Photosensitive resin compositions

Claim 2

A photosensitive resin composition which consists essentially of the following components: (A) a photopolymerizable unsaturated compound containing at least two terminal ethylene groups, (B) a reactive linear high molecular weight compound other than component (A) having in its side chain one or two functional groups selected from the class consisting of tetrahydrofurfuryl group and N-alkoxymethylcarbamoyl group, (C) a sensitizer capable of initiating polymerization of the unsaturated compound upon irradiation with active rays, (D) a compound other than components (A) and (B) having at least two epoxy groups, and (E) a latent curing agent for epoxy resins.

Claim 3

A photosensitive resin composition according to claim 1, wherein the photo-polymerizable unsaturated compound is an acrylic or methacrylic acid ester of a polyhydric alcohol.

Claim 4

A photosensitive resin composition according to claim 2, wherein the polyhydric alcohol is ethylene glycol, triethylene glycol, tetraethylene glycol, propylene glycol, trimethylolpropane, pentaerythritol or neopentyl glycol.

Claim 5

A photosensitive resin composition according to claim 1, wherein the photo-polymerizable unsaturated compound is an acrylic or methacrylic acid ester of an alkylene oxide adduct of bisphenol A.

Claim 6

A photosensitive resin composition according to claim 1, wherein the content of the photo-polymerizable unsaturated compound is 15 to 60% by weight based on the weight of the composition.

Claim 7

A photosensitive resin composition according to claim 1, wherein the reactive linear high molecular weight compound is a polymer of at least one monomer selected from the group consisting of monomers represented by the formulas, ##STR3## wherein R is hydrogen, methyl or ethyl, or ##STR4## wherein R is hydrogen or a C 1-4 alkyl and R' is hydrogen, a C 1-4 alkyl, nitrile or a halogen, or a copolymer of said monomer with another vinyl monomer.

Claim 8

A photosensitive resin composition according to clain 5, wherein the content of the reactive linear high molecular weight compound is 20 to 70% by weight based on the weight of the composition.

Claim 9

A photosensitive resin composition according to clain 5, wherein the content of the reactive linear high molecular weight compound is 20 to 70% by weight based on the weight of the composition.

Claim 10

A photosensitive resin composition according to claim 1, wherein the sensitizer is benzophenone, Michler's ketone, benzoin, a benzoin alkyl ether, 2-ethylanthraquinone, 3-t-butylanthraquinone or benzil.

Claim 11

A photosensitive resin composition according to claim 7, wherein the content of the sensitizer is 0.1 to 15% by weight based on the weight of the composition.

Claim 12

A photosensitive resin composition according to claim 1, wherein the compound having at least two epoxy groups is a novolac type epoxy resin prepolymer and its content is 5 to 50% by weight based on the weight of the composition.

Claim 13

A photosensitive resin composition according to claim 1, wherein the curing agent is a compound selected from the group consisting of boron trifluoride-amine complexes, amine tetrafluoroborates, dibasic acid hydrazides, alkylamine boranes, aromatic amine-inorganic acid complexes, extra-coordination silicates, dicyandiamide and N,N-diallylmelamine, and its content is 0.1 to 20% by weight based on the weight of the composition.

Claim 14

A photosensitive resin composition according to claim 1, wherein a thermal polymerization inhibitor, a plasticizer, a dye, a pigment and/or a filler is used as auxiliary components.

Claim 15

A photosensitive resin composition according to claim 1, wherein the content of the photo-polymerizable unsaturated compound is 10 to 90% by weight, the content of the reactive linear high molecular weight compound is 10-80% by weight, the content of the sensitizer is 0.1-15% by weight, the content of the compound having at least two epoxy groups is 5-80% by weight, and the content of the curing agent is from 0.2-12% by weight, said contents being based on the weight of the composition.

Claim 16

A photosensitive resin composition according to claim 1, wherein the photo-polymerizable unsaturated compound is an acrylic or methacrylic acid ester of a polyhydric alcohol; an acrylic or methacrylic acid ester of a bisphenol A-epichlorohydrin epoxy resin prepolymer; an acrylic or methacrylic acid ester of an alkylene oxide adduct of bisphenol A; methylene-bis-acrylamide, methylene-bis-methacrylamide, bis-acryl- or bis-methacryl-amide of a diamine; reaction product of diol monoacrylate or diol methacrylate with diisocyanate and triacryl formal or triallyl cyanurate; or a linear high molecular weight compound containing acryloyloxy or methacryloyloxy group in a side chain.

