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US4421528A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for making a modified silicon aluminum oxynitride based composite cutting tool

Assignee: Verizon Laboratories Inc
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Filing: 1982-05-20
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Granted: 1983-12-20
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Expires: 2002-05-20
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Abstract

Abstract An improved modified silicon aluminum oxynitride based composite cutting tool is made by forming a homogeneous matrix of a modified silicon aluminum oxynitride prior to uniformly dispersing a hard refractory material throughout the homogeneous matrix, then densifying the combined materials to form a composite cutting tool having a density greater than 98 percent of the theoretical density of the combined materials.

Inventors

  • 👤 Sergej-Tomislav Buljan
  • 👤 Vinod K. Sarin

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 12:02
CPC Classifications
B; B23; B23B; B23B27/00; B23B27/14; B23B27/148; C; C04; C04B; C04B35/00; C04B35/515; C04B35/58; C04B35/584; C04B35/593; C04B35/597

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 179 words
A process for obtaining an abrasion resistant cutting tool having a hard refractory material distributed in a homogeneous matrix containing a modified silicon aluminum oxynitride comprising: mixing from about 20 to about 90 volume percent silicon nitride, from about 5 to about 60 volume percent aluminum oxide, and from about 20 to about 25 volume percent of a modifier to form a mixture; reacting said mixture at a temperature from about 1400° C. to about 1800° C. for a period of time from about one to about eight hours in a non-oxidizing atmosphere to form a reacted mixture; comminuting a blend comprising from about 40 to about 95 volume percent of said reacted mixture and from about 5 to about 60 volume percent of a hard refractory material to form a composite blend; and densifying said composite blend to form a homogeneous matrix of said reacted mixture having a dispersed phase of said hard refractory material throughout said homogeneous matrix, said densifying being sufficient to obtain a density greater than 98 percent of theoretical density of said composite blend.
Claim 2
Dependent Claim 179 words
A process for obtaining an abrasion resistant cutting tool having a hard refractory material distributed in a homogeneous matrix containing a modified silicon aluminum oxynitride comprising: mixing from about 20 to about 90 volume percent silicon nitride, from about 5 to about 60 volume percent aluminum oxide, and from about 20 to about 25 volume percent of a modifier to form a mixture; reacting said mixture at a temperature from about 1400° C. to about 1800° C. for a period of time from about one to about eight hours in a non-oxidizing atmosphere to form a reacted mixture; comminuting a blend comprising from about 40 to about 95 volume percent of said reacted mixture and from about 5 to about 60 volume percent of a hard refractory material to form a composite blend; and densifying said composite blend to form a homogeneous matrix of said reacted mixture having a dispersed phase of said hard refractory material throughout said homogeneous matrix, said densifying being sufficient to obtain a density greater than 98 percent of theoretical density of said composite blend.
Claim 3
Dependent Claim 30 words
A process according to claim 1 wherein: said modifier is an oxide selected from the group consisting of Si, Y, Hf, Ce, Zr, Mg, Be, the lanthanides, and combinations thereof.
Claim 4
Dependent Claim 35 words
A process according to claim 1 wherein said hard refractory material is selected from the group consisting of TiC, TiN, Ti(C,N), HfC, HfN, Hf(C,N), WC, W(C,N), VC, VN, V(C,N), TaC, TaN, Ta(C,N), and combinations thereof.
Claim 5
Dependent Claim 28 words
A process according to claim 1 wherein: said hard refractory material is a carbide selected from the group consisting of TiC, HfC, WC, VC, TaC, and combinations thereof.
Claim 6
Dependent Claim 25 words
A process according to claim 1 wherein: said hard refractory material is a nitride selected from the group consisting of TiN, HfN, and combinations thereof.
Claim 7
Dependent Claim 25 words
A process according to claim 1 wherein: said hard refractory material is a carbonitride selected from the group consisting of Ti(C,N), Hf(C,N), and combinations thereof.
