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US4423702A
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Method for desulfurization, denitrifaction, and oxidation of carbonaceous fuels
Assignee: Florida Power Corp
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Filing: 1983-03-09
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Granted: 1984-01-03
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Expires: 2003-03-09
Abstract
Abstract A method for desulfurization, denitrification, and oxidation, of carbonaceous fuels including a two stage oxidation technique. The carbonaceous fuel, containing ash, along with an oxygen-containing gas is introduced into a first stage partial oxidation unit containing a molten ash slag maintained at a temperature of about 2200°-2600° F. A flux may also be introduced into the first stage partial oxidation unit for the purpose of increasing the basicity and maintaining the viscosity of the molten ash slag at a value no greater than about 10 poise. The carbonaceous fuel is gasified, and sulfur is chemically bound and captured in the molten ash slag. Since the first stage is operated in a gasification mode (reducing atmosphere), essentially all of the nitrogen in the fuel is converted to diatomic nitrogen, which results in low nitrogen oxide emissions upon final combustion. The first stage is also designed to physically remove a major portion of the fuel ash, the ash leaving the system as a molten slag. The combustible gas derived from partial oxidation (gasification) is directed along a substantially horizontal path to a second stage oxidation unit for final combustion. The sulfur-containing molten slag is removed to a water-sealed quench system or indirect water cooled system for disposal.
Inventors
- 👤 Robert A. Ashworth
- 👤 Antonio A. Padilla
- 👤 Larry A. Rodriguez
- 👤 Ned B. Spake
- 👤 Warnie L. Sage
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 13:30
CPC Classifications
F; F23; F23B; F23B90/00; F23B90/04; F23B90/06; C; C10; C10B; C10B49/00; C10B49/14; C10G; C10G9/00; C10G9/34; C10G9/36; C10G9/38; C10J; C10J3/00; C10J3/46; C10J3/48; C10J3/52; C10J3/526; C10J3/57; C10J3/72; C10J3/74; C10J3/78; C10J3/82; C10J3/84; C10J3/845; C10L; C10L10/00; C10L10/02; C10L10/06; C10L9/00; C10L9/02; C10G2400/00; C10G2400/26; C10J2300/00; C10J2300/09; C10J2300/0903; C10J2300/0906; C10J2300/0913; C10J2300/093; C10J2300/0943; C10J2300/0946; C10J2300/0953; C10J2300/0956; C10J2300/0959; C10J2300/0973; C10J2300/0983; C10J2300/0996; C10J2300/12; C10J2300/1253; C10J2300/16; C10J2300/1603; C10J2300/1606; C10J2300/18; C10J2300/1846
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
127 words
A method for desulfurization, denitrification and oxidation of carbonaceous fuels, said method comprising the steps of: a. introducing said carbonaceous fuel into a first stage partial oxidation unit containing molten slag at a temperature of about 2,200° F.-2,600° F.; b. simultaneously introducing oxygen-containing gas into said first unit, whereby partial oxidation of said carbonaceous fuel occurs to generate a combustible gas and at least about 50-99%, by weight, of the sulfur content of the carbonaceous fuel is chemically captured in said slag, fuel nitrogen being essentially completely converted to diatomic nitrogen; c. transferring said combustible gas along a substantially horizontal path to a second stage oxidation unit for combustion; and d. removing said sulfur containing slag for disposal, said slag remaining in a reducing atmosphere until quenched.
Claim 2
Independent Claim
127 words
A method for desulfurization, denitrification and oxidation of carbonaceous fuels, said method comprising the steps of: a. introducing said carbonaceous fuel into a first stage partial oxidation unit containing molten slag at a temperature of about 2,200° F.-2,600° F.; b. simultaneously introducing oxygen-containing gas into said first unit, whereby partial oxidation of said carbonaceous fuel occurs to generate a combustible gas and at least about 50-99%, by weight, of the sulfur content of the carbonaceous fuel is chemically captured in said slag, fuel nitrogen being essentially completely converted to diatomic nitrogen; c. transferring said combustible gas along a substantially horizontal path to a second stage oxidation unit for combustion; and d. removing said sulfur containing slag for disposal, said slag remaining in a reducing atmosphere until quenched.
Claim 3
Dependent Claim
30 words
A method as in claim 1 further comprising selecting said carbonaceous fuel from the class consisting essentially of coal, coke, petroleum coke, fuel oil, mixtures thereof and aqueous mixtures thereof.
Claim 4
Dependent Claim
27 words
A method as in claim 2 further comprising grinding said coal to a particle size no greater than about 0.125 inch prior to said introducing step a.
Claim 5
Dependent Claim
44 words
A method as in claim 1 wherein a flux is simultaneously introduced into said first unit in sufficient quantity to provide a suitable basicity of said molten slag and to maintain the viscosity of said molten slag at no more than about 10 poise.
Claim 6
Dependent Claim
31 words
A method as in claim 4 wherein said fuel, said flux and said gas are secant-to-tangentially injected into said first unit through nozzles located above the surface of said molten slag.
Claim 7
Dependent Claim
43 words
A method as in claim 5 wherein said secant-to-tangential injection comprises pneumatically feeding said fuel, flux and gas, and mixtures thereof, through nozzles mounted downwardly toward said surface of said molten slag at an angle of about 25°-50° with respect to said surface.
Claim 8
Dependent Claim
19 words
A method as in claim 4 further comprising selecting said flux from the class consisting essentially of alkali minerals.
Claim 9
Dependent Claim
25 words
A method as in claim 7 further comprising selecting said flux from the class consisting essentially of lime, limestone, dolomite, trona, nacholite, and mixtures thereof.
Claim 10
Dependent Claim
29 words
A method as in claim 7 further comprising pulverizing said flux to a particle size no greater than about 70% less than 200 mesh prior to said introducing step.
Claim 11
Dependent Claim
57 words
A method as in claim 1 further comprising transferring said combustible gas and removing said sulfur containing slag along a partially common pathway prior to delivery of said sulfur containing slag to said quench system, whereby any slag droplets entrained by said combustible gas will tend to impinge on said sulfur containing slag and be retained therein.
Claim 12
Dependent Claim
36 words
A method as in claim 10 further comprising baffling said substantially horizontal path of said combustible gas, whereby said gas will be directed downwardly toward said sulfur containing slag as said gas enters said common pathway.
Claim 13
Dependent Claim
28 words
A method as in claim 11 further comprising passing said molten slag past said baffling step to said quench system without substantially restricting the flow of said slag.
Claim 14
Dependent Claim
12 words
A method as in claim 1 wherein said oxygen-containing gas is air.
Claim 15
Dependent Claim
14 words
A method as in claim 1 wherein said oxygen-containing gas is oxygen enriched air.
Claim 16
Dependent Claim
12 words
A method as in claim 1 wherein said oxygen-containing gas is oxygen.
Claim 17
Dependent Claim
25 words
A method as in claim 1 wherein said second stage oxidation unit comprises a boiler combustion unit, said combustible reducing gas being the fuel thereof.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-01-02 | 1987-07-04 | 1988-01-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-01-02 | 1991-07-04 | 1992-01-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-01-02 | 1995-07-04 | 1996-01-03 | $7700.00 | Window Closed / Lapsed |