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Epoxy resins from hydroxy benzamides

Assignee: Dow Chemical Co
•
Filing: 1982-05-13
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Granted: 1983-08-09
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Expires: 2002-05-13
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Abstract

Abstract New epoxy resins are prepared by reacting a hydroxybenzamide or derivative thereof with an epihalo-hydrin followed by dehydrohalogenation. These epoxy resins have crystalline melting points, self-cure at elevated temperatures and cure rapidly in the presence of the usual epoxy resin curing agents. Also disclosed are hydrolyzed products of these epoxy resins and subsequent reactions with polyisocyanates.

Inventors

  • 👤 James L. Bertram
  • 👤 Edmund P. Woo

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 18:57
CPC Classifications
C; C08; C08G; C08G59/00; C08G59/14; C08G59/1405; C08G59/1427; C08G18/00; C08G18/06; C08G18/28; C08G18/30; C08G18/38; C08G18/3819; C08G18/3823; C08G18/3825; C08G18/40; C08G18/48; C08G18/50; C08G18/5021; C08G18/5036; C08G18/5039; C08G59/02; C08G59/04; C08G59/06; C08G59/063; C08G59/18; C08G59/20; C08G59/22; C08G59/28; C08G59/32; C08G59/3227; Y; Y10; Y10S; Y10S525/00; Y10S525/934; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31511

