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US4379063A
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Novel functional fluid
Assignee: DEUTSCHEBANK TRUST Co AMERICAS
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Filing: 1981-02-20
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Granted: 1983-04-05
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Expires: 2001-02-20
Abstract
Abstract Corrosion inhibiting aqueous functional fluids having high stability are provided which contain (a) water, (b) a corrosion inhibiting, surface active, water soluble or dispersible alkali metal, ammonium or organic amine salt of a water insoluble carboxylic acid group terminated monoamide, (c) a second surface active agent and optionally, (d) water soluble or dispersible lubricant. These functional fluids are useful as a metal working fluid or hydraulic fluid.
Inventors
- 👤 Mark A. Williams
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 08:31
CPC Classifications
C; C10; C10M; C10M105/00; C10M105/56; C10M105/68; C08; C08G; C08G59/00; C08G59/18; C08G59/40; C08G59/4007; C08G59/4014; C08G59/4028; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/64; C08G18/6407; C08G59/02; C08G59/04; C08G59/06; C08G59/063; C08G59/62; C08G59/621; C10M173/00; C10M173/02; C23; C23F; C23F11/00; C23F11/08; C23F11/10; C23F11/14; C10M2201/00; C10M2201/02; C10M2207/00; C10M2207/28; C10M2207/287; C10M2207/289; C10M2209/00; C10M2209/10; C10M2209/103; C10M2209/104; C10M2209/11; C10M2215/00; C10M2215/02; C10M2215/04; C10M2215/042; C10M2215/08; C10M2215/082; C10M2215/12; C10M2215/122; C10M2215/24; C10M2215/28; C10M2219/00; C10M2219/04; C10M2219/044; C10M2227/00; C10M2227/06; C10N; C10N2040/00; C10N2040/08; C10N2040/20; C10N2040/22; C10N2050/00; C10N2050/01; Y; Y10; Y10S; Y10S516/00; Y10S516/01; Y10S516/06
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
347 words
A corrosion inhibiting, aqueous functional fluid composition having a pH in the range of from 8 to 12 comprising (a) water, (b) a surface active, corrosion inhibiting, water soluble or dispersible alkali metal, ammonium or organic amine salt of a water insoluble carboxylic acid group terminated amide having one amide linkage ##STR46## per molecule and (c) a second surface active agent, wherein (b) has the following formula ##STR47## where R is a divalent C 4 to C 8 cycloaliphatic radical, R 1 is a monovalent organic radical selected from the group of: (a) a monovalent C 7 to C 10 aliphatic radical having at least one methyl or ethyl branch when R 2 is hydrogen, or (b) a monovalent C 1 to C 9 straight or branched chain aliphatic group when R 2 is a monovalent C 1 to C 9 straight or branched chain aliphatic group with the proviso that R 1 +R 2 shall have a combined total of from 7 to 10 carbon atoms and at least one of R 1 or R 2 has at least 4 carbon atoms, R 2 is hydrogen or a monovalent C 1 to C 9 branched or straight chain aliphatic group, Z is an alkali metal cation or a nitrogen containing cation having at least one hydrogen attached to the nitrogen, a positive charge equal to x and selected from the group consisting of ammonium cation and cations of a water soluble alkanolamine having 2 to 4 carbon atoms in the alkanol group, C 2 to C 6 alkyl amine, alkyl alkanolamine having 1 to 6 carbon atoms in the alkyl group and 2 to 4 carbon atoms in the alkanol group, heteroaliphatic monoamine in which the heteroatom is oxygen, heteroaliphatic polyamine having oxygen or nitrogen heteroatoms, alkylene diamine having 2 to 6 carbon atoms in the alkylene group, N-alkyl or N-hydroxyalkyl substituted alkylene diamine having 2 to 6 carbon atoms in the alkylene group, morpholine, N-alkyl substituted morpholine or N-aminoalkyl substituted morpholine, x is 1 to 3, y is 1 and m is 1 to 3
Claim 2
Dependent Claim
347 words
