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US4310652A Expired / Lapsed US ⏱️ 0.0 years remaining

Melt processable poly(ester carbonate) with high glass transition temperature

Assignee: Honeywell International Inc
•
Filing: 1980-03-24
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Granted: 1982-01-12
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Expires: 2000-03-24
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Abstract

Abstract Poly(ester aromatic dihydric alcohol) polymers having carbonate moieties, aromatic or cycloaliphatic dicarboxylic acid moieties and carbonate moieties and having high glass transition temperatures (over 100 DEG C.) and being melt processable. At least part of the aromatic dihydric alcohol moieties have the 4-carbon of each of two phenoxies covalently bonded to the same ring carbon of a carbocyclic or heterocyclic moiety. Representative poly(ester carbonates) are formed from bisphenol-A, phenolphthalein, terephthaloyl chloride and phosgene.

Inventors

  • 👤 Bruce T. DeBona
  • 👤 Dusan C. Prevorsek

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 15:33
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/64

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 89 words
A poly(ester carbonate) consisting essentially of about equimolar amounts of moieties derived from aromatic diols and a combination of carbonate moieties and aromatic or cycloalphatic diacyl moieties, with at least about 5 mol percent of the moieties derived from aromatic diols being a bisphenoxy moiety having the 4-carbon of each of two phenoxies covalently bonded to the same ring carbon of a carbocyclic of heterocyclic moiety, said carbocyclic or heterocyclic moiety having 5 to 14 cyclic atoms in 1 to 3 rings and being inert under polymerization reaction conditions.
Claim 2
Dependent Claim 89 words
A poly(ester carbonate) consisting essentially of about equimolar amounts of moieties derived from aromatic diols and a combination of carbonate moieties and aromatic or cycloalphatic diacyl moieties, with at least about 5 mol percent of the moieties derived from aromatic diols being a bisphenoxy moiety having the 4-carbon of each of two phenoxies covalently bonded to the same ring carbon of a carbocyclic of heterocyclic moiety, said carbocyclic or heterocyclic moiety having 5 to 14 cyclic atoms in 1 to 3 rings and being inert under polymerization reaction conditions.
Claim 3
Dependent Claim 37 words
The poly(ester carbonate) of claim 1 wherein the moieties derived from aromatic diols comprise about 5 to about 35 mol percent moieties derived from phenolphthalein and about 70 to about 95 mol percent moieties derived from bisphenol-A.
Claim 4
Dependent Claim 30 words
The poly(ester carbonate) of claim 1 or claim 2 wherein the aromatic or cycloaliphatic diacyl moieties are selected from the group consisting of terephthaloyl moieties, isophthaloyl moieties and mixtures thereof.
Claim 5
Dependent Claim 18 words
The poly(ester carbonate) of claim 1 or claim 2 wherein the aromatic or cycloaliphatic diacyl moieties are terephthaloyl.
Claim 6
Dependent Claim 38 words
The poly(ester carbonate) of claim 4 wherein the moieties derived from aromatic diols comprise between about 10 and about 25 mol percent moieties derived from phenolphthalein and about 75 to about 90 mol percent moieties derived from bisphenol-A.
Claim 7
Dependent Claim 35 words
The poly(ester-carbonate) of claim 1 wherein said bisphenoxy moiety is derived from the condensation of phenol with a carboxyl-containing compound selected from the group consisting of phthalic anhydride, cyclohexanone, fluorenone, indanone, tetralone, and mixtures thereof.

References Cited (Backward Citations)

US3169121A Cited
US3036037A Cited
US3036036A Cited
US3036039A Cited
GB1179400A Cited
US4156069A Cited
US4078999A Cited
US4105633A Cited
US4167536A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-01-11 1985-07-13 1986-01-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-01-11 1989-07-13 1990-01-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-01-11 1993-07-13 1994-01-12 $7700.00 Window Closed / Lapsed

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