy silane, (6) an acrylated silane, (7) a siloxy-containing polycarbinol, and (8) a matting agent.
Claim 23
Dependent Claim
62 words
A radiation-curable coating composition comprising: (1) a polymerizable epoxy compound, (2) a cationic initiator for initiating polymerization of said epoxy compound, (3) a polymerizable acrylic compound, (4) a free-radical initiator for initiating polymerization of said acrylic compound, said free-radical initiator comprising a haloalkylated aromatic ketone, (5) an epoxy silane, (6) an acrylated silane, (7) a siloxy-containing polycarbinol, and (8) a matting agent.
Claim 24
Dependent Claim
34 words
A radiation-curable coating composition comprising: (1) pentaerythritol triacrylate, (2) gamma-methacryloxypropyltrimethoxysilane, (3) 1,4-butanediol diglycidyl ether, (4) gamma-glycidoxypropyl trimethoxysilane, (5) bis(3,4-epoxy-6-methylcyclohexylmethyl) adipate, (6) 4,4'-bis-chloromethyl benzophenone, (7) triphenylsulfonium hexafluoroantimonate, (8) colloidal silica, and (9) a siloxy-containing polycarbinol.
Claim 25
Dependent Claim
34 words
A radiation-curable coating composition comprising: (1) pentaerythritol triacrylate, (2) gamma-methacryloxypropyltrimethoxysilane, (3) 1,4-butanediol diglycidyl ether, (4) gamma-glycidoxypropyl trimethoxysilane, (5) bis(3,4-epoxy-6-methylcyclohexylmethyl) adipate, (6) 4,4'-bis-chloromethyl benzophenone, (7) triphenylsulfonium hexafluoroantimonate, (8) colloidal silica, and (9) a siloxy-containing polycarbinol.
Claim 26
Dependent Claim
128 words
A photographic element comprising: (1) a support, (2) at least one image-bearing layer, and (3) a protective overcoat layer which is permanently bonded to at least one side of said element, said protective overcoat layer having been formed by (a) coating said element with a radiation-curable coating composition which forms a transparent, flexible, scratch-resistant, crosslinked polymeric layer upon radiation curing, said coating composition comprising: (1) a polymerizable epoxy compound, (2) a cationic initiator for initiating polymerization of said epoxy compound, (3) a polymerizable acrylic compound, (4) a free-radical initiator for initiating polymerization of said acrylic compound, said free-radical initiator comprising a haloalkylated aromatic ketone, and (5) a polymerizable organofunctional silane, and (b) subjecting said coating to radiation sufficient to cure said coating and bond it to said element.
Claim 27
Dependent Claim
128 words
A photographic element comprising: (1) a support, (2) at least one image-bearing layer, and (3) a protective overcoat layer which is permanently bonded to at least one side of said element, said protective overcoat layer having been formed by (a) coating said element with a radiation-curable coating composition which forms a transparent, flexible, scratch-resistant, crosslinked polymeric layer upon radiation curing, said coating composition comprising: (1) a polymerizable epoxy compound, (2) a cationic initiator for initiating polymerization of said epoxy compound, (3) a polymerizable acrylic compound, (4) a free-radical initiator for initiating polymerization of said acrylic compound, said free-radical initiator comprising a haloalkylated aromatic ketone, and (5) a polymerizable organofunctional silane, and (b) subjecting said coating to radiation sufficient to cure said coating and bond it to said element.
Claim 28
Dependent Claim
129 words
A photographic element comprising: (1) a support, (2) at least one image-bearing layer, and (3) a protective overcoat layer which is permanently bonded to the image-bearing side of said element; said protective overcoat layer having been formed by (a) coating said image-bearing side with a radiation-curable coating composition which forms a transparent, flexible, scratch-resistant, cross-linked polymeric layer upon radiation curing, said coating composition comprising (1) a polymerizable epoxy compound, (2) a cationic initiator for initiating polymerization of said epoxy compound, (3) a polymerizable acrylic compound, (4) a free-radical initiator for initiating polymerization of said acrylic compound, said free-radical initiator comprising a haloalkylated aromatic ketone, and (5) a polymerizable organofunctional silane, and (b) subjecting said coating to radiation sufficient to cure said coating and bond it to said image-bearing side.
