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Method for forming a pattern in a thin-film transistor having tellurium semiconductor layer

Assignee: Sharp Corp
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Filing: 1981-02-25
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Granted: 1983-10-25
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Expires: 2001-02-25
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Abstract

Abstract A method for Te pattern formation in the manufacture of a thin-film transistor having a semiconductor layer of Te. Developing and etching of the substrate having the Te layer and a resist layer overlaying the Te layer are simultaneously carried out by the use of a developing and etching solution after having been exposed to rays of UV-light.

Inventors

  • 👤 Shigehiro Minezaki

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 21:18
CPC Classifications
H; H10; H10D; H10D99/00; H10D30/00; H10D30/60; H10D30/67; H10D30/674; H10D30/675

Claims Analysis

Total Claims: 30
Claim 1
Independent Claim 161 words
A method for making a patterned tellurium semiconductor layer, comprising the steps of: depositing a tellurium semiconductor layer on a substrate; forming a photoresist layer, selected portions of said photoresist layer being soluble upon exposure to actinic radiation in an aqueous basic developing and etching solution consisting essentially of an effective amount of compounds selected from the group consisting of inorganic hydroxides, silicates, phosphates, organic bases, monobasic strong bases, water soluble basic amines, water soluble alcohols and mixtures thereof; soft baking the substrate having both the tellurium and photoresist layer thereon; exposing selected portions of the photoresist to actinic radiation to form a pattern in the photoresist; contacting the thus exposed device with said aqueous basic developing and etching solution to selectively remove the exposed portions of said photoresist and to selectively etch the corresponding portions of said tellurium semiconductor layer; washing the resultant device; and contacting the remaining resist layer with an organic solvent to remove the remaining resist layer.
Claim 2
Independent Claim 161 words
A method for making a patterned tellurium semiconductor layer, comprising the steps of: depositing a tellurium semiconductor layer on a substrate; forming a photoresist layer, selected portions of said photoresist layer being soluble upon exposure to actinic radiation in an aqueous basic developing and etching solution consisting essentially of an effective amount of compounds selected from the group consisting of inorganic hydroxides, silicates, phosphates, organic bases, monobasic strong bases, water soluble basic amines, water soluble alcohols and mixtures thereof; soft baking the substrate having both the tellurium and photoresist layer thereon; exposing selected portions of the photoresist to actinic radiation to form a pattern in the photoresist; contacting the thus exposed device with said aqueous basic developing and etching solution to selectively remove the exposed portions of said photoresist and to selectively etch the corresponding portions of said tellurium semiconductor layer; washing the resultant device; and contacting the remaining resist layer with an organic solvent to remove the remaining resist layer.
Claim 3
Dependent Claim 29 words
A method according to claim 1, wherein said aqueous basic developing and etching solution consists essentially of inorganic hydroxide, silicate, phosphate, organic base, monobasic strong base and mixtures thereof.
Claim 4
Dependent Claim 22 words
A method according to claim 1, wherein said aqueous developing and etching solution contains an inorganic hydroxide, a silicate and a phosphate.
Claim 5
Dependent Claim 20 words
A method according to claim 1, wherein said aqueous developing and etching solution contains a quaternary ammonium salt organic base.
Claim 6
Dependent Claim 23 words
A method according to claim 1, wherein said aqueous basic developing and etching solution contains a water-soluble basic amine and a water-soluble alcohol.
Claim 7
Dependent Claim 18 words
A method according to claim 1, wherein said tellurium semiconductor material has a thickness of about 100 Angstroms.
Claim 8
Dependent Claim 64 words
A method according to claim 1, wherein said inorganic hydroxides are selected from the group consisting of sodium hydroxide, potassium hydroxide, barium hydroxide, magnesium hydroxide and calcium hydroxide; said silicates are selected from the group consisting of sodium silicate and potassium silicate; said phosphates are selected from the group consisting of sodium phosphate and potassium phosphate; and said organic bases are quaternary ammonium salts.
Claim 9
Dependent Claim 46 words
A method according to claim 1, wherein said aqueous developing and etching solution contains quaternary ammonium salts selected from the group consisting of tetramethylammonium hydroxide, tetraethylammonium hydroxide, tetrapropylammonium hydroxide, tetrabutylammonium hydroxide, ethyltripropylammonium hydroxide, n-decyltrimethylammonium hydroxide, n-decyltriethylammonium hydroxide, n-dodecyltrimethylammonium hydroxide, n-dodecyltriethylammonium hydroxide, n-hexadecyltrimethylammonium hydroxide, and n-hexadecyltriethylammonium hydroxide.
Claim 10
Independent Claim 190 words
