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US4421900A Expired / Lapsed US ⏱️ 0.0 years remaining

Blends of natural and synthetic rubbers

Assignee: Bridgestone Firestone Inc
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Filing: 1982-04-16
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Granted: 1983-12-20
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Expires: 2002-04-16
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Abstract

Abstract A blend of natural and synthetic rubbers having processability and improved green strength and building tack is provided. The blend comprises from about 5 to 55 parts by weight of natural rubber, from about 30 to 50 parts by weight of a conjugated diene-containing synthetic rubber and, from about 5 to 50 parts by weight of a substituted acrylamide-containing synthetic rubber. The latter synthetic rubber comprises from about 0.3 to 10 percent by weight of an N-(alkoxymethyl)acrylamide monomer, based upon the weight of the substituted acrylamide-containing rubber.

Inventors

  • 👤 Gary R. Hamed

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 18:50
CPC Classifications
C; C08; C08L; C08L7/00; C08F; C08F236/00; C08F236/02; C08F236/04; C08L9/00; C08L9/06

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 304 words
A blend of natural and synthetic rubbers having processability and improved green strength and tack, said blend comprising: from about 5 to 55 parts by weight of natural rubber; from about 30 to 50 parts by weight of a conjugated diene-containing synthetic rubber having an average molecular weight of from about 50×10 3 to about 800×10 3 ; and from about 5 to 50 parts by weight of a substituted acrylamide-containing synthetic rubber having an average molecular weight of from about 50×10 3 to about 500×10 3 ; wherein said conjugated diene-containing synthetic rubber is selected from the group consisting of conjugated diene homopolymers and copolymers, prepared from conjugated diene monomers having from four to about 12 carbon atoms, with monomers containing a vinyl group selected from the group consisting of monovinyl aromatic compounds having from eight to about 20 carbon atoms and acrylic compounds having from three to about five carbon atoms including halogen-substituted compounds; said substituted acrylamide-containing synthetic rubber comprises from about 60 to 99.7 percent by weight of said conjugated diene monomer; from about 0 to 39.7 percent by weight of said monomer containing a vinyl group and copolymerizable with said conjugated diene monomer; and from about 0.3 to 10 percent by weight of an N-(alkoxymethyl)acrylamide monomer having the formula ##STR2## wherein R is a straight or branched alkyl chain having from 1 to about 20 carbon atoms, the weight of each said monomer component being based upon the total weight of said substituted acrylamide-containing synthetic rubber; and wherein said blend is based upon the following relationship: A+B≧C C+A≧B wherein A is equal to the parts by weight of said natural rubber, B is equal to the parts by weight of said conjugated diene-containing synthetic rubber, and C is equal to the parts by weight of said substituted acrylamide-containing synthetic rubber.
Claim 2
Dependent Claim 304 words
A blend of natural and synthetic rubbers having processability and improved green strength and tack, said blend comprising: from about 5 to 55 parts by weight of natural rubber; from about 30 to 50 parts by weight of a conjugated diene-containing synthetic rubber having an average molecular weight of from about 50×10 3 to about 800×10 3 ; and from about 5 to 50 parts by weight of a substituted acrylamide-containing synthetic rubber having an average molecular weight of from about 50×10 3 to about 500×10 3 ; wherein said conjugated diene-containing synthetic rubber is selected from the group consisting of conjugated diene homopolymers and copolymers, prepared from conjugated diene monomers having from four to about 12 carbon atoms, with monomers containing a vinyl group selected from the group consisting of monovinyl aromatic compounds having from eight to about 20 carbon atoms and acrylic compounds having from three to about five carbon atoms including halogen-substituted compounds; said substituted acrylamide-containing synthetic rubber comprises from about 60 to 99.7 percent by weight of said conjugated diene monomer; from about 0 to 39.7 percent by weight of said monomer containing a vinyl group and copolymerizable with said conjugated diene monomer; and from about 0.3 to 10 percent by weight of an N-(alkoxymethyl)acrylamide monomer having the formula ##STR2## wherein R is a straight or branched alkyl chain having from 1 to about 20 carbon atoms, the weight of each said monomer component being based upon the total weight of said substituted acrylamide-containing synthetic rubber; and wherein said blend is based upon the following relationship: A+B≧C C+A≧B wherein A is equal to the parts by weight of said natural rubber, B is equal to the parts by weight of said conjugated diene-containing synthetic rubber, and C is equal to the parts by weight of said substituted acrylamide-containing synthetic rubber.
Claim 3
Dependent Claim 31 words
A blend, as set forth in claim 1, wherein said conjugated diene monomer is 1,3-butadiene, said monomer containing a vinyl group is styrene and said conjugated diene-containing rubber is styrene-butadiene rubber.
Claim 4
Dependent Claim 27 words
A blend, as set forth in claim 1, comprising: 30 parts of natural rubber; 40 parts of styrene-butadiene rubber; and 30 parts of an N-(isobutoxymethyl)acrylamide-containing styrene-butadiene rubber.

References Cited (Backward Citations)

US3037963B1 Cited
US3037963A Cited
US3118852A Cited
US3247139A Cited
US3405200A Cited
US3798190A Cited
US3832317A Cited
US4254013A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-12-19 1987-06-20 1987-12-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-12-19 1991-06-20 1991-12-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-12-19 1995-06-20 1995-12-20 $7700.00 Window Closed / Lapsed

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