US4255299A
Expired / Lapsed
US
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Polymer containing perfluoroalkyl group, process for preparing the same and coating composition
Assignee: Daikin Industries Ltd
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Filing: 1979-12-19
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Granted: 1981-03-10
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Expires: 1999-12-19
Abstract
Abstract A polymer containing perfluoroalkyl group in its side chain which is an addition reaction product of a polymer having the following general formula: <IMAGE> (I) wherein R is phenyl group or alkoxyl group having 1 to 12 carbon atoms, R1 is alkyl group having 1 to 12 carbon atoms, and n is an integer of 10 to 2,000, with an epoxy compound selected from the group consisting of <IMAGE> (IIa) <IMAGE> (IIb) and <IMAGE> (IIc) wherein Rf is perfluoroalkyl group having 3 to 20 carbon atoms and R2 is alkyl group having 1 to 12 carbon atoms, the addition reaction product containing 0.1 to 50% by mole of the group derived from the epoxy compound having the formulae (IIa) to (IIc) per 1 mole of the recurring unit of the polymer having the formula (I). The polymer is good in compatibility with film-forming resins and solvents and improves the leveling property of a coating composition when incorporated thereinto and the surface smoothness of the film obtained from the composition.
Inventors
- 👤 Shigeo Daimon
- 👤 Kazuo Okamura
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 05:37
CPC Classifications
C; C08; C08F; C08F8/00; C08F8/34; C08F8/18; C08F8/30
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
129 words
A polymer containing perfluoroalkyl groups in its side chains which is an addition reaction product of a polymer having the following general formula: ##STR5## wherein R is a phenyl group or alkoxyl group having 1 to 12 carbon atoms, R 1 is an alkyl group having 1 to 12 carbon atoms, and n is an integer of 10 to 2,000, with an epoxy compound selected from the group consisting of ##STR6## wherein R f is a perfluoroalkyl group having 3 to 20 carbon atoms and R 2 is an alkyl group having 1 to 12 carbon atoms, the addition reaction product containing 0.1 to 50% by mole of the group derived from the epoxy compound per 1 mole of the recurring unit of the polymer having the formula (I).
Claim 2
Dependent Claim
129 words
A polymer containing perfluoroalkyl groups in its side chains which is an addition reaction product of a polymer having the following general formula: ##STR5## wherein R is a phenyl group or alkoxyl group having 1 to 12 carbon atoms, R 1 is an alkyl group having 1 to 12 carbon atoms, and n is an integer of 10 to 2,000, with an epoxy compound selected from the group consisting of ##STR6## wherein R f is a perfluoroalkyl group having 3 to 20 carbon atoms and R 2 is an alkyl group having 1 to 12 carbon atoms, the addition reaction product containing 0.1 to 50% by mole of the group derived from the epoxy compound per 1 mole of the recurring unit of the polymer having the formula (I).
Claim 3
Dependent Claim
129 words
The polymer of claim 1, in which the polymer of the formula (I) is that in which R is an alkoxyl group having 1 to 4 carbon atoms, R 1 is an alkyl group having 1 to 4 carbon atoms, and n is an integer of 50 to 1,500, and the epoxy compound is one member selected from the group consisting of the compounds of the formulae (IIa), (IIb) and (IIc) wherein R f is a perfluoroalkyl group having 3 to 10 carbon atoms and R 2 is an alkyl group having 1 to 3 carbon atoms, the addition reaction product containing 1 to 30% by mole of the group derived from the epoxy compound per 1 mole of the recurring unit of the polymer having the formula (I).
