Macromolecular complexes of amidocarbonylic water-soluble polymers and square planar platinous and equivalent organometallics

Claim 1

A complexed chemical composition comprising, in effectively bonded association: a normally water-soluble polymerizable compound having amidocarbonylic units in its structure and polyerizates of same and other amidocarbonylic polymerizates from nitrogenous precursors therefor (i.e., "WSP") as the complectant in and for the complex; and a square planar platinous and equivalent metalled organometallic compound (i.e., "SPOM") as the complectate in and for the complex; said WSP being a member of the polymer-providing materials and polymerizates selected from the Group consisting of: monomers and polymers and mixtures thereof of the hereinafter-defined Formula (I); and polymers and mixtures thereof of the hereinafter-defined Formula (II); and any of their possible mixtures; said SPOM being an organometallic compound of the hereinafter-defined Formula (III); the general arrangement of Formula (I) being: ##STR30## "D" is selected from the Group consisting of: oxygen; amino, methylene; alkyl-substituted methylenes of the structure "CHR--" in which R contains from 1 to about 3 carbon atoms; methylene carbonyl; ethylene carbonyl; and amido anhydride; "E" is a divalent link of 2 to 3 carbon atoms having the structure "--(CHR') x " in which x is an integer of value 2 to 3 and R' is hydrogen with the exception that in any single given instance R' can be selected from the Group consisting of: hydroxyl; alkyl radicals containing from 1 to about 3 carbon atoms; haloalkyl radicals containing from 1 to about 30 carbon atoms; phenylalkyl radicals in which the alkyl unit contains from 1 to about 30 carbon atoms; halophenylalkyl radicals in which the alkyl unit contains from 1 to about 30 carbon atoms; cycloalkyl radicals containing from about 5 to about 6 carbon atoms; alkyl-substituted about 5 to about 6 carbon atom-containing cycloalkyl radicals in which the alkyl unit contains from 1 to about 30 carbon atoms; halogenated alkyl-substituted about 5 to about 6 carbon atom-containing cycloalkyl radicals in which the alkyl unit contains from 1 to about 30 carbon atoms; phenyl radicals; alkyl-substituted phenyl radicals in which the alkyl unit contains from 1 to about 30 carbon atoms; halophenyl radicals; alpha-naphthyl radicals; alkyl-substituted alpha-naphthyl radicals in which the alkyl unit contains from 1 to about 30 carbon atoms; halogenated alpha-naphthyl radicals; halogenated alkyl-substituted alpha-naphthyl radicals in which the alkyl unit contains from 1 to about 30 carbon atoms and halogen attachment to the extent present is randomly positioned throughout the radical structure; beta-naphthyl radicals; alkyl-substituted beta-naphthyl radicals in which the alkyl unit contains from about 1 to about 30 carbon atoms; halogenated beta-naphthyl radicals; halogenated alkyl-substituted beta naphthyl radicals in which the alkyl unit contains from 1 to about 30 carbon atoms and halogen attachment to the extent present is randomly positioned throughout the radical structure; haloalkyl-substituted phenyl radicals in which the alkyl unit contains from 1 to about 30 carbon atoms; and halogenated alkyl-substituted phenyl radicals in which the alkyl unit contains from 1 to about 30 carbon atoms and halogen attachment to the extent present is randomly positioned throughout the radical structure; and "L" is selected from the Group consisting of: vinyl; allyl; and isopropenyl; the general arrangement of Formula (II) being: ##STR31## "Q" is an alkylene radical selected from the Group consisting of those of the structures "--(CH 2 ) 1-4 "; and "--(R s -CH) 1-2 " in which R s is a lower alkyl radical containing from 1 to about 6 carbon atoms; and "R"" is a radical containing in total from 1 to about 10 carbon atoms and is selected from the Group of those having said quantitative carbon-atom-limitations consisting of: alkyl radicals; alkyl-substituted alkyl radicals; haloalkyl radicals; halogenated alkyl-substituted radicals in which the halogen attachment to the extent present is randomly positioned throughout the radical structure; alkyl-substituted cycloalkyl radicals; halogenated alkyl-substituted cycloalkyl radicals in which the halogen attachment to the extend present is randomly positioned throughout the radical structure; and aminoalkyl radicals; with "n" being an integer of from 2 to about 5,000; the general arrangement of Formula (III) being: ##STR32## "M" is a purposively oxidation-numbered, combined, metaliferous constituent capable of accepting 8 orbital electrons from ligands at the interconnecting level of the metallic atoms selected from the Group consisting of: Pt(II); Pd(II); Ni(II); Rh(I); Ir(I); Au(III) and Cu(II), each of which is capable of making tetraligandal attachments; each "Z" is a ligand that as a radical is monovalent when individually taken and divalent when taken as a single, paired cluster of both of the Z's in coalescence and which can be independently chosen when monovalent and is selected from the Group consisting of: chloro; bromo; fluoro; iodo; ammonia; nitrate, divalent 1,2-diaminocyclohexane; cyclopropylamine; cyclobutylamine; cyclopentyl amine; cyclohexyl amine; ethylene imine; propylene imine; butylene imine; substituted amines of the structure "--NR s H 2 " in which R s is a lower alkyl radical containing from 1 to about 6 carbon atoms; monovalent and divalent ethylene diamine; substituted carboxylates of the structure "--O--CO--R a " in which R a is a radical containing in total from 1 to not more than about 10 carbon atoms and in its characterizability is any one of those that are alkyl, cycloalkyl, cycloalkyl-substituted alkyl and aryl-substituted alkyl; divalent dibasic acids of the structure "--O--CO--(CH 2 ) 0-3 --CO--O--"; univalent half-acid dibasic acids of the structure "--O--CO--(CH 2 ) 0-3 --CO--OJ" in which J is any one of the alkali metals and ammonium; divalent 1,2-cycloalkane dicarboxylates