Claim 29
Dependent Claim
129 words
A photographic element comprising: (1) a support, (2) at least one image-bearing layer, and (3) a protective overcoat layer which is permanently bonded to the image-bearing side of said element; said protective overcoat layer having been formed by (a) coating said image-bearing side with a radiation-curable coating composition which forms a transparent, flexible, scratch-resistant, cross-linked polymeric layer upon radiation curing, said coating composition comprising (1) a polymerizable epoxy compound, (2) a cationic initiator for initiating polymerization of said epoxy compound, (3) a polymerizable acrylic compound, (4) a free-radical initiator for initiating polymerization of said acrylic compound, said free-radical initiator comprising a haloalkylated aromatic ketone, and (5) a polymerizable organofunctional silane, and (b) subjecting said coating to radiation sufficient to cure said coating and bond it to said image-bearing side.
Claim 30
Dependent Claim
129 words
A photographic element comprising: (1) a support, (2) at least one image-bearing layer, and (3) a protective overcoat layer which is permanently bonded to the support side of said element; said protective overcoat layer having been formed by (a) coating said support side with a radiation-curable coating composition which forms a transparent, flexible, scratch-resistant, cross-linked polymeric layer upon radiation curing, said coating composition comprising: (1) a polymerizable epoxy compound, (2) a cationic initiator for initiating polymerization of said epoxy compound, (3) a polymerizable acrylic compound, (4) a free-radical initiator for initiating polymerization of said acrylic compound, said free-radical initiator comprising a haloalkylated aromatic ketone, and (5) a polymerizable organofunctional silane, and (b) subjecting said coating to radiation sufficient to cure said coating and bond it to said support side.
Claim 31
Dependent Claim
129 words
A photographic element comprising: (1) a support, (2) at least one image-bearing layer, and (3) a protective overcoat layer which is permanently bonded to the support side of said element; said protective overcoat layer having been formed by (a) coating said support side with a radiation-curable coating composition which forms a transparent, flexible, scratch-resistant, cross-linked polymeric layer upon radiation curing, said coating composition comprising: (1) a polymerizable epoxy compound, (2) a cationic initiator for initiating polymerization of said epoxy compound, (3) a polymerizable acrylic compound, (4) a free-radical initiator for initiating polymerization of said acrylic compound, said free-radical initiator comprising a haloalkylated aromatic ketone, and (5) a polymerizable organofunctional silane, and (b) subjecting said coating to radiation sufficient to cure said coating and bond it to said support side.
Claim 32
Dependent Claim
136 words
A photographic element comprising: (1) a support, (2) at least one image-bearing layer, and (3) protective overcoat layers which are permanently bonded to both the image-bearing side of said element and the support side of said element, each said protective overcoat layer having been formed by (a) coating the respective side with a radiation-curable coating composition which forms a transparent, flexible, scratch-resistant, cross-linked polymeric layer upon radiation curing, said coating composition comprising: (1) a polymerizable epoxy compound, (2) a cationic initiator for initiating polymerization of said epoxy compound, (3) a polymerizable acrylic compound, (4) a free-radical initiator for initiating polymerization of said acrylic compound, said free-radical initiator comprising a haloalkylated aromatic ketone, and (5) a polymerizable organofunctional silane and (b) subjecting said coating to radiation sufficient to cure said coating and bond it to said element.
Claim 33
Dependent Claim
136 words
A photographic element comprising: (1) a support, (2) at least one image-bearing layer, and (3) protective overcoat layers which are permanently bonded to both the image-bearing side of said element and the support side of said element, each said protective overcoat layer having been formed by (a) coating the respective side with a radiation-curable coating composition which forms a transparent, flexible, scratch-resistant, cross-linked polymeric layer upon radiation curing, said coating composition comprising: (1) a polymerizable epoxy compound, (2) a cationic initiator for initiating polymerization of said epoxy compound, (3) a polymerizable acrylic compound, (4) a free-radical initiator for initiating polymerization of said acrylic compound, said free-radical initiator comprising a haloalkylated aromatic ketone, and (5) a polymerizable organofunctional silane and (b) subjecting said coating to radiation sufficient to cure said coating and bond it to said element.
Claim 34
Dependent Claim
155 words
A photographic element comprising (1) a support, (2) at least one image-bearing layer, and (3) protective overcoat layers which are permanently bonded to both the image-bearing side of said element and the support side of said element, each said protective overcoat layer having been formed by (a) coating the respective side with a radiation-curable coating composition which forms a transparent, flexible, scratch-resistant, cross-linked polymeric layer upon radiation curing, said coating composition comprising: (1) a polymerizable epoxy compound, (2) a cationic initiator for initiating polymerization of said epoxy compound, (3) a polymerizable acrylic compound, (4) a free-radical initiator for initiating polymerization of said acrylic compound, said free-radical initiator comprising a haloalkylated aromatic ketone, (5) an epoxy silane, (6) an acrylated silane, (7) a siloxy-containing polycarbinol, and (8) a matting agent, and (b) subjecting said coating to ultraviolet radiation sufficient to cure it and bond it to the side of said element on which it is coated.