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 302 words
The product resulting from curing a curable composition containing an epoxy resin or mixture of epoxy resins represented by the following formulas I, II or III ##STR3## wherein each R is a divalent hydrocarbyl group having from 1 to about 18 carbon atoms, a group represented by the following formulas IV, V, VI or VII ##STR4## or R can combine with R 1 so as to form a stable heterocyclic ring with the nitrogen atoms; each A is independently a divalent hydrocarbyl group having from 1 to about 10 carbon atoms, ##STR5## each R 1 is independently hydrogen, a 2,3-epoxypropyl group, a 2-alkyl-2,3-epoxypropyl group, a monovalent hydrocarbyl group, or a hydroxyl substituted monovalent hydrocarbyl group, said hydrocarbyl groups having from 1 to about 9 carbon atoms, said alkyl having from 1 to about 4 carbon atoms; each R 2 and R 3 is independently hydrogen or an alkyl group having from 1 to about 4 carbon atoms; each R 4 is independently hydrogen, a hydrocarbyl group or a halogen substituted hydrocarbyl group having from 1 to about 9 carbon atoms; each R 8 is independently selected from the group represented by the following formula XIV ##STR6## or the same group as R 1 except that R 8 cannot be hydrogen; each R 9 is a divalent hydrocarbyl group having from two to about 4 carbon atoms; each X is independently hydrogen, chlorine, bromine or a hydrocarbyl or hydrocarbyloxy group having from 1 to about 9 carbon atoms; each m independently has a value of zero or 1; n has an average value of from about 0.01 to about 6; p has an average value of from 1 to about 10; q has an average value of at least 1; and each y and z independently has a value of 1 or 2.
Claim 2
Dependent Claim 302 words
The product resulting from curing a curable composition containing an epoxy resin or mixture of epoxy resins represented by the following formulas I, II or III ##STR3## wherein each R is a divalent hydrocarbyl group having from 1 to about 18 carbon atoms, a group represented by the following formulas IV, V, VI or VII ##STR4## or R can combine with R 1 so as to form a stable heterocyclic ring with the nitrogen atoms; each A is independently a divalent hydrocarbyl group having from 1 to about 10 carbon atoms, ##STR5## each R 1 is independently hydrogen, a 2,3-epoxypropyl group, a 2-alkyl-2,3-epoxypropyl group, a monovalent hydrocarbyl group, or a hydroxyl substituted monovalent hydrocarbyl group, said hydrocarbyl groups having from 1 to about 9 carbon atoms, said alkyl having from 1 to about 4 carbon atoms; each R 2 and R 3 is independently hydrogen or an alkyl group having from 1 to about 4 carbon atoms; each R 4 is independently hydrogen, a hydrocarbyl group or a halogen substituted hydrocarbyl group having from 1 to about 9 carbon atoms; each R 8 is independently selected from the group represented by the following formula XIV ##STR6## or the same group as R 1 except that R 8 cannot be hydrogen; each R 9 is a divalent hydrocarbyl group having from two to about 4 carbon atoms; each X is independently hydrogen, chlorine, bromine or a hydrocarbyl or hydrocarbyloxy group having from 1 to about 9 carbon atoms; each m independently has a value of zero or 1; n has an average value of from about 0.01 to about 6; p has an average value of from 1 to about 10; q has an average value of at least 1; and each y and z independently has a value of 1 or 2.
Claim 3
Dependent Claim 15 words
The product of claim 1 which is free of a curing agent for epoxy resins.
Claim 4
Dependent Claim 13 words
The product of claim 1 which contains a curing agent for epoxy resins.
Claim 5
Dependent Claim 298 words
A powder coating composition containing an epoxy resin or mixture of epoxy resins represented by the following formulas I, II or III ##STR7## wherein each R is a divalent hydrocarbyl group having from 1 to about 18 carbon atoms, a group represented by the following formulas IV, V, VI or VII ##STR8## or R can combine with R 1 so as to form a stable heterocyclic ring with the nitrogen atoms; each A is independently a divalent hydrocarbyl group having from 1 to about 10 carbon atoms, ##STR9## each R 1 is independently hydrogen, a 2,3-epoxypropyl group, a 2-alkyl-2,3-epoxypropyl group, a monovalent hydrocarbyl group, or a hydroxyl substituted monovalent hydrocarbyl group, said hydrocarbyl groups having from 1 to about 9 carbon atoms, said alkyl having from 1 to about 4 carbon atoms; each R 2 and R 3 is independently hydrogen or an alkyl group having from 1 to about 4 carbon atoms; each R 4 is independently hydrogen, a hydrocarbyl group or a halogen substituted hydrocarbyl group having from 1 to about 9 carbon atoms; each R 8 is independently selected from the group represented by the following formula XIV ##STR10## or the same group as R 1 except that R 8 cannot be hydrogen; each R 9 is a divalent hydrocarbyl group having from two to about 4 carbon atoms; each X is independently hydrogen, chlorine, bromine or a hydrocarbyl or hydrocarbyloxy group having from 1 to about 9 carbon atoms; each m independently has a value of zero or 1; n has an average value of from about 0.01 to about 6; p has an average value of from 1 to about 10; q has an average value of at least 1; and each y and z independently has a value of 1 or 2.
Claim 6
Dependent Claim 298 words
A powder coating composition containing an epoxy resin or mixture of epoxy resins represented by the following formulas I, II or III ##STR7## wherein each R is a divalent hydrocarbyl group having from 1 to about 18 carbon atoms, a group represented by the following formulas IV, V, VI or VII ##STR8## or R can combine with R 1 so as to form a stable heterocyclic ring with the nitrogen atoms; each A is independently a divalent hydrocarbyl group having from 1 to about 10 carbon atoms, ##STR9## each R 1 is independently hydrogen, a 2,3-epoxypropyl group, a 2-alkyl-2,3-epoxypropyl group, a monovalent hydrocarbyl group, or a hydroxyl substituted monovalent hydrocarbyl group, said hydrocarbyl groups having from 1 to about 9 carbon atoms, said alkyl having from 1 to about 4 carbon atoms; each R 2 and R 3 is independently hydrogen or an alkyl group having from 1 to about 4 carbon atoms; each R 4 is independently hydrogen, a hydrocarbyl group or a halogen substituted hydrocarbyl group having from 1 to about 9 carbon atoms; each R 8 is independently selected from the group represented by the following formula XIV ##STR10## or the same group as R 1 except that R 8 cannot be hydrogen; each R 9 is a divalent hydrocarbyl group having from two to about 4 carbon atoms; each X is independently hydrogen, chlorine, bromine or a hydrocarbyl or hydrocarbyloxy group having from 1 to about 9 carbon atoms; each m independently has a value of zero or 1; n has an average value of from about 0.01 to about 6; p has an average value of from 1 to about 10; q has an average value of at least 1; and each y and z independently has a value of 1 or 2.
Claim 7
Dependent Claim 11 words
An article coated with the powder coating composition of claim 4.

References Cited (Backward Citations)

US2730531A Cited
US3042692A Cited
US3562297A Cited
US3840598A Cited
US3798242A Cited
US3904658A Cited
US4229563A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-08-08 1987-02-07 1987-08-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-08-08 1991-02-07 1991-08-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-08-08 1995-02-07 1995-08-09 $7700.00 Window Closed / Lapsed

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