A corrosion inhibiting, aqueous functional fluid composition having a pH in the range of from 8 to 12 comprising (a) water, (b) a surface active, corrosion inhibiting, water soluble or dispersible alkali metal, ammonium or organic amine salt of a water insoluble carboxylic acid group terminated amide having one amide linkage ##STR46## per molecule and (c) a second surface active agent, wherein (b) has the following formula ##STR47## where R is a divalent C 4 to C 8 cycloaliphatic radical, R 1 is a monovalent organic radical selected from the group of: (a) a monovalent C 7 to C 10 aliphatic radical having at least one methyl or ethyl branch when R 2 is hydrogen, or (b) a monovalent C 1 to C 9 straight or branched chain aliphatic group when R 2 is a monovalent C 1 to C 9 straight or branched chain aliphatic group with the proviso that R 1 +R 2 shall have a combined total of from 7 to 10 carbon atoms and at least one of R 1 or R 2 has at least 4 carbon atoms, R 2 is hydrogen or a monovalent C 1 to C 9 branched or straight chain aliphatic group, Z is an alkali metal cation or a nitrogen containing cation having at least one hydrogen attached to the nitrogen, a positive charge equal to x and selected from the group consisting of ammonium cation and cations of a water soluble alkanolamine having 2 to 4 carbon atoms in the alkanol group, C 2 to C 6 alkyl amine, alkyl alkanolamine having 1 to 6 carbon atoms in the alkyl group and 2 to 4 carbon atoms in the alkanol group, heteroaliphatic monoamine in which the heteroatom is oxygen, heteroaliphatic polyamine having oxygen or nitrogen heteroatoms, alkylene diamine having 2 to 6 carbon atoms in the alkylene group, N-alkyl or N-hydroxyalkyl substituted alkylene diamine having 2 to 6 carbon atoms in the alkylene group, morpholine, N-alkyl substituted morpholine or N-aminoalkyl substituted morpholine, x is 1 to 3, y is 1 and m is 1 to 3
Claim 3
Dependent Claim
355 words
A corrosion inhibiting, aqueous functional fluid composition having a pH in the range of from 8 to 12 comprising (a) water, (b) a surface active, corrosion inhibiting, water soluble or dispersible alkali metal, ammonium or organic amine salt of a water insoluble carboxylic acid group terminated amide having one amide linkage ##STR48## per molecule, (c) a second surface active agent and (d) a water soluble or dispersible lubricant, wherein (b) has the following formula ##STR49## where R is a divalent C 4 to C 8 cycloaliphatic radical, R 1 is a monovalent organic radical selected from the group of: (a) a monovalent C 7 to C 10 aliphatic radical having at least one methyl or ethyl branch when R 2 is hydrogen, or (b) a monovalent C 1 to C 9 straight or branched chain aliphatic group when R 2 is a monovalent C 1 to C 9 straight or branched chain aliphatic group with the proviso that R 1 +R 2 shall have a combined total of from 7 to 10 carbon atoms and at least one of R 1 or R 2 has at least 4 carbon atoms, R 2 is a hydrogen or a monovalent C 1 to C 9 branched or straight chain aliphatic group, Z is an alkali metal cation or a nitrogen containing cation having at least one hydrogen attached to the nitrogen, a positive charge equal to x and selected from the group consisting of ammonium cation and cations of a water soluble alkanolamine having 2 to 4 carbon atoms in the alkanol group, C 2 to C 6 alkyl amine, alkyl alkanolamine having 1 to 6 carbon atoms in the alkyl group and 2 to 4 carbon atoms in the alkanol group, heteroaliphatic monoamine in which the heteroatom is oxygen, heteroaliphatic polyamine having oxygen or nitrogen heteroatoms, alkylene diamine having 2 to 6 carbon atoms in the alkylene group, N-alkyl or N-hydroxyalkyl substituted alkylene diamine having 2 to 6 carbon atoms in the alkylene group, morpholine, N-alkyl substituted morpholine or N-aminoalkyl substituted morpholine, x is 1 to 3 y is 1 and m is 1 to 3
Claim 4
Dependent Claim
355 words
