US4419407A
Expired / Lapsed
US
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Elastomeric coating compositions
Assignee: PPG Industries Ohio Inc
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Filing: 1982-01-29
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Granted: 1983-12-06
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Expires: 2002-01-29
Abstract
Abstract High solids thermosetting elastomeric coating compositions are disclosed. The resinous binder of the coating compositions is based on a hard polyester polyol containing cyclic moieties plasticized with a soft polyurethane polyol and cured with a curing agent capable of reacting with active hydrogens, for example, an aminoplast curing agent. The coating compositions are particularly useful on elastomeric substrates such as high density polyurethane foams, as well as on metal substrates such as steel and aluminum.
Inventors
- 👤 Robert M. Piccirilli
- 👤 Wen-Hsuan Chang
- 👤 Samuel Porter, Jr.
- 👤 James B. O'Dwyer
- 👤 Kyu-Wang Lee
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 14:54
CPC Classifications
C; C09; C09D; C09D167/00; C08; C08G; C08G18/00; C08G18/06; C08G18/08; C08G18/10; C08G18/28; C08G18/40; C08G18/4009; C08G18/42; C08G18/4205; C08G18/423; C09D175/00; C09D175/04; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31551
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
275 words
A thermosetting, elastomeric coating composition sprayable at resin solids content of at least 40 percent by weight and being flexible such that when the coating composition is deposited on an elastomeric substrate and cured, the coated substrate can be bent around a 1/4-inch mandrel with the coating facing outwardly and the coating exhibits no breaks or cracks when tested at 70-75° F., comprising as the film-forming constituents: (A) a hard polyester polyol having at least 20 percent by weight cyclic moieties and the percentage of cyclic moieties being not greater than that required to achieve said flexibility, having a hydroxyl value of at least 80 and the hydroxyl value being not greater than that required to achieve said flexibility, a molecular weight of 300 or greater but not greater than that required for formulating said coating composition with a sprayability of at least 40 percent by weight, and said polyester polyol having a Sward Hardness value of at least 15, (B) a polyurethane polyol having a molecular weight of 2,000 or greater but not greater than that required for formulating said coating composition with a sprayability of at least 40 percent by weight, and said polyurethane polyol having a Sward Hardness value of less than 10, and (C) a curing agent capable of reacting with the active hydrogens in (A) and (B) to form a crosslinked coating selected from the class consisting of aminoplast and polyisocyanates; the difference in Sward Hardness values between (A) and (B) being greater than 10; the ratio of (A)+(B):(C) being within the range of 5 to 0.5:1; the weight ratio of (A)+(C):(B) being within the range of 100 to 1:1.
Claim 2
Dependent Claim
275 words
A thermosetting, elastomeric coating composition sprayable at resin solids content of at least 40 percent by weight and being flexible such that when the coating composition is deposited on an elastomeric substrate and cured, the coated substrate can be bent around a 1/4-inch mandrel with the coating facing outwardly and the coating exhibits no breaks or cracks when tested at 70-75° F., comprising as the film-forming constituents: (A) a hard polyester polyol having at least 20 percent by weight cyclic moieties and the percentage of cyclic moieties being not greater than that required to achieve said flexibility, having a hydroxyl value of at least 80 and the hydroxyl value being not greater than that required to achieve said flexibility, a molecular weight of 300 or greater but not greater than that required for formulating said coating composition with a sprayability of at least 40 percent by weight, and said polyester polyol having a Sward Hardness value of at least 15, (B) a polyurethane polyol having a molecular weight of 2,000 or greater but not greater than that required for formulating said coating composition with a sprayability of at least 40 percent by weight, and said polyurethane polyol having a Sward Hardness value of less than 10, and (C) a curing agent capable of reacting with the active hydrogens in (A) and (B) to form a crosslinked coating selected from the class consisting of aminoplast and polyisocyanates; the difference in Sward Hardness values between (A) and (B) being greater than 10; the ratio of (A)+(B):(C) being within the range of 5 to 0.5:1; the weight ratio of (A)+(C):(B) being within the range of 100 to 1:1.
Claim 3
Dependent Claim
215 words
A thermosetting, elastomeric coating composition sprayable at resin solids content of at least 45 percent by weight and being flexible such that when the coating composition is deposited on an elastomeric substrate and cured, the coated substrate can be bent around a 1/4-inch mandrel with the coating facing outwardly and the coating exhibits no breaks or cracks when tested at 70-75° F., comprising as the film-forming constituents: (A) a hard polyester polyol having 20 to 70 percent by weight cyclic moieties and 15 to 80 percent by weight neopentyl moieties, said polyester having a hydroxyl value of 200 to 350, a molecular weight of 300 or greater but less than 1000, and a Sward Hardness value of 20 to 40, (B) a polyurethane polyol having a molecular weight of 2,000 to 10,000 and a Sward Hardness value of less than 10, and (C) a curing agent capable of reacting with the active hydrogens in (A) and (B) to form a crosslinked coating selected from the class consisting of aminoplast and polyisocyanates; the difference in Sward Hardness values between (A) and (B) being within the range of 20 to 40 inclusive; the ratio of (A)+(B):(C) being within the range of 2 to 1:1; the weight ratio of (A)+(C):(B) being within the range of 9 to 1:1.