Claim 35
Dependent Claim
155 words
A photographic element comprising (1) a support, (2) at least one image-bearing layer, and (3) protective overcoat layers which are permanently bonded to both the image-bearing side of said element and the support side of said element, each said protective overcoat layer having been formed by (a) coating the respective side with a radiation-curable coating composition which forms a transparent, flexible, scratch-resistant, cross-linked polymeric layer upon radiation curing, said coating composition comprising: (1) a polymerizable epoxy compound, (2) a cationic initiator for initiating polymerization of said epoxy compound, (3) a polymerizable acrylic compound, (4) a free-radical initiator for initiating polymerization of said acrylic compound, said free-radical initiator comprising a haloalkylated aromatic ketone, (5) an epoxy silane, (6) an acrylated silane, (7) a siloxy-containing polycarbinol, and (8) a matting agent, and (b) subjecting said coating to ultraviolet radiation sufficient to cure it and bond it to the side of said element on which it is coated.
Claim 36
Dependent Claim
24 words
A photographic element as claimed in claim 27 wherein said cationic initiator is a sulfonium salt and said free-radical initiator is a halomethylated benzophenone.
Claim 37
Dependent Claim
59 words
A photographic element as claimed in claim 27 wherein said epoxy compound is a mixture of 1,4-butanediol diglycidyl ether and bis(3,4-epoxy-6-methylcyclohexylmethyl) adipate, said cationic initiator is triphenylsulfonium hexafluoroantimonate, said acrylic compound is pentaerythritol triacrylate, said free-radical initiator is 4,4'-bis-chloromethyl benzophenone, said epoxy silane is gamma-glycidoxypropyl trimethoxysilane, said acrylated silane is gamma-methacryloxypropyl trimethoxysilane, and said matting agent is colloidal silica.
Claim 38
Dependent Claim
29 words
A photographic element as claimed in claim 26 wherein said support is a cellulose triacetate support and said image-bearing layer is an imagewise-exposed and processed gelatino/silver halide emulsion layer.
Claim 39
Dependent Claim
29 words
A photographic element as claimed in claim 26 wherein said support is a poly(ethylene terephthalate) support and said image-bearing layer is an imagewise-exposed and processed gelatino/silver halide emulsion layer.
Claim 40
Dependent Claim
108 words
An element comprising a photographic support and a protective overcoat layer, said protective overcoat layer having been formed by (a) coating said element with a radiation-curable coating composition which forms a transparent, flexible, scratch-resistant, cross-linked polymeric layer upon radiation curing, said coating composition comprising (1) a polymerizable epoxy compound, (2) a cationic initiator for initiating polymerization of said epoxy compound, (3) a polymerizable acrylic compound, (4) a free-radical initiator for initiating polymerization of said acrylic compound, said free-radical initiator comprising a haloalkylated aromatic ketone, and (5) a polymerizable organofunctional silane, and (b) subjecting said coating to radiation sufficient to cure said coating and bond it to said element.
Claim 41
Dependent Claim
108 words
An element comprising a photographic support and a protective overcoat layer, said protective overcoat layer having been formed by (a) coating said element with a radiation-curable coating composition which forms a transparent, flexible, scratch-resistant, cross-linked polymeric layer upon radiation curing, said coating composition comprising (1) a polymerizable epoxy compound, (2) a cationic initiator for initiating polymerization of said epoxy compound, (3) a polymerizable acrylic compound, (4) a free-radical initiator for initiating polymerization of said acrylic compound, said free-radical initiator comprising a haloalkylated aromatic ketone, and (5) a polymerizable organofunctional silane, and (b) subjecting said coating to radiation sufficient to cure said coating and bond it to said element.
Claim 42
Independent Claim
92 words
A method of protecting a photographic element against abrasion and scratches which comprises (a) coating at least one side of said element with a radiation-curable coating composition comprising (1) a polymerizable epoxy compound, (2) a cationic intiator for initiating polymerization of said epoxy compound, (3) a polymerizable acrylic compound, (4) a free-radical initiator for initiating polymerization of said acrylic compound, said free-radical initiator comprising a haloalkylated aromatic ketone, and (5) a polymerizable organofunctional silane, and (b) subjecting said coating to radiation sufficient to cure said coating and bond it to said element.
