Perfluorodiglycidyl ethers

Claim 2

A homopolymer of a perfluoroglycidylether of the formula ##STR33## wherein R F is: ##STR34## wherein R 1 is a carbon-carbon bond or a linear or branched perfluoroalkylene group of 1 to 12 carbon atoms; ##STR35## Y and Y' are --F or --CF 3 , provided that only one of Y and Y' can be --CF 3 ; or ##STR36## wherein R 3 is a linear or branched perfluoroalkylene group of carbon content such that the moiety ##STR37## does not exceed 15 carbon atoms; Y, independently, is --F or --CF 3 ; n is 1 to 4; and Q is as defined above.

Claim 3

A copolymer of a perfluoroglycidyl ether of the formula ##STR38## wherein R F is: ##STR39## wherein R 1 is a carbon-carbon bond or a linear or branched perfluoroalkylene group of 1 to 12 carbon atoms; ##STR40## Y and Y' are --F or --CF 3 , provided that only one of Y and Y' can be --CF 3 ; or ##STR41## wherein R 3 is a linear or branched perfluoroalkylene group of carbon content such that the moiety ##STR42## does not exceed 15 carbon atoms; Y, independently, is --F or --CF 3 ; n is 1 to 4; and Q is as defined above and at least one comonomer selected from the group consisting of hexafluoropropylene oxide, tetrafluoroethylene oxide, a different perfluoroglycidyl ether from the class of perfluoroglycidyl ethers described above and a perfluoroglycidyl ether of the formula ##STR43## wherein R 1 is: ##STR44## wherein R 1 is a carbon-carbon bond or a linear or branched perfluoroalkylene group of 1 to 12 carbon atoms; Q 1 is --SO 2 F, --COF, --F, --Cl, --Br, --I, --CN, --CO 2 H, --OC 6 F 5 , or --CO 2 R 4 where R 4 is --CH 3 or --C 2 H 5 ; Y and Y' are --F or --CF 3 , provided that only one of Y and Y' can be --CF 3 ; or (ii) --CF(R 2 ) 2 wherein R 2 is --F, --CF 2 Cl, --CF 2 CN, --CF 2 COF, --CF 2 CO 2 H, --CF 2 OCF(CF 3 ) 2 or --CF 2 CO 2 R 4 where R 4 is defined as above; or ##STR45## wherein R 3 is a linear or branched perfluoroalkylene group of carbon content such that the moiety ##STR46## does not exceed 15 carbon atoms; Y independently is --F or --CF 3 ; n is 1 to 4; l and Q 1 is as defined above; or (iv) --C 6 F 5 .

Claim 4

A copolymer of a perfluoroglycidyl ether of the formula ##STR38## wherein R F is: ##STR39## wherein R 1 is a carbon-carbon bond or a linear or branched perfluoroalkylene group of 1 to 12 carbon atoms; ##STR40## Y and Y' are --F or --CF 3 , provided that only one of Y and Y' can be --CF 3 ; or ##STR41## wherein R 3 is a linear or branched perfluoroalkylene group of carbon content such that the moiety ##STR42## does not exceed 15 carbon atoms; Y, independently, is --F or --CF 3 ; n is 1 to 4; and Q is as defined above and at least one comonomer selected from the group consisting of hexafluoropropylene oxide, tetrafluoroethylene oxide, a different perfluoroglycidyl ether from the class of perfluoroglycidyl ethers described above and a perfluoroglycidyl ether of the formula ##STR43## wherein R 1 is: ##STR44## wherein R 1 is a carbon-carbon bond or a linear or branched perfluoroalkylene group of 1 to 12 carbon atoms; Q 1 is --SO 2 F, --COF, --F, --Cl, --Br, --I, --CN, --CO 2 H, --OC 6 F 5 , or --CO 2 R 4 where R 4 is --CH 3 or --C 2 H 5 ; Y and Y' are --F or --CF 3 , provided that only one of Y and Y' can be --CF 3 ; or (ii) --CF(R 2 ) 2 wherein R 2 is --F, --CF 2 Cl, --CF 2 CN, --CF 2 COF, --CF 2 CO 2 H, --CF 2 OCF(CF 3 ) 2 or --CF 2 CO 2 R 4 where R 4 is defined as above; or ##STR45## wherein R 3 is a linear or branched perfluoroalkylene group of carbon content such that the moiety ##STR46## does not exceed 15 carbon atoms; Y independently is --F or --CF 3 ; n is 1 to 4; l and Q 1 is as defined above; or (iv) --C 6 F 5 .

