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US4222855A Expired / Lapsed US ⏱️ 0.0 years remaining

Production of high viscosity index lubricating oil stock

Assignee: Mobil Oil AS
•
Filing: 1979-03-26
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Granted: 1980-09-16
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Expires: 1999-03-26
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Abstract

Abstract Waxy hydrocarbon oils, e.g., of petroleum origin, boiling within the approximate range of 450 DEG to 1050 DEG F. are catalytically dewaxed utilizing a catalyst comprising a crystalline aluminosilicate zeolite possessing particularly characterized pore openings, such as, for example, ZSM-23 or ZSM-35, which may be associated with a hydrogenation metal.

Inventors

  • 👤 Bruce P. Pelrine
  • 👤 Nai Y. Chen

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 16:12
CPC Classifications
B; B01; B01J; B01J29/00; B01J29/04; B01J29/06; B01J29/70; B01J29/7049; B01J29/40; B01J29/42; B01J29/46; B01J2229/00; B01J2229/10; B01J2229/26; B01J2229/30; B01J2229/36; B01J2229/42; C; C10; C10G; C10G2400/00; C10G2400/10

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 172 words
A process for catalytically dewaxing a waxy hydrocarbon fraction boiling within the approximate range of 450° to 1050° F. to provide a lubricating oil of high viscosity index which comprises contacting said fraction at a temperature between about 500° and about 850° F., a pressure between about 100 and about 3000 psig at a liquid hourly space velocity between about 0.1 and about 10 with a catalyst comprising a crystalline aluminosilicate zeolite possessing particularly characterized pore openings defined by (1) a ratio of sorption of n-hexane to o-xylene, on a volume percent basis, of greater than 3, which sorption is determined at a P/P o of 0.1 and at a temperature of 50° C. for n-hexane and 80° C. for o-xylene and (2) by the ability of selectively cracking 3-methylpentane in preference to 2,3-dimethylbutane at 1000° F. and 1 atmosphere pressure from a 1/1/1 weight ratio mixture of n-hexane/3-methylpentane/2,3-dimethylbutane mixture with the ratio of rate constants k 3MP /k DMB being in excess of about 2 and recovering a dewaxed oil product.
Claim 2
Dependent Claim 172 words
A process for catalytically dewaxing a waxy hydrocarbon fraction boiling within the approximate range of 450° to 1050° F. to provide a lubricating oil of high viscosity index which comprises contacting said fraction at a temperature between about 500° and about 850° F., a pressure between about 100 and about 3000 psig at a liquid hourly space velocity between about 0.1 and about 10 with a catalyst comprising a crystalline aluminosilicate zeolite possessing particularly characterized pore openings defined by (1) a ratio of sorption of n-hexane to o-xylene, on a volume percent basis, of greater than 3, which sorption is determined at a P/P o of 0.1 and at a temperature of 50° C. for n-hexane and 80° C. for o-xylene and (2) by the ability of selectively cracking 3-methylpentane in preference to 2,3-dimethylbutane at 1000° F. and 1 atmosphere pressure from a 1/1/1 weight ratio mixture of n-hexane/3-methylpentane/2,3-dimethylbutane mixture with the ratio of rate constants k 3MP /k DMB being in excess of about 2 and recovering a dewaxed oil product.
Claim 3
Dependent Claim 24 words
The process of claim 1 wherein said contacting is effected in the presence of hydrogen and said zeolite is associated with a hydrogenation metal.
Claim 4
Dependent Claim 20 words
The process of claim 2 wherein said hydrogenation metal is selected from the group consisting of platinum, palladium and zinc.
Claim 5
Dependent Claim 10 words
The process of claim 1 wherein said zeolite is ZSM-23.
Claim 6
Dependent Claim 10 words
The process of claim 1 wherein said zeolite is ZSM-35.
Claim 7
Dependent Claim 14 words
The process of claim 1 wherein said waxy hydrocarbon is a waxy solvent-refined stock.
Claim 8
Dependent Claim 33 words
The process of claim 1 carried out in the presence of hydrogen, wherein the amount of hydrogen is between about 400 and about 8000 standard cubic feet of hydrogen per barrel of feedstock.
Claim 9
Dependent Claim 29 words
The process of claim 1 wherein said pressure is between about 200 and about 1000 psig and said liquid hourly space velocity is between about 0.5 and about 4.
Claim 10
Dependent Claim 10 words
The process of claim 1 wherein said zeolite is HZSM-23.
Claim 11
Dependent Claim 10 words
The process of claim 1 wherein said zeolite is HZSM-35.
Claim 12
Dependent Claim 13 words
The process of claim 1 wherein said zeolite is HZSM-23 associated with zinc.
Claim 13
Dependent Claim 13 words
The process of claim 1 wherein said zeolite is HZSM-23 associated with palladium.

References Cited (Backward Citations)

US3668113A Cited
US3700585A Cited
US3702886A Cited
US3755138A Cited
US3804746A Cited
US3968024A Cited
US4081490A Cited
US4104151A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-09-16 1984-03-17 1984-09-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-09-16 1988-03-17 1988-09-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-09-16 1992-03-17 1992-09-16 $7700.00 Window Closed / Lapsed

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