Claim 4
Dependent Claim
144 words
A process for preparing a polymer having perfluoroalkyl groups in its side chains which comprises reacting a polymer having the following general formula: ##STR7## wherein R is a phenyl group or an alkoxyl group having 1 to 12 carbon atoms, R 1 is an alkyl group having 1 to 12 carbon atoms, and n is an integer of 10 to 2,000, with an epoxy compound selected from the group consisting of ##STR8## wherein R f is a perfluoroalkyl group having 3 to 20 carbon atoms and R 2 is an alkyl group having 1 to 12 carbon atoms, in the presence of a tertiary amine or a quaternary ammonium salt so that the obtained reaction product contains 0.1 to 50% by mole of the group derived from the epoxy compound per 1 mole of the recurring unit of the polymer having the formula (I).
Claim 5
Dependent Claim
144 words
A process for preparing a polymer having perfluoroalkyl groups in its side chains which comprises reacting a polymer having the following general formula: ##STR7## wherein R is a phenyl group or an alkoxyl group having 1 to 12 carbon atoms, R 1 is an alkyl group having 1 to 12 carbon atoms, and n is an integer of 10 to 2,000, with an epoxy compound selected from the group consisting of ##STR8## wherein R f is a perfluoroalkyl group having 3 to 20 carbon atoms and R 2 is an alkyl group having 1 to 12 carbon atoms, in the presence of a tertiary amine or a quaternary ammonium salt so that the obtained reaction product contains 0.1 to 50% by mole of the group derived from the epoxy compound per 1 mole of the recurring unit of the polymer having the formula (I).
Claim 6
Dependent Claim
142 words
A coating composition comprising a film-forming resin and an effective amount of a polymer containing perfluoroalkyl groups in its side chains which is an addition reaction product of a polymer having the following general formula: ##STR9## wherein R is a phenyl group or an alkoxyl group having 1 to 12 carbon atoms, R 1 is an alkyl group having 1 to 12 carbon atoms, and n is an integer of 10 to 2,000, with an epoxy compound selected from the group consisting of ##STR10## wherein R f is a perfluoroalkyl group having 3 to 20 carbon atoms and R 2 is an alkyl group having 1 to 12 carbon atoms, the addition reaction product containing 0.1 to 50% by mole of the group derived from the epoxy compound per 1 mole of the recurring unit of the polymer having the formula (I).
Claim 7
Dependent Claim
142 words
A coating composition comprising a film-forming resin and an effective amount of a polymer containing perfluoroalkyl groups in its side chains which is an addition reaction product of a polymer having the following general formula: ##STR9## wherein R is a phenyl group or an alkoxyl group having 1 to 12 carbon atoms, R 1 is an alkyl group having 1 to 12 carbon atoms, and n is an integer of 10 to 2,000, with an epoxy compound selected from the group consisting of ##STR10## wherein R f is a perfluoroalkyl group having 3 to 20 carbon atoms and R 2 is an alkyl group having 1 to 12 carbon atoms, the addition reaction product containing 0.1 to 50% by mole of the group derived from the epoxy compound per 1 mole of the recurring unit of the polymer having the formula (I).
Claim 8
Dependent Claim
136 words
The coating composition of claim 4, in which the polymer containing perfluoroalkyl groups is an addition reaction product of the polymer of the formula (I) in which R is an alkoxyl group having 1 to 4 carbon atoms, R 1 is an alkyl group having 1 to 4 carbon atoms, and n is an integer of 50 to 1,500, with the epoxy compound selected from the group consisting of the compounds of the formulae (IIa), (IIb) and (IIc) wherein R f is a perfluoroalkyl group having 3 to 10 carbon atoms and R 2 is an alkyl group having 1 to 3 carbon atoms, the addition reaction product containing 1 to 30% by mole of the group derived from the epoxy compound per 1 mole of the recurring unit of the polymer having the formula (I).
Claim 9
Dependent Claim
34 words
The coating composition of claim 4, in which the polymer containing perfluoroalkyl groups is used in an amount of 0.05 to 2 parts by weight per 100 parts by weight of the film-forming resin.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-03-09 | 1984-09-08 | 1985-03-10 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-03-09 | 1988-09-08 | 1989-03-10 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-03-09 | 1992-09-08 | 1993-03-10 | $7700.00 | Window Closed / Lapsed |