Anisotropic melt phase forming poly(ester-carbonate) derived from 6-hydroxy-2-napthoic acid, aromatic diol, organic compound capable of forming a carbonate linkage, and, optionally, other aromatic hydroxy-acid and carbocyclic dicarboxylic acid

Claim 2

A melt-processable poly(ester-carbonate) capable of forming an anisotropic melt phase at a temperature below approximately 400° C. consisting essentially of recurring moieties I, II, III, and, optionally, IV and V wherein: I is ##STR19## II is O--Ar--O, where Ar is a divalent radical comprising at least one aromatic ring; III is ##STR20## IV is ##STR21## where Ar' is a divalent radical comprising at least one aromatic ring, other than 2,6-naphthylene; and V is ##STR22## where A is a divalent carbocyclic radical, wherein at least some of the hydrogen atoms present upon the rings optionally may be replaced by substitution selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, phenyl, and mixtures thereof, and wherein moiety I is present in the polymer in a concentration of at lesast approximately 20 mole percent, moiety IV is present in the polymer in a concentration within the range of approximately 0 to 60 mole percent, with the total molar concentration of moieties I and IV in the polymer being within the range of approximately 20 to 80 mole percent, moiety II is present in the polymer in a concentration within the range of approximately 10 to 40 mole percent, moiety III is present in the polymer in a concentration within the range of approximately 10 to 40 mole percent, and moiety V is present in the polymer in a concentration within the range of approximately 0 to 30 mole percent, with the molar concentration of moiety II being substantially equal to the sum of the molar concentrations of moieties III and V.

Claim 3

The melt-processable poly(ester-carbonate) of claim 1 which is capable of forming an anisotropic melt phase at a temperature below approximately 350° C.

Claim 4

The melt-processable poly(ester-carbonate) of claim 1 which exhibits an inherent viscosity of at least approximately 0.5 dl./g. when measured at a concentration of 0.1 weight/volume percent in pentafluorophenol at 60° C.

Claim 5

The melt-processable poly(ester-carbonate) of claim 1 wherein moiety I is present in a concentration within the range of approximately 20 to 70 mole percent.

Claim 6

The melt-processable poly(ester-carbonate) of claim 1 wherein moiety II is present in a concentration within the range of approximately 15 to 35 mole percent.

Claim 7

The melt-processable poly(ester-carbonate) of claim 1 wherein moiety III is derived from a diaryl carbonate.

Claim 8

The melt-processable poly(ester-carbonate) of claim 6 wherein moiety III is derived from diphenyl carbonate.

Claim 9

The melt-processable poly(ester-carbonate) of claim 1 wherein moiety III is present in a concentration within the range of approximately 15 to 35 mole percent.

Claim 10

The melt-processable poly(ester-carbonate) of claim 1 wherein IV is present in a concentration within the range of approximately 0 to 30 mole percent.

Claim 11

The melt-processable poly(ester-carbonate) of claim 1 wherein moiety V is derived from a member of the group consisting of terephthalic acid, isophthalic acid, 2,6-naphthalenedicarboxylic acid, trans-1,4-cyclohexanedicarboxylic acid, and mixtures thereof.

Claim 12

The melt-processable poly(ester-carbonate) of claim 1 wherein moiety V is present in a concentration within the range of approximately 0 to 20 mole percent.

Claim 13

A molding compound comprising the melt-processable poly(ester-carbonate) of claim 1 which incorporates approximately 1 to 60 percent by weight of a solid filler and/or reinforcing agent.

Claim 14

A molded article comprising the melt-processable poly(ester-carbonate) of claim 1.

Claim 15

A fiber which has been melt spun from the melt-processable poly(ester-carbonate) of claim 1.

Claim 16

A film which has been melt extruded from the melt-processable poly(ester-carbonate) of claim 1.