A method for making a thin-film transistor, comprising the steps of: forming a source electrode, a drain electrode, a gate electrode and a tellurium semiconductor layer, wherein the tellurium semiconductor layer is made by a process consisting essentially of the following steps: depositing a tellurium semiconductor layer on a substrate; forming a photoresist layer, selected portions of said photoresist layer being soluble upon exposure to ultraviolet light in an aqueous basic developing and etching solution consisting essentially of an effective amount of compounds selected from the group consisting of inorganic hydroxides, silicates, phosphates, organic bases, monobasic strong bases, water soluble basic amines, water soluble alcohols and mixtures thereof; soft baking the substrate having both the tellurium and photoresist layer thereon; exposing selected portions of the photoresist to ultraviolet light to form a pattern in the photoresist; contacting the thus exposed device with said aqueous basic developing and etching solution to selectively remove the exposed portions of said photoresist and to selectively etch the corresponding portions of said tellurium semiconductor layer; washing the resultant device; and contacting the remaining resist layer with an organic solvent to remove the remaining resist layer.
Claim 11
Independent Claim 190 words
A method for making a thin-film transistor, comprising the steps of: forming a source electrode, a drain electrode, a gate electrode and a tellurium semiconductor layer, wherein the tellurium semiconductor layer is made by a process consisting essentially of the following steps: depositing a tellurium semiconductor layer on a substrate; forming a photoresist layer, selected portions of said photoresist layer being soluble upon exposure to ultraviolet light in an aqueous basic developing and etching solution consisting essentially of an effective amount of compounds selected from the group consisting of inorganic hydroxides, silicates, phosphates, organic bases, monobasic strong bases, water soluble basic amines, water soluble alcohols and mixtures thereof; soft baking the substrate having both the tellurium and photoresist layer thereon; exposing selected portions of the photoresist to ultraviolet light to form a pattern in the photoresist; contacting the thus exposed device with said aqueous basic developing and etching solution to selectively remove the exposed portions of said photoresist and to selectively etch the corresponding portions of said tellurium semiconductor layer; washing the resultant device; and contacting the remaining resist layer with an organic solvent to remove the remaining resist layer.
Claim 12
Dependent Claim 29 words
A method according to claim 9, wherein said aqueous basic developing and etching solution consists essentially of inorganic hydroxide, silicate, phosphate, organic base, monobasic strong base and mixtures thereof.
Claim 13
Dependent Claim 22 words
A method according to claim 9, wherein said aqueous developing and etching solution contains an inorganic hydroxide, a silicate and a phosphate.
Claim 14
Dependent Claim 20 words
A method according to claim 9, wherein said aqueous developing and etching solution contains a quaternary ammonium salt organic base.
Claim 15
Dependent Claim 23 words
A method according to claim 9, wherein said aqueous basic developing and etching solution contains a water-soluble basic amine and a water-soluble alcohol.
Claim 16
Dependent Claim 18 words
A method according to claim 9, wherein said tellurium semiconductor material has a thickness of about 100 Angstroms.
Claim 17
Dependent Claim 64 words
A method according to claim 9, wherein said inorganic hydroxides are selected from the group consisting of sodium hydroxide, potassium hydroxide, barium hydroxide, magnesium hydroxide and calcium hydroxide; said silicates are selected from the group consisting of sodium silicate and potassium silicate; said phosphates are selected from the group consisting of sodium phosphate and potassium phosphate; and said organic bases are quaternary ammonium salts.
Claim 18
Dependent Claim 46 words
A method according to claim 9, wherein said aqueous developing and etching solution contains quaternary ammonium salts selected from the group consisting of tetramethylammonium hydroxide, tetraethylammonium hydroxide, tetrapropylammonium hydroxide, tetrabutylammonium hydroxide, ethyltripropylammonium hydroxide, n-decyltrimethylammonium hydroxide, n-decyltriethylammonium hydroxide, n-dodecyltrimethylammonium hydroxide, n-dodecyltriethylammonium hydroxide, n-hexadecyltrimethylammonium hydroxide, and n-hexadecyltriethylammonium hydroxide.
Claim 19
Dependent Claim 25 words
A method according to claim 9, wherein said exposed device is contacted with said aqueous basic developing and etching solution for 30 to 400 seconds.
Claim 20
Dependent Claim 16 words
A method according to claim 17, wherein said tellurium semiconductor layer is deposited by vacuum evaporation.
Claim 21
Dependent Claim 13 words
A method according to claim 9, wherein said photoresist contains a quinone diazide.
Claim 22
Dependent Claim 12 words
A method according to claim 9, wherein said photoresist contains o-quinone diazide.
Claim 23
Dependent Claim 19 words
A method according to claim 9, wherein said aqueous basic developing and etching solution contains a lower alkyl amine.
Claim 24
Dependent Claim 27 words
A method according to claim 9, wherein said aqueous basic developing and etching solution contains an amine selected from the group consisting of monoethanolamine, diethanolamine and triethanolamine.
Claim 25
Dependent Claim 33 words
A method according to claim 9, wherein said aqueous basic developing and etching solution contains a water-soluble alcohol selected from the group consisting of aliphatic primary alcohols, aliphatic polyhydric alcohols and cyclic alcohols.
Claim 26
Independent Claim 171 words
