Process for production of synthesis gas

Claim 2

A process for producing a synthesis gas capable of being upgraded to a pipeline gas, which process comprises: providing a reaction zone containing a molten salt consisting essentially of a major portion of sodium carbonate and a minor portion of at least 1 wt.% of sodium sulfide, said molten salt containing carbon in an amount of about 1 to 10% by weight of the molten salt and having a total solids concentration of less than about 25 wt.%, maintaining said molten salt at a temperature between about 1400° and 2000° F, introducing a sulfur-containing carbonaceous material, substanially pure oxygen, and recycled carbon dioxide from the process into said molten salt reaction zone, said substantially pure oxygen and carbon dioxide being introduced in an amount sufficient to provide about 0.6 to about 1.2 mole of carbon dioxide per mole of oxygen, controlling the foregoing conditions without the introduction of steam to promote CO production and decompose said carbonaceous material, whereby the sulfur component of the carbonaceous material is retained in the molten salt, the reaction being carried out at a pressure between 1 and 100 atmospheres, obtaining from said reaction zone an initial gaseous effluent containing carbon monoxide, hydrogen, hydrocarbons and carbon dioxide, and being essentially free of sulfur-containing pollutants, subjecting said gaseous effluent to a water gas shift reaction, recovering a resultant gaseous mixture of carbon dioxide, carbon monoxide and hydrogen from said shift reaction, removing the carbon dioxide from said resultant gaseous mixture, recycling a portion of said carbon dioxide for introduction thereof into said molten salt reaction zone, and separately recovering from the carbon dioxide removal process a substantially carbon-doxide-free synthesis gas capable of being upgraded to a pipeline gas.

Claim 3

A process as defined in claim 1, wherein said ratio of carbon dioxide to oxygen is between about 0.8 and about 1.1 mole of carbon dioxide per mole of oxygen.

Claim 4

A process as defined in claim 2, wherein said molten salt contains carbon in an amount of about 3.5 to about 7.5% by weight of the melt composition.

Claim 5

A process as defined in claim 3, wherein the molar ratio of carbon monoxide to carbon dioxide in said initial gaseous effluent is at least 9:1.

Claim 6

The process as defined in claim 2, wherein said temperature is between about 1600° and about 1800° F.

Claim 7

The process as defined in claim 1, wherein said carbonaceous material is selected from the group consisting of coal, coke, fuel oil, petroleum crude, petroleum residue, lignite and peat.

Claim 8

The process as defined in claim 1, wherein said carbonaceous material is coal, said process is carried out at a pressure between about 5 and about 30 atmospheres, and said initial gaseous effluent contains carbon monoxide, hydrogen and hydrocarbons as principal combustible components, together with carbon dioxide.

Claim 9

The process as defined in claim 7, wherein said molten salt is at a temperature between about 1600° and about 2000° F.

Claim 10

The process as defined in claim 1, wherein said water gas shift reaction is carried out so that the molar ratio of hydrogen to carbon monoxide in said gaseous mixture from said water gas shift reaction is about 3:1, and wherein, following said removal of carbon dioxide from said gas mixture, the resultant synthesis gas has a molar ratio of hydrogen to carbon monoxide of about 3:1 and is subjected to methanation, and wherein a pipeline gas consisting essentially of methane is recovered.

Claim 11

A process as defined in claim 1, wherein said water gas shift reaction is carried out so that the molar ratio of hydrogen to carbon monoxide in said gaseous mixture from said water gas shift reaction is about 2:1, and wherein, following said removal of carbon dioxide from said gaseous mixture, the resultant synthesis gas has a molar ratio of hydrogen to carbon monoxide of about 2:1 and is subjected to catalytic synthesis for production of methanol.

Claim 12

The process as defined in claim 8, wherein said molten salt contains carbon in an amount of about 3:5 to about 7.5% by weight of the melt composition, and the molar ratio of carbon monoxide to carbon dioxide in said initial gaseous effluent is at least 9:1.

Claim 13

A process for producing a pipeline gas which comprises providing a reaction zone containing a molten salt consisting essentially of sodium carbonate containing from about 1 to about 25 wt.% sodium sulfide, said molten salt containing carbon in an amount of about 3.5 to 7.5% by weight of the molten salt and having a total solids concentration of less than about 25 wt.%, maintaining said molten salt at a temperature between about 1600° and about 1800° F, introducing a sulfur-containing coal and a mixture of pure oxygen and recycled carbon dioxide from the process into said molten salt reaction zone, said mixture of oxygen and carbon dioxide consisting of about 0.8 to about 1 mole of carbon dioxide per mole of oxygen, controlling the foregoing conditions without the introduction of steam to promote CO production and decompose said coal, the reaction being carried out at a pressure between 5 and 30 atmospheres whereby the sulfur component of the coal is retained in the molten salt, obtaining from said reaction zone an initial gaseous effluent principally containing carbon monoxide, and also containing hydrogen, hydrocarbons and carbon dioxide, the molar ratio of carbon monoxide to carbon dioxide in said gaseous effluent being at least 9:1, said gaseous effluent having a BTU content of from about 250 to 325 BTU/scf and being essentially free of sulfur-containing pollutants, sugjecting said gaseous effluent to a water gas shift reaction carried out to provide a molar ratio of hydrogen to carbon monoxide in the resultant gaseous mixture from said water gas shift reaction of about 3:1, recovering said resultant gaseous mixture containing carbon dioxide, carbon monoxide and hydrogen, removing carbon dioxide from said last-mentioned mixture, recycling a portion of said carbon dioxide for admixture with oxygen prior to introduction thereof into said molten salt, subjecting the remaining synthesis gas mixture of hydrogen and carbon monoxide in a molar proportion of about 3:1 to methanation, and recovering a pipeline gas consisting essentially of methane.

Claim 14

A process for producing a pipeline gas which comprises providing a reaction zone containing a molten salt consisting essentially of sodium carbonate containing from about 1 to about 25 wt.% sodium sulfide, said molten salt containing carbon in an amount of about 3.5 to 7.5% by weight of the molten salt and having a total solids concentration of less than about 25 wt.%, maintaining said molten salt at a temperature between about 1600° and about 1800° F, introducing a sulfur-containing coal and a mixture of pure oxygen and recycled carbon dioxide from the process into said molten salt reaction zone, said mixture of oxygen and carbon dioxide consisting of about 0.8 to about 1 mole of carbon dioxide per mole of oxygen, controlling the foregoing conditions without the introduction of steam to promote CO production and decompose said coal, the reaction being carried out at a pressure between 5 and 30 atmospheres whereby the sulfur component of the coal is retained in the molten salt, obtaining from said reaction zone an initial gaseous effluent principally containing carbon monoxide, and also containing hydrogen, hydrocarbons and carbon dioxide, the molar ratio of carbon monoxide to carbon dioxide in said gaseous effluent being at least 9:1, said gaseous effluent having a BTU content of from about 250 to 325 BTU/scf and being essentially free of sulfur-containing pollutants, sugjecting said gaseous effluent to a water gas shift reaction carried out to provide a molar ratio of hydrogen to carbon monoxide in the resultant gaseous mixture from said water gas shift reaction of about 3:1, recovering said resultant gaseous mixture containing carbon dioxide, carbon monoxide and hydrogen, removing carbon dioxide from said last-mentioned mixture, recycling a portion of said carbon dioxide for admixture with oxygen prior to introduction thereof into said molten salt, subjecting the remaining synthesis gas mixture of hydrogen and carbon monoxide in a molar proportion of about 3:1 to methanation, and recovering a pipeline gas consisting essentially of methane.