Claim 17

A melt-processable poly(ester-carbonate) capable of forming an anisotropic melt phase at a temperature below approximately 400° C., consisting essentially of recurring moieties I, II, III, and optionally, IV and V wherein: I is ##STR23## II is O--Ar--O, where Ar is a divalent radical comprising at least one aromatic ring; III is ##STR24## IV is ##STR25## where Ar' is a divalent radical comprising at least one aromatic ring, other than 2,6-naphthylene; and V is ##STR26## where A is a divalent carbocyclic radical, wherein at least some of the hydrogen atoms present upon the rings optionally may be replaced by substitution selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, phenyl, and mixtures thereof, and wherein moiety I is present in the polymer in a concentration within the range of approximately 20 to 70 mole percent, moiety IV is present in the polymer in a concentration within the range of approximately 0 to 30 mole percent, with the total molar concentration of moieties I and IV in the polymer being within the range of approximately 20 to 70 mole percent, moiety II is present in the polymer in a concentration within the range of approximately 15 to 35 mole percent, moiety III is present in the polymer in a concentration within the range of approximately 15 to 35 mole percent, and moiety V is present in the polymer in a concentration within the range of approximately 0 to 20 mole percent, with the molar concentration of moiety II being substantially equal to the total molar concentration of moieties III and V.

Claim 18

A melt-processable poly(ester-carbonate) capable of forming an anisotropic melt phase at a temperature below approximately 400° C., consisting essentially of recurring moieties I, II, III, and optionally, IV and V wherein: I is ##STR23## II is O--Ar--O, where Ar is a divalent radical comprising at least one aromatic ring; III is ##STR24## IV is ##STR25## where Ar' is a divalent radical comprising at least one aromatic ring, other than 2,6-naphthylene; and V is ##STR26## where A is a divalent carbocyclic radical, wherein at least some of the hydrogen atoms present upon the rings optionally may be replaced by substitution selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, phenyl, and mixtures thereof, and wherein moiety I is present in the polymer in a concentration within the range of approximately 20 to 70 mole percent, moiety IV is present in the polymer in a concentration within the range of approximately 0 to 30 mole percent, with the total molar concentration of moieties I and IV in the polymer being within the range of approximately 20 to 70 mole percent, moiety II is present in the polymer in a concentration within the range of approximately 15 to 35 mole percent, moiety III is present in the polymer in a concentration within the range of approximately 15 to 35 mole percent, and moiety V is present in the polymer in a concentration within the range of approximately 0 to 20 mole percent, with the molar concentration of moiety II being substantially equal to the total molar concentration of moieties III and V.

Claim 19

The melt-processable poly(ester-carbonate) of claim 16 which is capable of forming an anisotropic melt phase at a temperature below approximately 350° C.

Claim 20

The melt-processable poly(ester-carbonate) of claim 16 which exhibits an inherent viscosity of at least approximately 0.5 dl./g. when measured at a concentration of 0.1 weight/volume percent in pentafluorophenol at 60° C.

Claim 21

The melt-processable poly(ester-carbonate) of claim 16 wherein moiety I is present in a concentration within the range of approximately 30 to 60 mole percent.

Claim 22

The melt-processable poly(ester-carbonate) of claim 16 wherein moiety II is a p-dioxyphenyl moiety.

Claim 23

The melt-processable poly(ester-carbonate) of claim 16 wherein moiety II is present in a concentration within the range of approximately 20 to 30 mole percent.

Claim 24

The melt-processable poly(ester-carbonate) of claim 16 wherein moiety III is derived from a diaryl carbonate.

Claim 25

The melt-processable poly(ester-carbonate) of claim 22 wherein moiety III is derived from diphenyl carbonate.

Claim 26

The melt-processable poly(ester-carbonate) of claim 1 wherein moiety III is present in a concentration within the range of approximately 20 to 30 mole percent.

Claim 27

The melt-processable poly(ester-carbonate) of claim 16 wherein moiety IV is a p-oxybenzoyl moiety.

Claim 28

The melt-processable poly(ester-carbonate) of claim 16 wherein moiety V is derived from a member of the group consisting of terephthalic acid, isophthalic acid, 2,6-naphthalenedicarboxylic acid, trans-1,4-cyclohexanedicarboxylic acid, and mixtures thereof.

Claim 29

The melt-processable poly(ester-carbonate) of claim 16 wherein moiety V is present in a concentration within the range of approximately 0 to 10 mole percent.

Claim 30

A molding compound comprising the melt-processable poly(ester-carbonate) of claim 16 which incorporates approximately 1 to 60 percent by weight of a solid filler and/or reinforcing agent.

Claim 31

A molded article comprising the melt-processable poly(ester-carbonate) of claim 16.

