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US4358392A Expired / Lapsed US ⏱️ 0.0 years remaining

Liquid crystal-base composition for an electro-optical device

Assignee: Asulab AG
•
Filing: 1981-02-24
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Granted: 1982-11-09
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Expires: 2001-02-24
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Abstract

Abstract The liquid crystal-base composition for an electro-optical device contains an anthraquinone pleochroic coloring agent of formula (I) as defined in claim 1, that is to say, with in particular at least one hydroxy or amino group in position 1 and a heterocyclic side chain which is directly substituted in position 2, or 2 and 6, or 3, or 3 and 7. The compounds (I) have a high order parameter and are stable, thereby imparting to the compositions the properties required for use thereof for example in a display device. ##STR1##

Inventors

  • 👤 Jacques Cognard
  • 👤 Trung H. Phan

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 12:37
CPC Classifications
C; C09; C09K; C09K19/00; C09K19/52; C09K19/60; C09K19/603; C09B; C09B1/00; C09B1/16; C09B1/20; C09B1/50; C09B1/54

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 250 words
A liquid crystal guest-host composition containing a liquid crystalline host and a guest pleochroic colouring agent for use in an electro-optical device, wherein said colouring agent is an anthraquinone compound represented by the general formula (I): ##STR14## in which R 1 is an amino group which can be alkylated or acylated, an alkoxy group or a hydroxy group; R 2 , R 3 and R 4 which are identical or different are each a hydrogen atom, an amino group which can be alkylated or acylated, a substituted or unsubstituted an alkoxy group, a hydroxy group, a nitro group, a halogen atom or a cyano group; A is selected from the group consisting of ##STR15## in which X is a hydrogen atom, a halogen atom, a mercaptan group, a cyano group, a cyclic, branched or straight alkyl chain, an alkoxyalkyl chain, a hydroxyalkyl chain, a pyridyl group, a benzyl group, a phenyl group, a para-alkylphenylene group, a para-alkoxyphenylene group, a para-cyanophenylene group, with at most 10 C atoms, or a group selected from OR', SR', OOCR', OOC--C 6 H 4 --R', SOC--C 6 H 4 --R', NHR', NHCOR', OCOOR' and OCOO--C 6 H 4 --R', in which R' is a hydrogen atom, a cyclic, branched or straight alkyl chain, an ethoxycarbonylalkyl chain, a cyanoalkyl chain or a phenyl group, with at most 10 C atoms, and n is an integer of from 3 to 7, and Y is a hydrogen atom or a side chain having the same definition as A.
Claim 2
Dependent Claim 250 words
A liquid crystal guest-host composition containing a liquid crystalline host and a guest pleochroic colouring agent for use in an electro-optical device, wherein said colouring agent is an anthraquinone compound represented by the general formula (I): ##STR14## in which R 1 is an amino group which can be alkylated or acylated, an alkoxy group or a hydroxy group; R 2 , R 3 and R 4 which are identical or different are each a hydrogen atom, an amino group which can be alkylated or acylated, a substituted or unsubstituted an alkoxy group, a hydroxy group, a nitro group, a halogen atom or a cyano group; A is selected from the group consisting of ##STR15## in which X is a hydrogen atom, a halogen atom, a mercaptan group, a cyano group, a cyclic, branched or straight alkyl chain, an alkoxyalkyl chain, a hydroxyalkyl chain, a pyridyl group, a benzyl group, a phenyl group, a para-alkylphenylene group, a para-alkoxyphenylene group, a para-cyanophenylene group, with at most 10 C atoms, or a group selected from OR', SR', OOCR', OOC--C 6 H 4 --R', SOC--C 6 H 4 --R', NHR', NHCOR', OCOOR' and OCOO--C 6 H 4 --R', in which R' is a hydrogen atom, a cyclic, branched or straight alkyl chain, an ethoxycarbonylalkyl chain, a cyanoalkyl chain or a phenyl group, with at most 10 C atoms, and n is an integer of from 3 to 7, and Y is a hydrogen atom or a side chain having the same definition as A.
Claim 3
Dependent Claim 34 words
A composition according to claim 1 wherein Y is in position 6 of the anthraquinone ring when A is substituted in position 2 and in position 7 when A is substituted in position 3.
Claim 4
Dependent Claim 43 words
A composition according to claim 1 wherein the anthraquinone base structure which is substituted in position 2 or 2 and 6 or 3 or 3 and 7 is selected from the group comprising 1-aminoanthraquinone, 1,4-diaminoanthraquinone, 1,5-diaminoanthraquinone, 1-amino-4-hydroxyanthraquinone, 1,8-diamino-4,5-dihydroxy-anthraquinone, 1,4-diamino-5-nitroanthraquinone, 1,4,5,8-tetraminoanthraquinone, 1,5-diamino-4,8-dihydroxyanthraquinone and 1-amino-4-nitroanthraquinone.
Claim 5
Dependent Claim 16 words
A composition according to claim 1 wherein the colouring agent is represented by the formula ##STR16##
Claim 6
Dependent Claim 16 words
A composition according to claim 1 wherein the colouring agent is represented by the formula: ##STR17##
Claim 7
Dependent Claim 18 words
A composition according to claim 1 comprising one or more nematic liquid crystals of positive or negative anisotropy.
Claim 8
Dependent Claim 19 words
A composition according to claim 6 comprising an optically active agent inducing a cholesteric structure and/or an alignment agent.
Claim 9
Dependent Claim 22 words
A composition according to claim 1 containing a solution of from 0.5 to 5% of an anthraquinone colouring agent of formula (I).
Claim 10
Dependent Claim 35 words
A composition according to claim 1 comprising about 1.5% of an anthraquinone colouring agent of formula (I), about 3% of an optically active agent inducing a cholesteric structure and about 2% of an alignment agent.
Claim 11
Dependent Claim 17 words
A composition according to claim 1 comprising at least one other anthraquinone colouring agent of formula (I).
Claim 12
Dependent Claim 21 words
A composition according to claim 1 comprising at least one other anthraquinone colouring agent different from those represented by formula (I).

References Cited (Backward Citations)

US4288147A Cited
GB2037803A Cited
US4299720A Cited
US4273929A Cited
US4232950A Cited
DE3009974A1 Cited
US4304683A Cited
EP0026004A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-11-08 1986-05-10 1986-11-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-11-08 1990-05-10 1990-11-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-11-08 1994-05-10 1994-11-09 $7700.00 Window Closed / Lapsed

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