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US4387156A Expired / Lapsed US ⏱️ 0.0 years remaining

Imageable film containing a metal oxide opacifying layer

Assignee: 3M Co
•
Filing: 1981-02-04
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Granted: 1983-06-07
•
Expires: 2001-02-04
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Abstract

Abstract Imaging materials are disclosed which comprise a substrate having a metal/ (metal oxide or sulfide) coating with an optical density of at least 0.2 on one surface of the substrate and a photoresist layer over said coating.

Inventors

  • 👤 George H. Crawford
  • 👤 Richard S. Fisch

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 15:14
CPC Classifications
G; G03; G03F; G03F1/00; G03F1/54

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 141 words
An imageable article comprising (a) a substrate, (b) on at least one surface of said substrate a first opacifying layer comprising a dispersion of (i) metal and (ii) metal oxide with an optical density of at least 0.2 derived from the dispersion, and (c) a photoresist layer on said first layer, wherein said opacifying layer is at least 15 Angstroms in thickness and comprises a mixture of (a) metal and (b) metal oxide, said opacifying layer characterized by having a region of higher concentration of metal on one surface than on a second surface, and having said one surface of the said opacifying layer bonded to said substrate, having said second surface facing away from said substrate, and having a zone of continuous transition of the concentration of metal from said region of higher concentration of metal to said second surface.
Claim 2
Dependent Claim 141 words
An imageable article comprising (a) a substrate, (b) on at least one surface of said substrate a first opacifying layer comprising a dispersion of (i) metal and (ii) metal oxide with an optical density of at least 0.2 derived from the dispersion, and (c) a photoresist layer on said first layer, wherein said opacifying layer is at least 15 Angstroms in thickness and comprises a mixture of (a) metal and (b) metal oxide, said opacifying layer characterized by having a region of higher concentration of metal on one surface than on a second surface, and having said one surface of the said opacifying layer bonded to said substrate, having said second surface facing away from said substrate, and having a zone of continuous transition of the concentration of metal from said region of higher concentration of metal to said second surface.
Claim 3
Dependent Claim 19 words
The imageable article of claim 1, wherein the same metal comprises said (i) metal and said (ii) metal oxide.
Claim 4
Dependent Claim 17 words
The imageable article of claim 1 wherein said photoresist is a negative acting polyethylenically unsaturated photosensitive composition.
Claim 5
Dependent Claim 15 words
The imageable article of claim 1 wherein said photoresist comprises a positive acting photoresist composition.
Claim 6
Dependent Claim 28 words
The imageable article of claim 4 wherein said metal is selected from the group consisting of aluminum, tin, zinc, chromium, titanium, magnesium, manganese, nickel, iron, and mixtures thereof.
Claim 7
Dependent Claim 50 words
The article of claim 1 wherein said photosensitive resist layer is selected from the group consisting of: (a) positive acting photoresists comprising a polymeric binding and a positive acting diazonium salt or resin, and (b) negative acting photoresists comprising a composition capable of photopolymerizing in an imagewise fashion when irradiated.
Claim 8
Dependent Claim 28 words
The article of claim 6 wherein said photosensitive resist layer is a positive acting photoresist comprising a positive acting diazonium salt or resin in an epoxy polymeric binder.
Claim 9
Dependent Claim 41 words
The article of claim 1, 6 or 7 wherein the same metal comprises said metal and said metal oxide and said metal is selected from the group consisting of aluminum, tin, zinc, chromium, titanium, magnesium, manganese, nickel, iron and mixtures thereof.
Claim 10
Dependent Claim 24 words
The article of claim 1, 6 or 7 wherein the same metal comprises said metal and said metal oxide and that metal comprises aluminum.

References Cited (Backward Citations)

US3811894A Cited
US3975197A Cited
US4021592A Cited
US4292388A Cited
US4292393A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-06-06 1986-12-06 1987-06-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-06-06 1990-12-06 1991-06-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-06-06 1994-12-06 1995-06-07 $7700.00 Window Closed / Lapsed

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