Polyesters of N,N-di-alkanol-amines with di-(hydroxy-alkyl-benzyl) malonic acids and use thereof as stabilizers for polymers

Claim 2

Polyesters of N,N-di-alkanol-amines with di-(hydroxy-alkyl-benzyl)malonic acids, having the general formula: ##STR13## wherein: each of R 1 and R 2 , which may be the same or different, is an alkyl radical having 1 to 6 carbon atoms, an aralkyl radical having 7 to 9 carbon atoms or a cyclo-alkyl radical having 5 to 8 carbon atoms; A is a nitrogen containing divalent radical selected from the group consisting of: (a) a radical ##STR14## in which R 3 may be an alkyl radical having 1 to 12 carbon atoms, an aryl radical having 6 to 12 carbon atoms or an alkyl-substituted piperidyl radical of the type: ##STR15## wherein: each of R 4 , R 5 , R 6 and R 7 , which may be the same or different, is an alkyl radical having 1 to 4 carbon atoms, and R 8 is hydrogen or an alkyl radical having 1 to 4 carbon atoms; (b) a radical ##STR16## wherein R 3 has the same meaning specified hereinbefore and B is an alkylene radical having 2 to 12 carbon atoms or a cyclo-alkylene radical having 3 to 12 carbon atoms; (c) a radical ##STR17## wherein: each of R 9 , R 10 , R 11 , R 12 , R 13 , R 14 , R 15 and R 16 , which may the same or different is hydrogen or an alkyl radical having 1 to 4 carbon atoms, or two by two belong to an aliphatic or aromatic cycle having 5 to 12 carbon atoms; m is an integer from 1 to 12 and n is an integer from 2 to 100.

Claim 3

Polyesters of N,N-di-alkanol-amines with di-(hydroxy-alkyl-benzyl)malonic acids, having general formula (I), according to claim 1, characterized in that the average value of n ranges from 4 to 20.

Claim 4

Compositions of thermoplastic synthetic polymers, stabilized to oxidation and to ageing, having incorporated therein, in an amount sufficient to prevent any degradation of the polymer, a polyester of a N,N-di-alkanol amine with a di-(hydroxy-alkyl-benzyl)malonic acid, having the general formula: ##STR18## wherein: each of R 1 and R 2 , which may be the same or different, is an alkyl radical having 1 to 6 carbon atoms, an aralkyl radical having 7 to 9 carbon atoms or a cyclo-alkyl radical having 5 to 8 carbon atoms; A is a nitrogen containing divalent radical selected from the group consisting of: (a) a radical ##STR19## in which R 3 may be an alkyl radical having 1 to 12 carbon atoms, an aryl radical having 6 to 12 carbon atoms, or an alkyl-substituted piperidyl radical of the type: ##STR20## wherein: each of R 4 , R 5 , R 6 and R 7 , which may be the same or different, is an alkyl radical having 1 to 4 carbon atoms, and R 8 is hydrogen or an alkyl radical having 1 to 4 carbon atoms; (b) a radical ##STR21## wherein R 3 has the same meaning specified hereinbefore and B is an alkylene radical having 2 to 12 carbon atoms or a cyclo-alkylene radical having 3 to 12 carbon atoms; (c) a radical ##STR22## wherein: each of R 9 , R 10 , R 11 , R 12 , R 13 , R 14 , R 15 and R 16 , which may be the same or different, is hydrogen or an alkyl radical having 1 to 4 carbon atoms, or two by two belong to an aliphatic or aromatic cycle having 5 to 12 carbon atoms; m is an integer from 1 to 12 and n is an integer from 2 to 100.

Claim 5

Compositions of thermoplastic synthetic polymers, stabilized to oxidation and to ageing, having incorporated therein, in an amount sufficient to prevent any degradation of the polymer, a polyester of a N,N-di-alkanol amine with a di-(hydroxy-alkyl-benzyl)malonic acid, having the general formula: ##STR18## wherein: each of R 1 and R 2 , which may be the same or different, is an alkyl radical having 1 to 6 carbon atoms, an aralkyl radical having 7 to 9 carbon atoms or a cyclo-alkyl radical having 5 to 8 carbon atoms; A is a nitrogen containing divalent radical selected from the group consisting of: (a) a radical ##STR19## in which R 3 may be an alkyl radical having 1 to 12 carbon atoms, an aryl radical having 6 to 12 carbon atoms, or an alkyl-substituted piperidyl radical of the type: ##STR20## wherein: each of R 4 , R 5 , R 6 and R 7 , which may be the same or different, is an alkyl radical having 1 to 4 carbon atoms, and R 8 is hydrogen or an alkyl radical having 1 to 4 carbon atoms; (b) a radical ##STR21## wherein R 3 has the same meaning specified hereinbefore and B is an alkylene radical having 2 to 12 carbon atoms or a cyclo-alkylene radical having 3 to 12 carbon atoms; (c) a radical ##STR22## wherein: each of R 9 , R 10 , R 11 , R 12 , R 13 , R 14 , R 15 and R 16 , which may be the same or different, is hydrogen or an alkyl radical having 1 to 4 carbon atoms, or two by two belong to an aliphatic or aromatic cycle having 5 to 12 carbon atoms; m is an integer from 1 to 12 and n is an integer from 2 to 100.

Claim 6

Compositions according to claim 3, in which the polyester having general formula (I) is present in an amount ranging from 0.01 to 5% on the weight of the polymer.

Claim 7

Compositions according to claim 3, in which the thermoplastic synthetic polymer is a polyolefin.

Claim 8

Compositions according to claim 5, in which the polyolefin is polypropylene consisting prevailingly of isotactic macromolecules.

Claim 9

Compositions according to claim 5, in which the polyester having general formula (I) is present in an amount ranging from 0.01 to 2% by weight on the weight of the polyolefin.

Claim 10

Compositions according to the preceding claim 3, in which the thermoplastic synthetic polymer is polyvinyl chloride or polyvinylidene chloride.

Claim 11

Compositions according to claim 8, in which the polyester having general formula (I) is present in an amount ranging from 0.01 to 1% by weight on the weight of the polymer.

Claim 12

Compositions according to the preceding claim 3, in which the thermoplastic synthetic polymer is a polyurethane or a polyamide.

Claim 13

Compositions according to claim 10, in which the polyester having general formula (I) is present in an amount ranging from 0.01 to 5% by weight on the weight of the polymer.

Claim 14

Compositions according to claim 3, in which the polyester having general formula (I) is employed in admixture with at least one adjuvant.

Claim 15

Compositions according to claim 12, in which the adjuvants are selected from the group consisting of antioxidants, ultraviolet ray absorbers, pigments, fillers, basic nitrogen containing polycondensates and auxiliary stabilizers.

Claim 16

Compositions according to claim 12, in which the ratio by weight of adjuvant or adjuvants to the polyester having general formula (I) is from 0.5:1 to 3:1.