Claim 43
Independent Claim
92 words
A method of protecting a photographic element against abrasion and scratches which comprises (a) coating at least one side of said element with a radiation-curable coating composition comprising (1) a polymerizable epoxy compound, (2) a cationic intiator for initiating polymerization of said epoxy compound, (3) a polymerizable acrylic compound, (4) a free-radical initiator for initiating polymerization of said acrylic compound, said free-radical initiator comprising a haloalkylated aromatic ketone, and (5) a polymerizable organofunctional silane, and (b) subjecting said coating to radiation sufficient to cure said coating and bond it to said element.
Claim 44
Independent Claim
98 words
A method for protecting a photographic element against abrasion and scratches which comprises (a) coating both sides of said element with a radiation-curable coating composition comprising (1) a polymerizable epoxy compound, (2) a cationic initiator for initiating polymerization of said epoxy compound, (3) a polymerizable acrylic compound, (4) a free-radical initiator for initiating polymerization of said acrylic compound, said free-radical initiator comprising a haloalkylated aromatic ketone, and (5) a polymerizable organofunctional silane, and (b) subjecting each said coating to radiation sufficient to cure it and bond it to the side of the element on which it is coated.
Claim 45
Independent Claim
98 words
A method for protecting a photographic element against abrasion and scratches which comprises (a) coating both sides of said element with a radiation-curable coating composition comprising (1) a polymerizable epoxy compound, (2) a cationic initiator for initiating polymerization of said epoxy compound, (3) a polymerizable acrylic compound, (4) a free-radical initiator for initiating polymerization of said acrylic compound, said free-radical initiator comprising a haloalkylated aromatic ketone, and (5) a polymerizable organofunctional silane, and (b) subjecting each said coating to radiation sufficient to cure it and bond it to the side of the element on which it is coated.
Claim 46
Dependent Claim
21 words
A method as claimed in claim 34 wherein said composition contains an epoxy silane, an acrylated silane, and a siloxy-containing polycarbinol.
Claim 47
Dependent Claim
15 words
A method as claimed in claim 34 wherein said cationic initiator is a sulfonium salt.
Claim 48
Dependent Claim
15 words
A method as claimed in claim 34 wherein said free-radical initiator is a halomethylated benzophenone.
Claim 49
Independent Claim
172 words
A method of treating a photographic element comprising a support and at least one image-bearing layer, said element having defects such as scratches, abrasion marks and the like on one or both sides thereof which impair the appearance or projection capabilities of said element, which method comprises (a) applying to said element, at least in the region of said element in which said defects are located, a radiation-curable composition which fills in said defects and forms a transparent, flexible, scratch-resistant, cross-linked polymeric material upon radiation curing, said composition comprising (1) a polymerizable epoxy compound, (2) a cationic initiator for initiating polymerization of said epoxy compound, (3) a polymerizable acrylic compound, (4) a free-radical initiator for initiating polymerization of said acrylic compound, said free-radical initiator comprising a haloalkylated aromatic ketone, and (5) a polymerizable organofunctional silane, and (b) subjecting said composition to radiation sufficient to cure it and bond it to said element, whereby the adverse effects of said defects on the appearance or projection capabilities of said element are reduced or eliminated.
Claim 50
Independent Claim
172 words
A method of treating a photographic element comprising a support and at least one image-bearing layer, said element having defects such as scratches, abrasion marks and the like on one or both sides thereof which impair the appearance or projection capabilities of said element, which method comprises (a) applying to said element, at least in the region of said element in which said defects are located, a radiation-curable composition which fills in said defects and forms a transparent, flexible, scratch-resistant, cross-linked polymeric material upon radiation curing, said composition comprising (1) a polymerizable epoxy compound, (2) a cationic initiator for initiating polymerization of said epoxy compound, (3) a polymerizable acrylic compound, (4) a free-radical initiator for initiating polymerization of said acrylic compound, said free-radical initiator comprising a haloalkylated aromatic ketone, and (5) a polymerizable organofunctional silane, and (b) subjecting said composition to radiation sufficient to cure it and bond it to said element, whereby the adverse effects of said defects on the appearance or projection capabilities of said element are reduced or eliminated.
Claim 51
Dependent Claim
25 words
A method as claimed in claim 38 wherein said radiation-curable composition has a viscosity in the range of from about 10 to about 100 centipoises.
Claim 52
Dependent Claim
26 words
A method as claimed in claim 38 wherein said radiation-curable composition is applied only to the region of said element in which said defects are located.