A corrosion inhibiting, aqueous functional fluid composition having a pH in the range of from 8 to 12 comprising (a) water, (b) a surface active, corrosion inhibiting, water soluble or dispersible alkali metal, ammonium or organic amine salt of a water insoluble carboxylic acid group terminated amide having one amide linkage ##STR48## per molecule, (c) a second surface active agent and (d) a water soluble or dispersible lubricant, wherein (b) has the following formula ##STR49## where R is a divalent C 4 to C 8 cycloaliphatic radical, R 1 is a monovalent organic radical selected from the group of: (a) a monovalent C 7 to C 10 aliphatic radical having at least one methyl or ethyl branch when R 2 is hydrogen, or (b) a monovalent C 1 to C 9 straight or branched chain aliphatic group when R 2 is a monovalent C 1 to C 9 straight or branched chain aliphatic group with the proviso that R 1 +R 2 shall have a combined total of from 7 to 10 carbon atoms and at least one of R 1 or R 2 has at least 4 carbon atoms, R 2 is a hydrogen or a monovalent C 1 to C 9 branched or straight chain aliphatic group, Z is an alkali metal cation or a nitrogen containing cation having at least one hydrogen attached to the nitrogen, a positive charge equal to x and selected from the group consisting of ammonium cation and cations of a water soluble alkanolamine having 2 to 4 carbon atoms in the alkanol group, C 2 to C 6 alkyl amine, alkyl alkanolamine having 1 to 6 carbon atoms in the alkyl group and 2 to 4 carbon atoms in the alkanol group, heteroaliphatic monoamine in which the heteroatom is oxygen, heteroaliphatic polyamine having oxygen or nitrogen heteroatoms, alkylene diamine having 2 to 6 carbon atoms in the alkylene group, N-alkyl or N-hydroxyalkyl substituted alkylene diamine having 2 to 6 carbon atoms in the alkylene group, morpholine, N-alkyl substituted morpholine or N-aminoalkyl substituted morpholine, x is 1 to 3 y is 1 and m is 1 to 3
Claim 5
Dependent Claim
342 words
A corrosion inhibiting, aqueous functional fluid composition having a pH in the range of from 8 to 12 comprising (a) water, (b) a surface active, corrosion inhibiting, water soluble or dispersible alkali metal, ammonium or organic amine salt of a water insoluble carboxylic acid group terminated amide having one amide linkage ##STR50## per molecule and (c) a second surface active agent, wherein (b) has the following formula ##STR51## where R is a divalent aromatic radical, R 1 is a monovalent organic radical selected from the group of: (a) a monovalent C 7 to C 10 aliphatic radical having at least one methyl or ethyl branch when R 2 is hydrogen, or (b) a monovalent C 1 to C 9 straight or branched chain aliphatic group when R 2 is a monovalent C 1 to C 9 straight or branched chain aliphatic group with the proviso that R 1 +R 2 shall have a combined total of from 7 to 10 carbon atoms and at least one of R 1 or R 2 has at least 4 carbon atoms, R 2 is hydrogen or a monovalent C 1 to C 9 branched or straight chain aliphatic group, Z is an alkali metal cation or a nitrogen containing cation having at least one hydrogen attached to the nitrogen, a positive charge equal to x and selected from the group consisting of ammonium cation and cations of a water soluble alkanolamine having 2 to 4 carbon atoms in the alkanol group, C 2 to C 6 alkyl amine, alkyl alkanolamine having 1 to 6 carbon atoms in the alkyl group and 2 to 4 carbon atoms in the alkanol group, heteroaliphatic monoamine in which the heteroatom is oxygen, heteroaliphatic polyamine having oxygen or nitrogen heteroatoms, alkylene diamine having 2 to 6 carbon atoms in the alkylene group, N-alkyl or N-hydroxyalkyl substituted alkylene diamine having 2 to 6 carbon atoms in the alkylene group, morpholine, N-alkyl substituted morpholine or N-aminoalkyl substituted morpholine, x is 1 to 3, y is 1 and m is 1 to 3
Claim 6
Dependent Claim
342 words