Claim 4
Dependent Claim
215 words
A thermosetting, elastomeric coating composition sprayable at resin solids content of at least 45 percent by weight and being flexible such that when the coating composition is deposited on an elastomeric substrate and cured, the coated substrate can be bent around a 1/4-inch mandrel with the coating facing outwardly and the coating exhibits no breaks or cracks when tested at 70-75° F., comprising as the film-forming constituents: (A) a hard polyester polyol having 20 to 70 percent by weight cyclic moieties and 15 to 80 percent by weight neopentyl moieties, said polyester having a hydroxyl value of 200 to 350, a molecular weight of 300 or greater but less than 1000, and a Sward Hardness value of 20 to 40, (B) a polyurethane polyol having a molecular weight of 2,000 to 10,000 and a Sward Hardness value of less than 10, and (C) a curing agent capable of reacting with the active hydrogens in (A) and (B) to form a crosslinked coating selected from the class consisting of aminoplast and polyisocyanates; the difference in Sward Hardness values between (A) and (B) being within the range of 20 to 40 inclusive; the ratio of (A)+(B):(C) being within the range of 2 to 1:1; the weight ratio of (A)+(C):(B) being within the range of 9 to 1:1.
Claim 5
Dependent Claim
21 words
The coating composition of claims 1 or 2 sprayable at a resin solids content of 45 to 65 percent by weight.
Claim 6
Dependent Claim
15 words
The coating composition of claim 1 comprising 20 to 70 percent by weight cyclic moieties.
Claim 7
Dependent Claim
15 words
The coating composition of claims 1 or 4 in which the cyclic moieties are cycloaliphatic.
Claim 8
Dependent Claim
13 words
The coating composition of claim 1 in which the polyester contains neopentyl moieties.
Claim 9
Dependent Claim
32 words
The coating composition of claims 1 or 2 in which the polyester polyol is formed from reacting a cycloaliphatic dicarboxylic acid or its functional equivalent thereof with a polyol containing neopentyl groups.
Claim 10
Dependent Claim
30 words
The coating composition of claim 7 in which the cycloaliphatic dicarboxylic acid is selected from the class consisting of hexahydrophthalic acid and dimethylcyclohexane dicarboxylic acid or their functional equivalents thereof.
Claim 11
Dependent Claim
26 words
The coating composition of claim 7 in which the polyol containing neopentyl group branching is selected from the class consisting of 2,2-dimethyl-3-hydroxypropyl 2,2-dimethyl-3-hydroxypropionate and neopentyl glycol.
Claim 12
Dependent Claim
19 words
The coating composition of claim 1 in which the polyester polyol has a molecular weight of 1000 or less.
Claim 13
Dependent Claim
34 words
The coating composition of claims 1 or 2 in which the aminoplast is a melamine-, urea- or benzoguanamineformaldehyde condensate etherified with an alcohol containing 1 to 4 carbon atoms including mixtures of such alcohols.
Claim 14
Dependent Claim
16 words
The coating composition of claims 1 or 2 in which the polyisocyanate is a blocked polyisocyanate.
Claim 15
Dependent Claim
17 words
The coating composition of claims 1 or 2 in which the polyurethane polyol is a polyester-polyurethane polyol.
Claim 16
Dependent Claim
20 words
The coating composition of claims 1 or 2 in which the polyurethane polyol has a molecular weight less than 5000.
Claim 17
Dependent Claim
13 words
A coated article coated with the coating composition of claims 1 or 2.
Claim 18
Dependent Claim
17 words
The coated article of claim 15 which has a colored base coat and a clear top coat.
References Cited (Backward Citations)
US2734876A
Cited
US2720500A
Cited
US2967840A
Cited
US3535287A
Cited
US3464938A
Cited
US3477976A
Cited
US3668275A
Cited
US3668276A
Cited
US3668277A
Cited
US3678128A
Cited
US3691258A
Cited
US3624232A
Cited
US3912790A
Cited
US3852375A
Cited
US3819757A
Cited
US3994851A
Cited
US3928265A
Cited
US3962522A
Cited
GB1477008A
Cited
US3907736A
Cited
US3957709A
Cited
US4169825A
Cited
US4025474A
Cited
US4093675A
Cited
US4104240A
Cited
US4054614A
Cited
US4101603A
Cited
US4113793A
Cited
US4088619A
Cited
US4154891A
Cited
US4165307A
Cited
US4204014A
Cited
US4158652A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-12-05 | 1987-06-06 | 1987-12-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-12-05 | 1991-06-06 | 1991-12-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-12-05 | 1995-06-06 | 1995-12-06 | $7700.00 | Window Closed / Lapsed |