of the structure "--O--CO--CyAlk--CO--O" in which CyAlk in its characterizability is any one of those containing in total from 3 to about 10 carbon atoms exclusive of the carboxylate carbons that are cycloalkane, halocycloalkane, alkyl-substituted cycloalkane, cycloalkyl-substituted cycloalkane and aryl-substituted cycloalkane; divalent 1,2-aryl dicarboxylates of the structure "--O--CO--Ar--CO--O--" in which Ar in its characterizability is any one of those containing in total from 6 to about 12 carbon atoms exclusive of the carboxylate carbons that are aryl, haloaryl, alkyl-substituted aryl, cycloalkyl-substituted aryl, aryl-substituted aryl, halogenated alkyl-substituted aryl, halogenated cycloalkyl-substituted aryl and halogenated aryl-substituted aryl; monovalent glycerates of the structure "--O--CO--CHOH--CH 2 OH"; any of the members of the below-defined Group for the substituent Y; any of the members of the below-defined Group for the entity A when that entity is in bidentate ligandal attachment to M and accordingly in effect constituting a divalent paired cluster of both Z's including clustered Z's independently integral and linking said entity A to M, clustered Z's connected with at least a single substituent grouping on said entity A and clustered Z's founded as constitutional and integral component atoms in said entity A; and any of the members of the below-defined Group for the substituent G depending from said entity A; "A" is an entity that in its characterizability is any one of those that are aromatic and heterocyclic and which is in bidentate ligandal connection with both members of the below-defined Group for the divalent, linking X units including independently integral X's connected with and accepting said entity A, independently integral X's interlinkingly connected with at least a single substituent grouping on said entity A and X's founded as constitutional and integral component atoms in said entity A and which entity A is selected from the Group consisting of: an X-connected substituted benzene that has 0-3 G substituents and 1-4 Y substituents therefrom depending; an X-connected substituted naphthalene that has 0-5 G substitutents and 1-6 Y substitutents therefrom depending; an X-connected substituted bipyridyl that has 0-5 G substituents and 1-6 Y substituents therefrom depending; an X-connected substituted 1,8-naphthpyridine that has 0-5 G substituents and 1-6 Y substituents therefrom depending; an X-connected 1,9-anthracene that has 0-7 G substituents and 1-8 Y substituents therefrom depending; an X-connected 4,5-phenanthrene that has 0-7 G substituents and 1-8 Y substituents therefrom depending; an X-connected 1,2-fluorene that has 0-5 G substituents and 1-6 Y substituents therefrom depending; and an X-connected 4,5-phenanthroline that has 0-7 substituents and 1-8 Y substituents therefrom depending; "Y" is at least a single substituent depending from said entity A that is selected and done independently so when in plurality from the Group consisting of: hydroxyl radicals; sulfhydryl radicals; sulfonic acid radicals; nitro radicals; carboxylate radicals; omega carboxylic acid ether radicals of the structure "O--O(CH 2 ) 1-6 CO--OH"; chloro omega carboxylic acid ether radicals; bromo omega, carboxylic acid ether radicals; sulfonyl radicals; imino radicals; thiosulfonic acid radicals following the general typical structure "--O--OSS--OH"; substituted ureido radicals of the structure ##STR33## ureylene radicals of the structure "--NR s --CO--N--H"; in which R s is a lower alkyl unit containing from 1 to about 6 carbon atoms; amido radicals of the structure "--CO--NH 2 "; alkali metal salts of any of said above-described Y radicals; and ammonium salts of any of said above-described Y radicals; each "X" is an at least equivalently if not actually divalent in function linking unit depending on residual protonation therein and thereof which makes paired connection between "M" and the entity "A" and each of which X units can be identical or independently different excepting when both X's are the N's in said above-identified heterocyclic entities for "A", which X units are selected from the Group consisting of: bivalent oxygen (i.e., "--O--"); bivalent sulfur (i.e., "--S--"); bivalent amine (i.e., "--NH 2 --"); bivalent sulfoxyl units (i.e., "--SO 3 --"); bivalent carboxyl units (i.e., "--COO--"); effectively bivalent 1-6 methylene group(s)-containing omega carboxylic acid ether units and chloro- and bromo- substituted derivatives thereof; effectively bivalent derivatives of mercapto carbonyl units (i.e., "--CO--S--"); effectively bivalent derivatives of hydroxy(thiocarbonyl) units (i.e., "--CS--O--"); effectively bivalent 0-6 methylene group(s)-containing omega mercapto(thiocarbonyl) ether units and chloro- and bromo- derivatives thereof; effectively divalent sulfonyl units (i.e., "--SO 2 -- "); effectively divalent imino units ##STR34## effectively divalent thiosulfonic acid units of representative structure "--O--SSO--O"; effectively divalent substituted ureido units. ##STR35## effectively divalent ureylene units ##STR36## effectively divalent substituted ureylene units of the structure ##STR37## in which R s is a lower alkyl substituent containing from 1 to about 6 carbon atoms; plus effectively divalent amido units (i.e., "--CO--NH 2 --"); and "G" is an optional substituent of any desired polarity which when present is at least singular in number of depending units in attachment with said entity A that is chosen independently when present in any allowable plurality and is selected from the Group consisting of: hydrogen; any of the monovalent members of the above-defined Group for the ligandal substituent Z; any of the members when provided so as to be in monovalent form of the above-defined Group Y substituent for said entity A; and with the exception of already-here-included hydroxyl radicals any of the members of the Group R' substituents which may depend from said unit E in the structure of the above-givedn Formula (I).