A corrosion inhibiting, aqueous functional fluid composition having a pH in the range of from 8 to 12 comprising (a) water, (b) a surface active, corrosion inhibiting, water soluble or dispersible alkali metal, ammonium or organic amine salt of a water insoluble carboxylic acid group terminated amide having one amide linkage ##STR50## per molecule and (c) a second surface active agent, wherein (b) has the following formula ##STR51## where R is a divalent aromatic radical, R 1 is a monovalent organic radical selected from the group of: (a) a monovalent C 7 to C 10 aliphatic radical having at least one methyl or ethyl branch when R 2 is hydrogen, or (b) a monovalent C 1 to C 9 straight or branched chain aliphatic group when R 2 is a monovalent C 1 to C 9 straight or branched chain aliphatic group with the proviso that R 1 +R 2 shall have a combined total of from 7 to 10 carbon atoms and at least one of R 1 or R 2 has at least 4 carbon atoms, R 2 is hydrogen or a monovalent C 1 to C 9 branched or straight chain aliphatic group, Z is an alkali metal cation or a nitrogen containing cation having at least one hydrogen attached to the nitrogen, a positive charge equal to x and selected from the group consisting of ammonium cation and cations of a water soluble alkanolamine having 2 to 4 carbon atoms in the alkanol group, C 2 to C 6 alkyl amine, alkyl alkanolamine having 1 to 6 carbon atoms in the alkyl group and 2 to 4 carbon atoms in the alkanol group, heteroaliphatic monoamine in which the heteroatom is oxygen, heteroaliphatic polyamine having oxygen or nitrogen heteroatoms, alkylene diamine having 2 to 6 carbon atoms in the alkylene group, N-alkyl or N-hydroxyalkyl substituted alkylene diamine having 2 to 6 carbon atoms in the alkylene group, morpholine, N-alkyl substituted morpholine or N-aminoalkyl substituted morpholine, x is 1 to 3, y is 1 and m is 1 to 3
Claim 7
Dependent Claim
349 words
A corrosion inhibiting, aqueous functional fluid composition having a pH in the range of from 8 to 12 comprising (a) water, (b) a surface active, corrosion inhibiting, water soluble or dispersible alkali metal, ammonium or organic amine salt of a water insoluble carboxylic acid group terminated amide having one amide linkage ##STR52## per molecule, (c) a second surface active agent and (d) a water soluble or dispersible lubricant, wherein (b) has the following formula ##STR53## where R is a divalent aromatic radical, R 1 is a monovalent organic radical selected from the group of: (a) a monovalent C 7 to C 10 aliphatic radical having at least one methyl or ethyl branch when R 2 is hydrogen, or (b) a monovalent C 1 to C 9 straight or branched chain aliphatic group when R 2 is a monovalent C 1 to C 9 straight or branched chain aliphatic group with the proviso that R 1 +R 2 shall have a combined total of from 7 to 10 carbon atoms and at least one of R 1 or R 2 has at least 4 carbon atoms, R 2 is hydrogen or a monovalent C 1 to C 9 branched or straight chain aliphatic group, Z is an alkali metal cation or a nitrogen containing cation having at least one hydrogen attached to the nitrogen, a positive charge equal to x and selected from the group consisting of ammonium cation and cations of a water soluble alkanolamine having 2 to 4 carbon atoms in the alkanol group, C 2 to C 6 alkyl amine, alkyl alkanolamine having 1 to 6 carbon atoms in the alkyl group and 2 to 4 carbon atoms in the alkanol group, heteroaliphatic monoamine in which the heteroatom is oxygen, heteroaliphatic polyamine having oxygen or nitrogen heteroatoms, alkylene diamine having 2 to 6 carbon atoms in the alkylene group, N-alkyl or N-hydroxyalkyl substituted alkylene diamine having 2 to 6 carbon atoms in the alkylene group, morpholine, N-alkyl substituted morpholine or N-aminoalkyl substituted morpholine, x is 1 to 3 y is 1 and m is 1 to 3
Claim 8
Dependent Claim
349 words
