US4222855A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Production of high viscosity index lubricating oil stock
Assignee: Mobil Oil AS
•
Filing: 1979-03-26
•
Granted: 1980-09-16
•
Expires: 1999-03-26
Abstract
Abstract Waxy hydrocarbon oils, e.g., of petroleum origin, boiling within the approximate range of 450 DEG to 1050 DEG F. are catalytically dewaxed utilizing a catalyst comprising a crystalline aluminosilicate zeolite possessing particularly characterized pore openings, such as, for example, ZSM-23 or ZSM-35, which may be associated with a hydrogenation metal.
Inventors
- 👤 Bruce P. Pelrine
- 👤 Nai Y. Chen
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 16:12
CPC Classifications
B; B01; B01J; B01J29/00; B01J29/04; B01J29/06; B01J29/70; B01J29/7049; B01J29/40; B01J29/42; B01J29/46; B01J2229/00; B01J2229/10; B01J2229/26; B01J2229/30; B01J2229/36; B01J2229/42; C; C10; C10G; C10G2400/00; C10G2400/10
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
172 words
A process for catalytically dewaxing a waxy hydrocarbon fraction boiling within the approximate range of 450° to 1050° F. to provide a lubricating oil of high viscosity index which comprises contacting said fraction at a temperature between about 500° and about 850° F., a pressure between about 100 and about 3000 psig at a liquid hourly space velocity between about 0.1 and about 10 with a catalyst comprising a crystalline aluminosilicate zeolite possessing particularly characterized pore openings defined by (1) a ratio of sorption of n-hexane to o-xylene, on a volume percent basis, of greater than 3, which sorption is determined at a P/P o of 0.1 and at a temperature of 50° C. for n-hexane and 80° C. for o-xylene and (2) by the ability of selectively cracking 3-methylpentane in preference to 2,3-dimethylbutane at 1000° F. and 1 atmosphere pressure from a 1/1/1 weight ratio mixture of n-hexane/3-methylpentane/2,3-dimethylbutane mixture with the ratio of rate constants k 3MP /k DMB being in excess of about 2 and recovering a dewaxed oil product.
Claim 2
Dependent Claim
172 words
A process for catalytically dewaxing a waxy hydrocarbon fraction boiling within the approximate range of 450° to 1050° F. to provide a lubricating oil of high viscosity index which comprises contacting said fraction at a temperature between about 500° and about 850° F., a pressure between about 100 and about 3000 psig at a liquid hourly space velocity between about 0.1 and about 10 with a catalyst comprising a crystalline aluminosilicate zeolite possessing particularly characterized pore openings defined by (1) a ratio of sorption of n-hexane to o-xylene, on a volume percent basis, of greater than 3, which sorption is determined at a P/P o of 0.1 and at a temperature of 50° C. for n-hexane and 80° C. for o-xylene and (2) by the ability of selectively cracking 3-methylpentane in preference to 2,3-dimethylbutane at 1000° F. and 1 atmosphere pressure from a 1/1/1 weight ratio mixture of n-hexane/3-methylpentane/2,3-dimethylbutane mixture with the ratio of rate constants k 3MP /k DMB being in excess of about 2 and recovering a dewaxed oil product.
Claim 3
Dependent Claim
24 words
The process of claim 1 wherein said contacting is effected in the presence of hydrogen and said zeolite is associated with a hydrogenation metal.
Claim 4
Dependent Claim
20 words
The process of claim 2 wherein said hydrogenation metal is selected from the group consisting of platinum, palladium and zinc.
Claim 5
Dependent Claim
10 words
The process of claim 1 wherein said zeolite is ZSM-23.
Claim 6
Dependent Claim
10 words
The process of claim 1 wherein said zeolite is ZSM-35.
Claim 7
Dependent Claim
14 words
The process of claim 1 wherein said waxy hydrocarbon is a waxy solvent-refined stock.
Claim 8
Dependent Claim
33 words
The process of claim 1 carried out in the presence of hydrogen, wherein the amount of hydrogen is between about 400 and about 8000 standard cubic feet of hydrogen per barrel of feedstock.
Claim 9
Dependent Claim
29 words
The process of claim 1 wherein said pressure is between about 200 and about 1000 psig and said liquid hourly space velocity is between about 0.5 and about 4.
Claim 10
Dependent Claim
10 words
The process of claim 1 wherein said zeolite is HZSM-23.
Claim 11
Dependent Claim
10 words
The process of claim 1 wherein said zeolite is HZSM-35.
Claim 12
Dependent Claim
13 words
The process of claim 1 wherein said zeolite is HZSM-23 associated with zinc.
Claim 13
Dependent Claim
13 words
The process of claim 1 wherein said zeolite is HZSM-23 associated with palladium.
References Cited (Backward Citations)
US3668113A
Cited
US3700585A
Cited
US3702886A
Cited
US3755138A
Cited
US3804746A
Cited
US3968024A
Cited
US4081490A
Cited
US4104151A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-09-16 | 1984-03-17 | 1984-09-16 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-09-16 | 1988-03-17 | 1988-09-16 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-09-16 | 1992-03-17 | 1992-09-16 | $7700.00 | Window Closed / Lapsed |