Claim 53
Dependent Claim
20 words
A method as claimed in claim 38 wherein said radiation-curable composition covers at least one entire surface of said element.
Claim 54
Dependent Claim
28 words
A method as claimed in claim 38 wherein said support is a cellulose triacetate support and said image-bearing layer is an imagewise-exposed and processed gelatino/silver halide emulsion layer.
Claim 55
Dependent Claim
28 words
A method as claimed in claim 38 wherein said support is a poly(ethylene terephthalate) support and said image-bearing layer is an imagewise-exposed and processed gelatino/silver halide emulsion layer.
Claim 56
Independent Claim
149 words
A method of treating a photographic motion picture film comprising a poly(ethylene terephthalate) support and at least one imagewise-exposed and processed gelatino/silver halide emulsion layer, said film having scratches in said support which impair its projection capabilities, which method comprises (a) coating said support with a radiation-curable composition which fills in said scratches and forms a transparent, flexible, scratch-resistant, cross-linked polymeric layer upon radiation curing, said composition comprising (1) a polymerizable epoxy compound, (2) a cationic initiator for initiating polymerization of said epoxy compound, (3) a polymerizable acrylic compound, (4) a free-radical initiator for initiating polymerization of said acrylic compound, said free-radical initiator comprising a haloalkylated aromatic ketone, and (5) a polymerizable organofunctional silane and (b) subjecting said coating to radiation sufficient to cure it and bond it to said support, whereby the adverse effects of said scratches on the projection capabilities of said film are reduced or eliminated.
Claim 57
Independent Claim
149 words
A method of treating a photographic motion picture film comprising a poly(ethylene terephthalate) support and at least one imagewise-exposed and processed gelatino/silver halide emulsion layer, said film having scratches in said support which impair its projection capabilities, which method comprises (a) coating said support with a radiation-curable composition which fills in said scratches and forms a transparent, flexible, scratch-resistant, cross-linked polymeric layer upon radiation curing, said composition comprising (1) a polymerizable epoxy compound, (2) a cationic initiator for initiating polymerization of said epoxy compound, (3) a polymerizable acrylic compound, (4) a free-radical initiator for initiating polymerization of said acrylic compound, said free-radical initiator comprising a haloalkylated aromatic ketone, and (5) a polymerizable organofunctional silane and (b) subjecting said coating to radiation sufficient to cure it and bond it to said support, whereby the adverse effects of said scratches on the projection capabilities of said film are reduced or eliminated.
Claim 58
Independent Claim
149 words
A method of treating a photographic motion picture film comprising a cellulose triacetate support and at least one imagewise-exposed and processed gelatino/silver halide emulsion layer, said film having scratches in said support which impair its projection capabilities, which method comprises (a) coating said support with a radiation-curable composition which fills in said scratches and forms a transparent, flexible, scratch-resistant, cross-linked polymeric layer upon radiation curing, said composition comprising (1) a polymerizable epoxy compound, (2) a cationic initiator for initiating polymerization of said epoxy compound, (3) a polymerizable acrylic compound, (4) a free-radical initiator for initiating polymerization of said acrylic compound, said free-radical initiator comprising a haloalkylated aromatic ketone, and (5) a polymerizable organofunctional silane and (b) subjecting said coating to radiation sufficient to cure it and bond it to said support, whereby the adverse effects of said scratches on the projection capabilities of said film are reduced or eliminated.
Claim 59
Independent Claim
149 words
A method of treating a photographic motion picture film comprising a cellulose triacetate support and at least one imagewise-exposed and processed gelatino/silver halide emulsion layer, said film having scratches in said support which impair its projection capabilities, which method comprises (a) coating said support with a radiation-curable composition which fills in said scratches and forms a transparent, flexible, scratch-resistant, cross-linked polymeric layer upon radiation curing, said composition comprising (1) a polymerizable epoxy compound, (2) a cationic initiator for initiating polymerization of said epoxy compound, (3) a polymerizable acrylic compound, (4) a free-radical initiator for initiating polymerization of said acrylic compound, said free-radical initiator comprising a haloalkylated aromatic ketone, and (5) a polymerizable organofunctional silane and (b) subjecting said coating to radiation sufficient to cure it and bond it to said support, whereby the adverse effects of said scratches on the projection capabilities of said film are reduced or eliminated.
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-01-16 | 1987-07-18 | 1988-01-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-01-16 | 1991-07-18 | 1992-01-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-01-16 | 1995-07-18 | 1996-01-17 | $7700.00 | Window Closed / Lapsed |