A corrosion inhibiting, aqueous functional fluid composition having a pH in the range of from 8 to 12 comprising (a) water, (b) a surface active, corrosion inhibiting, water soluble or dispersible alkali metal, ammonium or organic amine salt of a water insoluble carboxylic acid group terminated amide having one amide linkage ##STR52## per molecule, (c) a second surface active agent and (d) a water soluble or dispersible lubricant, wherein (b) has the following formula ##STR53## where R is a divalent aromatic radical, R 1 is a monovalent organic radical selected from the group of: (a) a monovalent C 7 to C 10 aliphatic radical having at least one methyl or ethyl branch when R 2 is hydrogen, or (b) a monovalent C 1 to C 9 straight or branched chain aliphatic group when R 2 is a monovalent C 1 to C 9 straight or branched chain aliphatic group with the proviso that R 1 +R 2 shall have a combined total of from 7 to 10 carbon atoms and at least one of R 1 or R 2 has at least 4 carbon atoms, R 2 is hydrogen or a monovalent C 1 to C 9 branched or straight chain aliphatic group, Z is an alkali metal cation or a nitrogen containing cation having at least one hydrogen attached to the nitrogen, a positive charge equal to x and selected from the group consisting of ammonium cation and cations of a water soluble alkanolamine having 2 to 4 carbon atoms in the alkanol group, C 2 to C 6 alkyl amine, alkyl alkanolamine having 1 to 6 carbon atoms in the alkyl group and 2 to 4 carbon atoms in the alkanol group, heteroaliphatic monoamine in which the heteroatom is oxygen, heteroaliphatic polyamine having oxygen or nitrogen heteroatoms, alkylene diamine having 2 to 6 carbon atoms in the alkylene group, N-alkyl or N-hydroxyalkyl substituted alkylene diamine having 2 to 6 carbon atoms in the alkylene group, morpholine, N-alkyl substituted morpholine or N-aminoalkyl substituted morpholine, x is 1 to 3 y is 1 and m is 1 to 3
Claim 9
Dependent Claim
408 words
A corrosion inhibiting, aqueous functional fluid composition having a pH in the range of from 8 to 12 comprising (a) water, (b) a surface active, corrosion inhibiting, water soluble or dispersible alkali metal, ammonium or organic amine salt of a water insoluble carboxylic acid group terminated amide having one amide linkage ##STR54## per molecule and (c) a second surface active agent, wherein (b) has the following formula ##STR55## where R is a divalent radical selected from the group consisting of a monoethylenically unsaturated C 2 to C 3 aliphatic radical having two free valences in a cis stereo configuration, R 1 is a monovalent organic radical selected from the group of: (a) a monovalent C 7 to C 10 aliphatic group having at least one methyl or ethyl branch or a monovalent heteroaliphatic group having at least one methyl or ethyl branch and the formula R 3 --OR 4 n (II) wherein R 3 is a straight chain or a methyl or ethyl branched C 6 to C 12 alkyl radical, R 4 is a C 2 to C 3 alkylene radical and n is 1 to 2 when R 2 is hydrogen, or (b) a monovalent C 1 to C 11 straight or branched chain aliphatic radical when R 2 is a C 1 to C 11 straight or branched chain monovalent aliphatic radical with the proviso that R 1 +R 2 shall have a combined total of from 8 to 12 carbon atoms and at least one of R 1 or R 2 shall have at least 5 carbon atoms, R 2 is hydrogen or a monovalent C 1 to C 11 branched or straight chain aliphatic group, Z is an alkali metal cation or a nitrogen containing cation having at least one hydrogen attached to the nitrogen, a positive charge equal to x and selected from the group consisting of ammonium cation and cations of a water soluble alkyl alkanolamine having 1 to 6 carbon atoms in the alkyl group and 2 to 4 carbon atoms in the alkanol group, heteroaliphatic monoamine in which the heteroatom is oxygen, heteroaliphatic polyamine having oxygen or nitrogen heteroatoms, alkylene diamine having 2 to 6 carbon atoms in the alkylene group, N-alkyl or N-hydroxyalkyl substituted alkylene diamine having 2 to 6 carbon atoms in the alkylene group, morpholine, N-alkyl substituted morpholine or N-aminoalkyl substituted morpholine, x is 1 to 3, y is 1 and m is 1 to 3.
