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Production of high viscosity index lubricating oil stock

Assignee: Mobil Oil AS
•
Filing: 1981-01-13
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Granted: 1983-02-08
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Expires: 2001-01-13
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Abstract

Abstract A method for enhancing both the pour point and viscosity index (V.I.) of crude oils of high wax content by contact of the same with two different zeolites, such as ZSM-5 and ZSM-35 is disclosed.

Inventors

  • 👤 Stephen M. Oleck
  • 👤 Robert C. Wilson, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 11:13
CPC Classifications
C; C10; C10G; C10G45/00; C10G45/58; C10G45/60; C10G45/64; B; B01; B01J; B01J29/00; B01J29/04; B01J29/06; B01J29/80; B01J29/40; B01J29/65; C10G2400/00; C10G2400/10

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 194 words
A process for catalytically dewaxing a waxy hydrocarbon fraction boiling within the approximate range of 450° to 1050° F. to provide a lubricating oil of high viscosity index which comprises contacting said fraction at a temperature between about 500° and about 675° F., a pressure between about 100 and about 3000 psig at a liquid hourly space velocity between about 0.1 and about 10 with a catalyst comprising two different types of crystalline aluminosilicate zeolites, one type which possesses particularly characterized pore openings defined by (1) a ratio of sorption of n-hexane to o-xylene, on a volume percent basis, of greater than 3, which sorption is determined at a P/P o of 0.1 and at a temperature of 50° C. for n-hexane and 80° C. for o-xylene and (2) by the ability of selectively cracking 3-methylpentane in preference to 2,3-dimethylbutane at 1000° F. and 1 atmosphere pressure from a 1/1/1 weight ratio mixture of n-hexane/3-methylpentane/2,3-dimethylbutane mixture with the ratio of rate constants k 3MP /k DMB being in excess of about 2 and the other type selected from the group consisting of ZSM-5 and ZSM-11 and mixtures thereof and recovering a dewaxed oil product.
Claim 2
Dependent Claim 194 words
A process for catalytically dewaxing a waxy hydrocarbon fraction boiling within the approximate range of 450° to 1050° F. to provide a lubricating oil of high viscosity index which comprises contacting said fraction at a temperature between about 500° and about 675° F., a pressure between about 100 and about 3000 psig at a liquid hourly space velocity between about 0.1 and about 10 with a catalyst comprising two different types of crystalline aluminosilicate zeolites, one type which possesses particularly characterized pore openings defined by (1) a ratio of sorption of n-hexane to o-xylene, on a volume percent basis, of greater than 3, which sorption is determined at a P/P o of 0.1 and at a temperature of 50° C. for n-hexane and 80° C. for o-xylene and (2) by the ability of selectively cracking 3-methylpentane in preference to 2,3-dimethylbutane at 1000° F. and 1 atmosphere pressure from a 1/1/1 weight ratio mixture of n-hexane/3-methylpentane/2,3-dimethylbutane mixture with the ratio of rate constants k 3MP /k DMB being in excess of about 2 and the other type selected from the group consisting of ZSM-5 and ZSM-11 and mixtures thereof and recovering a dewaxed oil product.
Claim 3
Dependent Claim 28 words
The process of claim 1 wherein said contacting is effected in the presence of hydrogen and at least one of said zeolites is associated with a hydrogenation component.
Claim 4
Dependent Claim 26 words
The process of claim 2 wherein said hydrogenation component is selected from the group consisting of nickel, cobalt, molybdenum and tungsten or mixtures and compounds thereof.
Claim 5
Dependent Claim 17 words
The process of claim 1 wherein one of said zeolites is ZSM-23 and the other is ZSM-5.
Claim 6
Dependent Claim 17 words
The process of claim 1 wherein one of said zeolites is ZSM-35 and the other is ZSM-5.
Claim 7
Dependent Claim 18 words
The process of claim 4 wherein said hydrocarbon fraction is first contacted with ZSM-23 and then with ZSM-5.
Claim 8
Dependent Claim 19 words
The process of claim 4 wherein said hydrocarbon fraction is contacted with a catalyst mixture comprising ZSM-23 and ZSM-5.
Claim 9
Dependent Claim 18 words
The process of claim 5 wherein said hydrocarbon fraction is first contacted with ZSM-35 and then with ZSM-5.
Claim 10
Dependent Claim 19 words
The process of claim 5 wherein said hydrocarbon fraction is contacted with a catalyst mixture comprising ZSM-35 and ZSM-5.
Claim 11
Dependent Claim 13 words
The process of claim 1 wherein both zeolites are in the hydrogen form.
Claim 12
Dependent Claim 13 words
The process of claim 2 wherein both zeolites are in the hydrogen form.
Claim 13
Dependent Claim 13 words
The process of claim 3 wherein both zeolites are in the hydrogen form.
Claim 14
Dependent Claim 13 words
The process of claim 4 wherein both zeolites are in the hydrogen form.
Claim 15
Dependent Claim 13 words
The process of claim 5 wherein both zeolites are in the hydrogen form.
Claim 16
Dependent Claim 13 words
The process of claim 6 wherein both zeolites are in the hydrogen form.
Claim 17
Dependent Claim 13 words
The process of claim 7 wherein both zeolites are in the hydrogen form.
Claim 18
Dependent Claim 13 words
The process of claim 8 wherein both zeolites are in the hydrogen form.
Claim 19
Dependent Claim 13 words
The process of claim 9 wherein both zeolites are in the hydrogen form.
Claim 20
Dependent Claim 33 words
The process of claim 1 wherein the dewaxed oil product is subjected to a hydrotreating operation by contact of the same at elevated temperatures and pressures with added hydrogen over a hydrogenation catalyst.

References Cited (Backward Citations)

US3764520A Cited
USRE28398E Cited
US4016245A Cited
US4081490A Cited
US4076842A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-02-07 1986-08-09 1987-02-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-02-07 1990-08-09 1991-02-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-02-07 1994-08-09 1995-02-08 $7700.00 Window Closed / Lapsed

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