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US4419390A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for rendering non-platable semiconductor substrates platable

Assignee: Individual
•
Filing: 1980-09-29
•
Granted: 1983-12-06
•
Expires: 2000-09-29
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Abstract

Abstract A process and compositions are described for the reception of electrolytic or electroless plating onto non-platable substrates, in particular, semiconductor substrates. The process comprises immersion of the non-platable substrate in a promoter composition containing primary metal ions, selected from the group consisting of nickel, cobalt, iron, and copper, and mixtures thereof, and a suitable reducing agent. The reducing agent is capable of chemically reacting with the non-platable substrate and the primary metal ions and the concentration of the reducing agent relative to the primary metal ions is so adjusted as to permit the initial chemical interaction of the reducing agent with the non-platable substrate and then the heterogeneous reduction of some of the primary metal ions present in the promoter composition. In addition, the promoter composition also comprises other metal ions selected from the group consisting of tin, cadmium, zinc, thallium, and lead and mixtures thereof, the other metal ions being in a sufficient concentration to inhibit the growth of metallic sites formed at the conclusion of the immersion of the non-platable substrate in the promoter composition.

Inventors

  • 👤 Nathan Feldstein

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 19:17
CPC Classifications
C; C23; C23C; C23C18/00; C23C18/16; C23C18/1601; C23C18/1633; C23C18/1646; C23C18/165; C23C18/1651; C23C18/18; C23C18/1851; C23C18/1872; C23C18/1886; C23C18/1893; C23C18/20; C23C18/2006; C23C18/2046; C23C18/2073; C23C18/2086; C23C18/22; C23C18/28; C23C18/285; C23C18/31; C23C18/32; C23C18/34; H; H05; H05K; H05K1/00; H05K1/02; H05K1/03; H05K1/0306; H05K3/00; H05K3/10; H05K3/18; H05K3/181; H05K3/22; H05K3/24; H05K3/244; H05K3/245

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 216 words
A process for rendering a non-platable substrate platable by conventional electroless plating, said process resulting in the deposition of metallic sites, said sites being catalytic to said conventional electroless plating, said substrate selected from the group consisting of silicon, germanium, and III-V compounds, comprising the step of immersing said non-platable substrate into a promoter composition wherein said promoter composition is a single composition which comprises a suitable reducing agent and primary metal ions selected from the group consisting of nickel, cobalt, and iron wherein said reducing agent is capable of chemically reacting with said non-platable substrate and said primary metal ions and further wherein the concentration of said reducing agent relative to said primary metal ions is so adjusted as to permit the initial chemical interaction of the reducing agent with the non-platable substrate and then the heterogeneous reduction of some of the primary metal ions present in the promoter composition, and further wherein said promoter composition also comprises other metal ions selected from the group consisting of tin, cadmium, zinc, thallium, and lead and mixtures thereof, said other metal ions being present in a lower concentration relative to said reducing agent and in a sufficient concentration to inhibit the growth of said metallic sites and further wherein said process is prior to conventional electroless plating.
Claim 2
Dependent Claim 216 words
A process for rendering a non-platable substrate platable by conventional electroless plating, said process resulting in the deposition of metallic sites, said sites being catalytic to said conventional electroless plating, said substrate selected from the group consisting of silicon, germanium, and III-V compounds, comprising the step of immersing said non-platable substrate into a promoter composition wherein said promoter composition is a single composition which comprises a suitable reducing agent and primary metal ions selected from the group consisting of nickel, cobalt, and iron wherein said reducing agent is capable of chemically reacting with said non-platable substrate and said primary metal ions and further wherein the concentration of said reducing agent relative to said primary metal ions is so adjusted as to permit the initial chemical interaction of the reducing agent with the non-platable substrate and then the heterogeneous reduction of some of the primary metal ions present in the promoter composition, and further wherein said promoter composition also comprises other metal ions selected from the group consisting of tin, cadmium, zinc, thallium, and lead and mixtures thereof, said other metal ions being present in a lower concentration relative to said reducing agent and in a sufficient concentration to inhibit the growth of said metallic sites and further wherein said process is prior to conventional electroless plating.
Claim 3
Dependent Claim 22 words
The process according to claim 1 wherein the concentration of said reducing agent is in molar excess to said primary metal ions.
Claim 4
Dependent Claim 13 words
The process according to claim 1 wherein said primary metal ions are nickel.
Claim 5
Dependent Claim 15 words
The process according to claim 1 wherein said promoter composition is used above room temperature.
Claim 6
Dependent Claim 16 words
The process according to claim 1 wherein said reducing agent is dimethylamine borane and/or its derivatives.
Claim 7
Dependent Claim 16 words
The process according to claim 1 wherein said reducing agent is a borohydride and/or its derivatives.
Claim 8
Dependent Claim 15 words
The process according to claim 1 wherein said reducing agent is hydrazine and/or its derivatives.
Claim 9
Dependent Claim 65 words
The process according to claim 1, wherein said promoter composition further contains secondary metal ions capable of reacting with said reducing agent selected from the group consisting of palladium, gold, silver, and platinum and mixtures thereof said secondary metal ions being in a concentration such as to permit their reaction with the reducing agent in a fashion similar to that of the primary metal ions.
Claim 10
Dependent Claim 12 words
The process according to claim 1 wherein said non-platable substrate is silicon.

References Cited (Backward Citations)

US3096182A Cited
US3666529A Cited
US3671291A Cited
US3853590A Cited
SU429483A1 Cited
US3772056A Cited
US3962494A Cited
US4002778A Cited
US3870526A Cited
US3958048A Cited
US3993801A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-12-05 1987-06-06 1987-12-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-12-05 1991-06-06 1991-12-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-12-05 1995-06-06 1995-12-06 $7700.00 Window Closed / Lapsed

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