Claim 17

A photosensitive resin composition according to claim 1, wherein the reactive linear molecular weight compound comprises N-n-butoxymethylacrylamide-tetrahydrofurfuryl methacrylate copolymer, N-ethoxymethylacrylamide-tetrahydrofurfuryl methacrylate-methyl methacrylate copolymer, N-methoxymethylacrylamide-tetrahydrofurfuryl methacrylate-styrene copolymer, N-n-butoxymethylmethacrylamide-tetrahydrofurfuryl methacrylate-acrylonitrile copolymer, N-n-butoxymethylacrylamide-tetrahydrofurfuryl methacrylate-styrene-acrylonitrile copolymer, N-n-butoxy-methylacrylamide-methyl methacrylate copolymer, N-n-propoxyacrylamide-methyl methacrylate copolymer, N-n-butoxymethylmethacrylamide-ethyl methacrylate copolymer, N-n-butoxymethylacrylamide-acrylonitrile-styrene-methyl methacrylate copolymer, tetrahydrofurfuryl acrylate polymer, tetrahydrofurfuryl methacrylate polymer, tetrahydrofurfuryl acrylate-vinyl compound copolymer, and tetrahydrofurfuryl methacrylate-vinyl compound copolymer.

Claim 18

A photosensitive resin composition according to claim 1, wherein the compound having at least two epoxy compounds is an epoxy resin prepolymer or a vinyl copolymerization product of glycidyl methacrylate.

Claim 19

A photosensitive resin composition which consists essentially of (A) a photo-polymerizable unsaturated compound containing at least two terminal ethylene groups selected from the group consisting of acrylic or methacrylic acid ester of a polyhydric alcohol; an acrylic or methacrylic acid ester of a bisphenol A-epichlorohydrin epoxy resin prepolymer; an acrylic or methacrylic acid ester of an alkylene oxide adduct of bisphenol A; methylene-bis-acrylamide, methylene-bis-methacrylamide, bis-acryl- or bis-methacryl-amide of a diamine; reaction product of diol monoacrylate or diol methacrylate with diisocyanate and triacryl formal or triallyl cyanurate; and a linear high molecular weight compound containing acryloyloxy or methacryloyloxy group in a side chain, (B) a reactive linear high molecular weight compound having in its side chain one or two functional groups selected from the class consisting of tetrahydrofurfuryl group and N-alkoxymethylcarbamoyl group comprising a polymer of at least one monomer selected from the group consisting of monomers represented by the formulae: ##STR5## wherein R is hydrogen, methyl or ethyl, or ##STR6## wherein R is hydrogen or a C 1-4 alkyl and R' is hydrogen, a C 1-4 alkyl, nitrile or a halogen, or a copolymer of said monomer with another vinyl monomer, (C) a synthesizer selected from the group consisting of benzophenone, Michler's ketone, benzoin, a benzoin alkyl ether, 2-ethyl-anthraquinone, 3-t-butylanthraquinone and benzil, and (D) an epoxy resin having at least two epoxy groups and (E) a latent curing agent for said epoxy resin.

Claim 20

A photosensitive resin composition which consists essentially of (A) a photo-polymerizable unsaturated compound containing at least two terminal ethylene groups selected from the group consisting of acrylic or methacrylic acid ester of a polyhydric alcohol; an acrylic or methacrylic acid ester of a bisphenol A-epichlorohydrin epoxy resin prepolymer; an acrylic or methacrylic acid ester of an alkylene oxide adduct of bisphenol A; methylene-bis-acrylamide, methylene-bis-methacrylamide, bis-acryl- or bis-methacryl-amide of a diamine; reaction product of diol monoacrylate or diol methacrylate with diisocyanate and triacryl formal or triallyl cyanurate; and a linear high molecular weight compound containing acryloyloxy or methacryloyloxy group in a side chain, (B) a reactive linear high molecular weight compound having in its side chain one or two functional groups selected from the class consisting of tetrahydrofurfuryl group and N-alkoxymethylcarbamoyl group comprising a polymer of at least one monomer selected from the group consisting of monomers represented by the formulae: ##STR5## wherein R is hydrogen, methyl or ethyl, or ##STR6## wherein R is hydrogen or a C 1-4 alkyl and R' is hydrogen, a C 1-4 alkyl, nitrile or a halogen, or a copolymer of said monomer with another vinyl monomer, (C) a synthesizer selected from the group consisting of benzophenone, Michler's ketone, benzoin, a benzoin alkyl ether, 2-ethyl-anthraquinone, 3-t-butylanthraquinone and benzil, and (D) an epoxy resin having at least two epoxy groups and (E) a latent curing agent for said epoxy resin.

Claim 21

A photosensitive resin composition according to claim 17, wherein the epoxy resin is an epoxy resin prepolymer or a vinyl copolymerization product of glycidyl methacrylate.

Claim 22

A photosensitive resin composition according to claim 18, wherein the curing agent is a compound selected from the group consisting of boron trifluoride-amine complexes, amine tetrafluoroborates, dibasic acid hydrazides, alkylamine boranes, aromatic amine-inorganic acid complexes, extra-coordination silicates, dicyandiamide and N,N-diallylmelamine.

Claim 23

A photosensitive resin composition according to claim 19, wherein the content of the photo-polymerizable unsaturated compound is 10 to 90% by weight, the content of the reactive linear high molecular weight compound is 10-80% by weight, the content of the sensitizer is 0.1-15% by weight, the content of the compound having at least two epoxy groups is 5-80% by weight, and the content of the curing agent is from 0.2-12% by weight, said contents being based on the weight of the composition.