Claim 5

A copolymer of claim 2 in which the comonomer is hexafluoropropylene oxide.

Claim 6

A copolymer of a perfluorodiglycidyl ether of claim 1 and a polymer selected from the group consisting of homopolymers of hexafluoropropylene oxide, homopolymers of tetrafluoroethylene oxide, and copolymers of at least two of hexafluoropropylene oxide, tetrafluoroethylene oxide and perfluoroglycidyl ethers of the formula: ##STR47## wherein R F 1 is: ##STR48## wherein R 1 is a carbon-carbon bond or a linear or branched perfluoroalkylene group of 1 to 12 carbon atoms; Q 1 is --SO 2 F, --COF, --F, --Cl, --Br, --I, --CN, --CO 2 H, --OC 6 F 5 , or --CO 2 R 4 where R 4 is --CH 3 or --C 2 H 5 ; Y and Y' are --F or --CF 3 , provided that only one of Y and Y' can be --CF 3 ; or (ii) --CF(R 2 ) 2 wherein R 2 is --F, --CF 2 Cl, --CF 2 CN, --CF 2 COF, --CF 2 CO 2 H, --CF 2 OCF(CF 3 ) 2 or --CF 2 CO 2 R 4 where R 4 is defined as above; or ##STR49## wherein R 3 is a linear or branched perfluoroalkylene group of carbon content such that the moiety ##STR50## does not exceed 15 carbon atoms; Y independently is --F or --CF 3 ; n is 1 to 4; and Q 1 is as defined above; or (iv) --C 6 F 5 .

Claim 7

A copolymer of a perfluorodiglycidyl ether of claim 1 and a polymer selected from the group consisting of homopolymers of hexafluoropropylene oxide and copolymers of hexafluoropropylene oxide and perfluoroglycidyl ethers of the formula: ##STR51## wherein R F 1 is: ##STR52## wherein R 1 is a carbon-carbon bond or a linear or branched perfluoroalkylene group of 1 to 12 carbon atoms; Q 1 is --SO 2 F, --COF, --F, --Cl, --Br, --I, --CN, --CO 2 H, --OC 6 F 5 , or --CO 2 R 4 where R 4 is --CH 3 or --C 2 H 5 ; Y and Y' are --F or --CF 3 , provided that only one of Y and Y' can be --CF 3 ; or (ii) --CF(R 2 ) 2 wherein R 2 is --F, --CF 2 Cl, --CF 2 CN, --CF 2 COF, --CF 2 CO 2 H, --CF 2 OCF(CF 3 ) 2 or --CF 2 CO 2 R 4 where R 4 is defined as above; or ##STR53## wherein R 3 is a linear or branched perfluoroalkylene group of carbon content such that the moiety ##STR54## does not exceed 15 carbon atoms; Y independently is --F or --CF 3 ; n is 1 to 4; and Q 1 is as defined above; or (iv) --C 6 F 5 .

Claim 8

A copolymer of a perfluorodiglycidyl ether of claim 1 and a copolymer of hexafluoropropylene oxide and perfluoro-6,7-epoxy-4-oxaheptanenitrile.

Claim 9

The copolymer of claim 6 in which the perfluorodiglycidyl ether of claim 1 is perfluoro-1,2-epoxy-13,14-epoxy-4,11-dioxatetradecane.

Claim 10

The copolymer of claim 6 wherein the perfluorodiglycidyl ether of claim 1 is perfluoro-1,2-epoxy-15,16-epoxy-6,11-dimethyl-4,7,10,13-tetraoxahexadecane

Claim 11

A vulcanized article made from a copolymer of claim 4.