Claim 10
Dependent Claim
408 words
A corrosion inhibiting, aqueous functional fluid composition having a pH in the range of from 8 to 12 comprising (a) water, (b) a surface active, corrosion inhibiting, water soluble or dispersible alkali metal, ammonium or organic amine salt of a water insoluble carboxylic acid group terminated amide having one amide linkage ##STR54## per molecule and (c) a second surface active agent, wherein (b) has the following formula ##STR55## where R is a divalent radical selected from the group consisting of a monoethylenically unsaturated C 2 to C 3 aliphatic radical having two free valences in a cis stereo configuration, R 1 is a monovalent organic radical selected from the group of: (a) a monovalent C 7 to C 10 aliphatic group having at least one methyl or ethyl branch or a monovalent heteroaliphatic group having at least one methyl or ethyl branch and the formula R 3 --OR 4 n (II) wherein R 3 is a straight chain or a methyl or ethyl branched C 6 to C 12 alkyl radical, R 4 is a C 2 to C 3 alkylene radical and n is 1 to 2 when R 2 is hydrogen, or (b) a monovalent C 1 to C 11 straight or branched chain aliphatic radical when R 2 is a C 1 to C 11 straight or branched chain monovalent aliphatic radical with the proviso that R 1 +R 2 shall have a combined total of from 8 to 12 carbon atoms and at least one of R 1 or R 2 shall have at least 5 carbon atoms, R 2 is hydrogen or a monovalent C 1 to C 11 branched or straight chain aliphatic group, Z is an alkali metal cation or a nitrogen containing cation having at least one hydrogen attached to the nitrogen, a positive charge equal to x and selected from the group consisting of ammonium cation and cations of a water soluble alkyl alkanolamine having 1 to 6 carbon atoms in the alkyl group and 2 to 4 carbon atoms in the alkanol group, heteroaliphatic monoamine in which the heteroatom is oxygen, heteroaliphatic polyamine having oxygen or nitrogen heteroatoms, alkylene diamine having 2 to 6 carbon atoms in the alkylene group, N-alkyl or N-hydroxyalkyl substituted alkylene diamine having 2 to 6 carbon atoms in the alkylene group, morpholine, N-alkyl substituted morpholine or N-aminoalkyl substituted morpholine, x is 1 to 3, y is 1 and m is 1 to 3.
