← Back to Patent Explorer
US4404269A Expired / Lapsed US ⏱️ 0.0 years remaining

Developer containing magnetic and non-magnetic toner

Assignee: Kyocera Mita Industrial Co Ltd
•
Filing: 1981-11-13
•
Granted: 1983-09-13
•
Expires: 2001-11-13
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A two-component dry-type composite developer which is a mixture of 100 parts of (A) magnetic toner particles of a binder resin and 40 to 70% by weight of magnetite having a bulk density of at least 0.45 g/ml, a number average maximum size of at least 0.5 μm and a maximum size/minimum size ratio of from 1.0 to 5.5 and 1 to 30 parts of (B) non-magnetic toner particles of binder resin, pigment and negative charge controlling agent. The magnetic toner particles have an electrostatic capacitance of 7 to 8.5 picofarad, a dielectric constant of 3.59 to 4.36, and a volume resistivity of 1.2 to 8.6×10 14 Ω-cm, and the nonmagnetic toner particles have an electrostatic capacitance of 6.0 to 8.0 picofarad and a dielectric constant of 3.08 to 4.10. The toner particles (A) and (B) have friction chargeability characteristics of the same polarity and are consumed at the same rate during development such that the mixing ratio remains constant and the development characteristics are not changed during use. Copies of from soft to hard tones can be obtained by changing the mixing ratio. Development and transfer efficiencies are improved.

Inventors

  • 👤 Nobuhiro Miyakawa
  • 👤 Kouzi Maekawa
  • 👤 Masanori Fujii

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 01:35
CPC Classifications
G; G03; G03G; G03G9/00; G03G9/08; G03G9/0819; G03G9/0821; G03G9/0823; G03G9/083; G03G9/0836

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 288 words
In a two-component simultaneously consumable, dry-type composite developer which comprises a mixture of magnetic toner particles composed of a dispersion of a powdery magnetic material in an electrically insulating binder resin medium and non-magnetic toner particles composed of a dispersion of a coloring agent in an electrically insulating binder resin medium, the improvement wherein the magnetic toner particles comprise (a) a resin binder medium and (b) 40 to 70% by weight, based on the sum of the binder and powdery magnetic material, of magnetite having a bulk density of at least 0.45 g/ml, a number average maximum size as measured by an electron microscope of at least 0.5 μm and a maximum size/minimum size ratio of from 1.0 to 5.5, the magnetic toner particles have an electrostatic capacitance of 7 to 8.5 pF (picofarad), a dielectric constant of 3.59 to 4.36, and a volume resistivity of 1.2×10 - to about 8.6×10 14 Ω-cm, as determined under conditions of an electrode gap of 0.65 mm, an electrode sectional area of 1.43 cm 2 and an inter-electrode load of 105 g/cm 2 , the non-magnetic toner particles comprise (i) a resin binder medium, (ii) 2 to 10% by weight, based on the resin binder medium, of a pigment, and (iii) a negative charge controlling agent composed of a chromium-, iron- or cobalt-containing complex salt dye, and have an electrostatic capacitance of 6.0 to 8.0 pF and a dielectric constant of 3.08 to 4.10, as determined under said conditions, the magnetic toner particles and the non-magnetic toner particles have a friction chargeability characteristic of the same polarity, and the magnetic toner particles and the non-magnetic toner particles are present in the developer at a weight ratio of from 100:1 to 100:30.
Claim 2
Dependent Claim 288 words
In a two-component simultaneously consumable, dry-type composite developer which comprises a mixture of magnetic toner particles composed of a dispersion of a powdery magnetic material in an electrically insulating binder resin medium and non-magnetic toner particles composed of a dispersion of a coloring agent in an electrically insulating binder resin medium, the improvement wherein the magnetic toner particles comprise (a) a resin binder medium and (b) 40 to 70% by weight, based on the sum of the binder and powdery magnetic material, of magnetite having a bulk density of at least 0.45 g/ml, a number average maximum size as measured by an electron microscope of at least 0.5 μm and a maximum size/minimum size ratio of from 1.0 to 5.5, the magnetic toner particles have an electrostatic capacitance of 7 to 8.5 pF (picofarad), a dielectric constant of 3.59 to 4.36, and a volume resistivity of 1.2×10 - to about 8.6×10 14 Ω-cm, as determined under conditions of an electrode gap of 0.65 mm, an electrode sectional area of 1.43 cm 2 and an inter-electrode load of 105 g/cm 2 , the non-magnetic toner particles comprise (i) a resin binder medium, (ii) 2 to 10% by weight, based on the resin binder medium, of a pigment, and (iii) a negative charge controlling agent composed of a chromium-, iron- or cobalt-containing complex salt dye, and have an electrostatic capacitance of 6.0 to 8.0 pF and a dielectric constant of 3.08 to 4.10, as determined under said conditions, the magnetic toner particles and the non-magnetic toner particles have a friction chargeability characteristic of the same polarity, and the magnetic toner particles and the non-magnetic toner particles are present in the developer at a weight ratio of from 100:1 to 100:30.
Claim 3
Dependent Claim 44 words
A developer as set forth in claim 1, wherein the magnetite consists of a non-pulverizable agglomerate of cubic particles and the number average particle size of the agglomerate is in the range of from 1 to 10 μm as measured by an electron microscope.
Claim 4
Dependent Claim 28 words
A developer as set forth in claim 2, wherein the agglomerate has an apparent density of 0.5 to 1.5 as measured according to the method of JIS K-5101.
Claim 5
Dependent Claim 37 words
A developer as set forth in claim 2, wherein the agglomerate has a saturation magnetization of 75 to 88 emu/g, a residual magnetization of 3 to 12 emu/g and a coercive force of 40 to 150 Oe.
Claim 6
Dependent Claim 40 words
A developer as set forth in claim 1 or 2, wherein the magnetic toner particles have a number average particle size of 5 to 35 μm, which is at least 2 times the number average particle size of the magnetite.
Claim 7
Dependent Claim 56 words
A developer as set forth in claim 1, 2, 3 or 4 wherein the magnetic toner particles have an electrostatic capacitance of 7.2 to 8.2 pF, and a dielectric constant of 3.69 to 4.21, and the non-magnetic toner particles have an electrostatic capacitance of 6.2 to 7.7 pF and a dielectric constant of 3.18 to 3.95.
Claim 8
Dependent Claim 41 words
A developer as set forth in claim 6 wherein the magnetic toner particles comprise (a) said resin binder medium and (b) 45 to 65% by weight, based on the sum of the binder medium and powdery magnetic material, of said magnetite.
Claim 9
Dependent Claim 32 words
A developer as set forth in claim 6 wherein the magnetic toner particles and the non-magnetic toner particles are present in the developer at a weight ratio of from 100:2 to 100:20.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-09-12 1987-03-14 1987-09-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-09-12 1991-03-14 1991-09-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-09-12 1995-03-14 1995-09-13 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag