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US3962522A Expired / Lapsed US ⏱️ 0.0 years remaining

Poly(esterurethane) coating cured with an aminoplast on a solid substrate

Assignee: PPG Industries Inc
•
Filing: 1975-04-21
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Granted: 1976-06-08
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Expires: 1995-04-21
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Abstract

Abstract Cured coatings having a high degree of extensibility and other desirable properties are obtained from compositions comprising a hydroxyl-containing, urethane reaction product containing a polyester component and an amine-aldehyde resin. Preferred compositions contain a polymeric polyol of low glass transition temperature. These compositions are storage-stable in one package, and the cured coatings are adherent, durable and highly extensible. These coatings are particularly useful on resilient and rubbery substrates, such as foam rubber, polyurethane foam and vinyl foam, and on soft metal surfaces such as mild steel and aluminum.

Inventors

  • 👤 Wen-Hsuan Chang
  • 👤 Marvis E. Hartman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 15:45
CPC Classifications
C; C08; C08J; C08J7/00; C08J7/04; C08J7/0427; C08J7/043; C08J7/046; C08J2475/00; Y; Y10; Y10T; Y10T428/00; Y10T428/249921; Y10T428/249953; Y10T428/249987; Y10T428/249991; Y10T428/31504; Y10T428/31551; Y10T428/31554; Y10T428/31678; Y10T428/31681

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 215 words
A coated article comprising a solid substrate having thereon a cured coating comprising the reaction product of: A. an ungelled hydroxyl-containing urethane reaction product of an organic polyisocyanate and a polyhydric material, wherein a major portion of said polyhydric material is a saturated polyester polyol; said polyester polyol being selected from the class consisting of: 1. condensates of i. an alcohol component having an average functionality of at least about 1.9, and ii. a saturated acid component consisting essentially of 1 or more monomeric carboxylic acids or anhydrides having 2 to 14 carbon atoms per molecule, said component having an average functionality of at least about 1.9; and 2. a lactone-polyester formed from reacting lactones or mixtures of lactones in which the lactone has the following structural formula: ##EQU2## wherein n is at least 4, at least n + 2R's are hydrogen, and the remaining R's are substituents selected from the group consisting of hydrogen, alkyl, cycloalkyl, alkoxy and single ring aromatic hydrocarbon radicals with a polyol or a hydroxy acid; said polyhydric material containing a total of not more than one gram-mole of compounds having a functionality of 3 or more per 500 grams of polyhydric material; said urethane reaction product having a hydroxyl value of at least 10; and b. an amine-aldehyde condensate.
Claim 2
Dependent Claim 215 words
A coated article comprising a solid substrate having thereon a cured coating comprising the reaction product of: A. an ungelled hydroxyl-containing urethane reaction product of an organic polyisocyanate and a polyhydric material, wherein a major portion of said polyhydric material is a saturated polyester polyol; said polyester polyol being selected from the class consisting of: 1. condensates of i. an alcohol component having an average functionality of at least about 1.9, and ii. a saturated acid component consisting essentially of 1 or more monomeric carboxylic acids or anhydrides having 2 to 14 carbon atoms per molecule, said component having an average functionality of at least about 1.9; and 2. a lactone-polyester formed from reacting lactones or mixtures of lactones in which the lactone has the following structural formula: ##EQU2## wherein n is at least 4, at least n + 2R's are hydrogen, and the remaining R's are substituents selected from the group consisting of hydrogen, alkyl, cycloalkyl, alkoxy and single ring aromatic hydrocarbon radicals with a polyol or a hydroxy acid; said polyhydric material containing a total of not more than one gram-mole of compounds having a functionality of 3 or more per 500 grams of polyhydric material; said urethane reaction product having a hydroxyl value of at least 10; and b. an amine-aldehyde condensate.
Claim 3
Dependent Claim 14 words
The coated article of claim 1 in which said substrate is a polyurethane foam.
Claim 4
Dependent Claim 26 words
The coated article of claim 1 in which said composition includes as an additional component a polymeric polyol having a glass transition temperature below about 25°C.
Claim 5
Dependent Claim 14 words
The coated article of claim 3 in which said polymeric polyol is a poly(oxyalkylene)glycol.
Claim 6
Dependent Claim 12 words
The coated article of claim 4 in which said poly(oxyalkylene)glycol is poly(oxytetramethylene)glycol.
Claim 7
Dependent Claim 15 words
The coated article of claim 3 in which said polymeric polyol is a polyester polyol.
Claim 8
Dependent Claim 23 words
The coated article of claim 1 in which said aminealdehyde condensate is an alkylated condensation product of formaldehyde with melamine, urea, or benzoguanamine.
Claim 9
Dependent Claim 12 words
The coated article of claim 1 in which the lactone is epsilon-caprolactone.

References Cited (Backward Citations)

US2625535A Cited
US2856474A Cited
US3148173A Cited
US3384606A Cited
US3368988A Cited
US3457324A Cited
US3759873A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-06-08 1979-12-08 1980-06-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-06-08 1983-12-08 1984-06-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-06-08 1987-12-08 1988-06-08 $7700.00 Window Closed / Lapsed

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