Claim 11
Dependent Claim
415 words
A corrosion inhibiting, aqueous functional fluid composition having a pH in the range of from 8 to 12 comprising (a) water, (b) a surface active, corrosion inhibiting, water soluble or dispersible alkali metal, ammonium or organic amine salt of a water insoluble carboxylic acid group terminated amide having one amide linkage ##STR56## per molecule, (c) a second surface active agent and (d) a water soluble or dispersible lubricant, wherein (b) has the following formula ##STR57## where R is a divalent radical selected from the group consisting of a monoethylenically unsaturated C 2 to C 3 aliphatic radical having two free valences in a cis stereo configuration, R 1 is a monovalent organic radical selected from the group of: (a) a monovalent C 7 to C 10 aliphatic group having at least one methyl or ethyl branch or a monovalent heteroaliphatic group having at least one methyl or ethyl branch and the formula R 3 --OR 4 n (II) wherein R 3 is a straight chain or a methyl or ethyl branched C 6 to C 12 alkyl radical, R 4 is a C 2 to C 3 alkylene radical and n is 1 to 2 when R 2 is hydrogen, or (b) a monovalent C 1 to C 11 straight or branched chain aliphatic radical when R 2 is a C 1 to C 11 straight or branched chain monovalent aliphatic radical with the proviso that R 1 +R 2 shall have a combined total of from 8 to 12 carbon atoms and at least one of R 1 or R 2 shall have at least 5 carbon atoms, R 2 is hydrogen or a monovalent C 1 to C 11 branched or straight chain aliphatic group, Z is an alkali metal cation or a nitrogen containing cation having at least one hydrogen attached to the nitrogen, a positive charge equal to x and selected from the group consisting of ammonium cation and cations of a water soluble alkyl alkanolamine having 1 to 6 carbon atoms in the alkyl group and 2 to 4 carbon atoms in the alkanol group, heteroaliphatic monoamine in which the heteroatom is oxygen, heteroaliphatic polyamine having oxygen or nitrogen heteroatoms, alkylene diamine having 2 to 6 carbon atoms in the alkylene group, N-alkyl or N-hydroxyalkyl substituted alkylene diamine having 2 to 6 carbon atoms in the alkylene group, morpholine, N-alkyl substituted morpholine or N-aminoalkyl substituted morpholine, x is 1 to 3 y is 1 and m is 1 to 3.
Claim 12
Dependent Claim
415 words
A corrosion inhibiting, aqueous functional fluid composition having a pH in the range of from 8 to 12 comprising (a) water, (b) a surface active, corrosion inhibiting, water soluble or dispersible alkali metal, ammonium or organic amine salt of a water insoluble carboxylic acid group terminated amide having one amide linkage ##STR56## per molecule, (c) a second surface active agent and (d) a water soluble or dispersible lubricant, wherein (b) has the following formula ##STR57## where R is a divalent radical selected from the group consisting of a monoethylenically unsaturated C 2 to C 3 aliphatic radical having two free valences in a cis stereo configuration, R 1 is a monovalent organic radical selected from the group of: (a) a monovalent C 7 to C 10 aliphatic group having at least one methyl or ethyl branch or a monovalent heteroaliphatic group having at least one methyl or ethyl branch and the formula R 3 --OR 4 n (II) wherein R 3 is a straight chain or a methyl or ethyl branched C 6 to C 12 alkyl radical, R 4 is a C 2 to C 3 alkylene radical and n is 1 to 2 when R 2 is hydrogen, or (b) a monovalent C 1 to C 11 straight or branched chain aliphatic radical when R 2 is a C 1 to C 11 straight or branched chain monovalent aliphatic radical with the proviso that R 1 +R 2 shall have a combined total of from 8 to 12 carbon atoms and at least one of R 1 or R 2 shall have at least 5 carbon atoms, R 2 is hydrogen or a monovalent C 1 to C 11 branched or straight chain aliphatic group, Z is an alkali metal cation or a nitrogen containing cation having at least one hydrogen attached to the nitrogen, a positive charge equal to x and selected from the group consisting of ammonium cation and cations of a water soluble alkyl alkanolamine having 1 to 6 carbon atoms in the alkyl group and 2 to 4 carbon atoms in the alkanol group, heteroaliphatic monoamine in which the heteroatom is oxygen, heteroaliphatic polyamine having oxygen or nitrogen heteroatoms, alkylene diamine having 2 to 6 carbon atoms in the alkylene group, N-alkyl or N-hydroxyalkyl substituted alkylene diamine having 2 to 6 carbon atoms in the alkylene group, morpholine, N-alkyl substituted morpholine or N-aminoalkyl substituted morpholine, x is 1 to 3 y is 1 and m is 1 to 3.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-04-04 | 1986-10-04 | 1987-04-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-04-04 | 1990-10-04 | 1991-04-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-04-04 | 1994-10-04 | 1995-04-05 | $7700.00 | Window Closed / Lapsed |