Claim 8
Dependent Claim 22 words
A process according to claim 1 wherein: said mixture is heated to a temperature from about 1600° C. to about 1800° C.
Claim 9
Dependent Claim 25 words
A process according to claim 1 wherein: said non-oxidizing atmosphere is a gas selected from the group consisting of nitrogen, helium, argon, and combinations thereof.
Claim 10
Dependent Claim 82 words
A process according to claim 1 wherein said densifying comprises: pressing said composite blend to form a composite body; and sintering said composite body at a sintering temperature from about 1600° C. to about 1800° C. in an inert gas atmosphere to form a homogeneous matrix of said reacted mixture having a dispersed phase of said hard refractory material throughout said homogeneous matrix, said densifying being sufficient to obtain a density greater than 98 percent of theoretical density of said composite blend.
Claim 11
Dependent Claim 19 words
A process according to claim 9 wherein: said sintering temperature is from about 1700° C. to about 1800° C.
Claim 12
Dependent Claim 25 words
A process according to claim 9 wherein: said inert gas atmosphere is a gas selected from the group consisting of nitrogen, argon, and combinations thereof.
Claim 13
Dependent Claim 82 words
A process according to claim 1 wherein said densifying comprises: hot-pressing said composite blend at a pressure greater than 2000 psig (13,790 kN/M 2 ) and a temperature from about 1600° C. to about 1900° C. in an inert gas atmosphere to form a homogeneous matrix of said reacted mixture having a dispersed phase of said hard refractory material throughout said homogeneous matrix, said densifying being sufficient to obtain a density greater than 98 percent of theoretical density of said composite blend.
Claim 14
Dependent Claim 21 words
A process according to claim 12 wherein: said temperature of said hot-pressing is from about 1700° C. to about 1900° C.
Claim 15
Dependent Claim 25 words
A process according to claim 12 wherein: said inert gas atmosphere is a gas selected from the group consisting of nitrogen, argon, and combinations thereof.
Claim 16
Dependent Claim 90 words
A process according to claim 1 wherein said densifying comprises: gas overpressure sintering at a gas overpressure from about 150 psig to about 200 psig (about 1,030 to about 1,380 kN/M 2 ) and a temperature from about 1600° C. to about 1950° C. in an inert gas atmosphere to form a homogeneous matrix of said reacted mixture having a dispersed phase of said hard refractory material throughout said homogeneous matrix, said densifying being sufficient to obtain a density greater than 98 percent of theoretical density of said composite blend.
Claim 17
Dependent Claim 23 words
A process according to claim 15 wherein: said temperature of said gas overpressure sintering is from about 1700° C. to about 1950° C.
Claim 18
Dependent Claim 25 words
A process according to claim 15 wherein: said inert gas atmosphere is a gas selected from the group consisting of nitrogen, argon, and combinations thereof.
Claim 19
Dependent Claim 80 words
A process according to claim 1 wherein said densifying comprises: hot-isostatic pressing at a pressure greater than 10,000 psig (68,947 kN/M 2 ) and a temperature from about 1600° C. to about 1900° C. in an inert gas atmosphere to form a homogeneous matrix of said reacted mixture having a dispersed phase of said hard refractory material throughout said homogeneous matrix, said densifying being sufficient to obtain a density greater than 98 percent of theoretical density of said composite blend.
Claim 20
Dependent Claim 22 words
A process according to claim 18 wherein: said temperature of said hot-isostatic pressing is from about 1700° C. to about 1800° C.
Claim 21
Dependent Claim 25 words
A process according to claim 18 wherein: said inert gas atmosphere is a gas selected from the group consisting of nitrogen, argon, and combinations thereof.

References Cited (Backward Citations)

DE2353093C3 Cited
US4131459A Cited
SU537986A1 Cited
US4252768A Cited
US4113503A Cited
US4147759A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-12-19 1987-06-20 1987-12-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-12-19 1991-06-20 1991-12-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-12-19 1995-06-20 1995-12-20 $7700.00 Window Closed / Lapsed

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