A method for making a patterned tellurium semiconductor layer, comprising the steps of: depositing a tellurium semiconductor layer on a substrate by vacuum evaporation; forming a photoresist layer, selected portions of said photoresist layer being soluble upon exposure to actinic radiation in an aqueous basic developing and etching solution consisting essentially of an effective amount of compounds selected from the group consisting of inorganic hydroxides, silicates, phosphates, organic bases, monobasic strong bases, water soluble basic amines, water soluble alcohols and mixtures thereof; soft baking the substrate having both the tellurium and photoresist layer thereon; exposing selected portions of the photoresist to ultraviolet light to form a pattern in the photoresist; contacting the thus exposed device with said aqueous basic developing and etching solution for 30 to 400 seconds to selectively remove the exposed portions of said photoresist and to selectively etch the corresponding portions of said tellurium semiconductor layer; washing the resultant device with water; and contacting the remaining resist layer with an organic solvent to remove the remaining resist layer.
Claim 27
Independent Claim 171 words
A method for making a patterned tellurium semiconductor layer, comprising the steps of: depositing a tellurium semiconductor layer on a substrate by vacuum evaporation; forming a photoresist layer, selected portions of said photoresist layer being soluble upon exposure to actinic radiation in an aqueous basic developing and etching solution consisting essentially of an effective amount of compounds selected from the group consisting of inorganic hydroxides, silicates, phosphates, organic bases, monobasic strong bases, water soluble basic amines, water soluble alcohols and mixtures thereof; soft baking the substrate having both the tellurium and photoresist layer thereon; exposing selected portions of the photoresist to ultraviolet light to form a pattern in the photoresist; contacting the thus exposed device with said aqueous basic developing and etching solution for 30 to 400 seconds to selectively remove the exposed portions of said photoresist and to selectively etch the corresponding portions of said tellurium semiconductor layer; washing the resultant device with water; and contacting the remaining resist layer with an organic solvent to remove the remaining resist layer.
Claim 28
Independent Claim 200 words
A method for making a thin-film transistor, comprising the steps of: forming a source electrode, a drain electrode, a gate electrode and a tellurium semiconductor layer, wherein the tellurium semiconductor layer is made by a process consisting essentially of the following steps: depositing a tellurium semiconductor layer on a substrate by vacuum evaporation; forming a photoresist layer, selected portions of said photoresist layer being soluble upon exposure to actinic radiation in an aqueous basic developing and etching solution consisting essentially of an effective amount of compounds selected from the group consisting of inorganic hydroxides, silicates, phosphates, organic bases, monobasic strong bases, water soluble basic amines, water soluble alcohols and mixtures thereof; soft baking the substrate having both the tellurium and photoresist layer thereon; exposing selected portions of the photoresist to ultraviolet light to form a pattern in the photoresist; contacting the thus exposed device for 30 to 400 seconds with said aqueous basic developing and etching solution to selectively remove the exposed portions of said photoresist and to selectively etch the corresponding portions of said tellurium semiconductor layer; washing the resultant device with water; and contacting the remaining resist layer with an organic solvent to remove the remaining resist layer.
Claim 29
Independent Claim 200 words
A method for making a thin-film transistor, comprising the steps of: forming a source electrode, a drain electrode, a gate electrode and a tellurium semiconductor layer, wherein the tellurium semiconductor layer is made by a process consisting essentially of the following steps: depositing a tellurium semiconductor layer on a substrate by vacuum evaporation; forming a photoresist layer, selected portions of said photoresist layer being soluble upon exposure to actinic radiation in an aqueous basic developing and etching solution consisting essentially of an effective amount of compounds selected from the group consisting of inorganic hydroxides, silicates, phosphates, organic bases, monobasic strong bases, water soluble basic amines, water soluble alcohols and mixtures thereof; soft baking the substrate having both the tellurium and photoresist layer thereon; exposing selected portions of the photoresist to ultraviolet light to form a pattern in the photoresist; contacting the thus exposed device for 30 to 400 seconds with said aqueous basic developing and etching solution to selectively remove the exposed portions of said photoresist and to selectively etch the corresponding portions of said tellurium semiconductor layer; washing the resultant device with water; and contacting the remaining resist layer with an organic solvent to remove the remaining resist layer.
Claim 30
Dependent Claim 14 words
A method according to claim 24 or 25, wherein said photoresist comprises o-quinone diazide.

References Cited (Backward Citations)

US3639185A Cited
CA976353A Cited
US4113494A Cited
US4379827A Cited
US4008084A Cited
US4142898A Cited
US4292388A Cited
US4292392A Cited
US4271257A Cited
US4292393A Cited
US4292395A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-10-24 1987-04-25 1987-10-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-10-24 1991-04-25 1991-10-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-10-24 1995-04-25 1995-10-25 $7700.00 Window Closed / Lapsed

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