Claim 32

A fiber which has been melt spun from the melt-processable poly(ester-carbonate) of claim 16.

Claim 33

A film which has been melt extruded from the melt-processable poly(ester-carbonate) of claim 16.

Claim 34

A melt-processable poly(ester-carbonate) capable of forming an anisotropic melt phase at a temperature below approximately 400° C. consisting essentially of recurring moieties I, II, III, and, optionally, IV and V wherein: I is ##STR27## II is ##STR28## III is ##STR29## IV is ##STR30## and V is ##STR31## where A is a divalent carbocyclic radical, wherein at least some of the hydrogen atoms present upon the rings optionally may be replaced by substitution selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, phenyl, and mixtures thereof, and wherein moiety I is present in the polymer in a concentration within the range of approximately 20 to 70 mole percent, moiety IV is present in the polymer in a concentration within the range of approximately 0 to 30 mole percent, with the total molar concentration of moieties I and IV in the polymer being within the range of approximately 20 to 70 mole percent, moiety II is present in the polymer in a concentration within the range of approximately 20 to 30 mole percent, moiety III is present in the polymer in a concentration within the range of approximately 20 to 30 mole percent, and moiety V is present in the polymer in a concentration within the range of approximately 0 to 10 mole percent, with the molar concentration of moiety II being substantially equal to the total molar concentration of moieties III and V.

Claim 35

A melt-processable poly(ester-carbonate) capable of forming an anisotropic melt phase at a temperature below approximately 400° C. consisting essentially of recurring moieties I, II, III, and, optionally, IV and V wherein: I is ##STR27## II is ##STR28## III is ##STR29## IV is ##STR30## and V is ##STR31## where A is a divalent carbocyclic radical, wherein at least some of the hydrogen atoms present upon the rings optionally may be replaced by substitution selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, phenyl, and mixtures thereof, and wherein moiety I is present in the polymer in a concentration within the range of approximately 20 to 70 mole percent, moiety IV is present in the polymer in a concentration within the range of approximately 0 to 30 mole percent, with the total molar concentration of moieties I and IV in the polymer being within the range of approximately 20 to 70 mole percent, moiety II is present in the polymer in a concentration within the range of approximately 20 to 30 mole percent, moiety III is present in the polymer in a concentration within the range of approximately 20 to 30 mole percent, and moiety V is present in the polymer in a concentration within the range of approximately 0 to 10 mole percent, with the molar concentration of moiety II being substantially equal to the total molar concentration of moieties III and V.

Claim 36

The melt-processable poly(ester-carbonate) of claim 32 which is capable of forming an anisotropic melt phase at a temperature below approximately 350° C.

Claim 37

The melt-processable poly(ester-carbonate) of claim 32 which exhibits an inherent viscosity of at least approximately 0.5 dl./g. when measured at a concentration of 0.1 weight/volume percent in pentafluorophenol at 60° C.

Claim 38

The melt-processable poly(ester-carbonate) of claim 32 wherein moiety III is derived from a diaryl carbonate.

Claim 39

The melt-processable poly(ester-carbonate) of claim 35 wherein moiety III is derived from diphenyl carbonate.

Claim 40

The melt-processable poly(ester-carbonate) of claim 32 wherein moiety IV is present in a concentration within the range of approximately 5 to 30 mole percent.

Claim 41

The melt-processable poly(ester-carbonate) of claim 32 wherein moiety V is derived from a member of the group consisting of terephthalic acid, isophthalic acid, 2,6-naphthalenedicarboxylic acid, trans-1,4-cyclohexanedicarboxylic acid, and mixtures thereof.

Claim 42

The melt-processable poly(ester-carbonate) of claim 32 wherein moiety V is present in a concentration within the range of approximately 5 to 10 mole percent.

Claim 43

A molding compound comprising the melt-processable poly(ester-carbonate) of claim 32 which incorporates approximately 1 to 60 percent by weight of a solid filler and/or reinforcing agent.

Claim 44

A molded article comprising the melt-processable poly(ester-carbonate) of claim 32.

Claim 45

A fiber which has been melt spun from the melt-processable poly(ester-carbonate) of claim 32.

Claim 46

A film which has been melt extruded from the melt-processable poly(ester-carbonate) of claim 32.