Electro-optical composition of the guest-host type

Claim 2

An electro-optical composition comprising a host liquid crystal admixed with a linear, noncondensed aromatic guest dichroic dye of the formula: ##STR13## where Ar 1 and Ar 2 can be the same or a different mono or polycyclic aromatic radical selected from: ##STR14## or (j) combinations of two or more of (a)-(i) joined together in a linear, noncondensed structure, with the proviso that when Ar 1 or Ar 2 comprise only one of (a)-(i), the radical is joined to the quinonoid ring at a 1 (para) type ring position in the case of (a) and at a 2 type ring position in the case of (b)-(i) and that when Ar 1 or Ar 2 comprise the combination of two or more of (a)-(i), radical (a) is linked to adjacent radicals at 1,4 type ring positions, radicals (b), (c), (d) and (e) are linked to adjacent radicals at 2,5 type ring positions and radicals (f) through (i), when present, are terminal radicals at the end of the dye molecule and are linked to adjacent (a), (b), (c), (d), or (e) radicals at a 2 ring position, and with the further proviso that the terminal radical of the dye molecule may include a generally linear, nonionic substituent at a 4 type terminal ring position in the case of (a), at a 5 type terminal ring position in the case of (b), (c), (d) and (e), at a 4 or 5 terminal ring positions in the case of (f) and (g) and at 5 or 6 terminal ring positions in the case of (h) and (i) and where X is a monovalent blocking substituent which is not fused to the adjacent aromatic radical so as to ensure the linear, noncondensed molecular structure.

Claim 3

The composition of claim 1 wherein the aromatic radicals AR 1 or Ar 2 can also include: ##STR15## where X is defined in said claim, when the radical is joined to a 3,6 substituent quinonoid ring at a 1(para) type ring position in the case of (a1), at 1 and 4 type ring positions in the case of (b1) and at a 2 ring position in the case of (c1)-(e1).

Claim 4

The composition of claim 1 wherein X can be H, Cl, Br, F, alkyl, alkoxy or acyloxy.

Claim 5

The composition of claim 1 wherein the generally linear substituent can be alkyl, alkoxy, alkylamino, alkylsulfono, 4-alkylpiperidyl, 4-(trans-4-alkylcyclohexyl) piperidyl or nitro.

Claim 6

An electro-optical composition comprising a host liquid crystal admixed with a linear, noncondensed aromatic guest dichroic dye of the formula: ##STR16## were Ar 1 and Ar 2 can be the same or different mono or polycylic aromatic radical selected from: ##STR17## or (i) combinations of two or more of (a)-(h) joined together in a linear, noncondensed structure, with the proviso that when Ar 1 or Ar 2 comprise only one of (a)-(h), the radical is joined to the quinonoid ring at a 1(para) type ring position in the case of (a) and at 2 ring position in the of (b)-(h) and that when Ar 1 or Ar 2 comprise the combination of two or more of (a)-(h), radical (a) is linked to adjacent radicals at 1,4 type ring positions, radicals (b), (c) and (d) at 2,5 type ring positions and radicals (e)-(h), when present, are terminal radicals at the end of the dye molecule and are linked to adjacent (a), (b), (c) or (d) radicals at a 2 ring position, and with the further proviso that the terminal radical of the dye molecule may include a generally linear, nonionic substituent at a 4-type terminal ring position in the case of (a), at a 5-type terminal ring position in the case of (b), (c) and (d), at the 4 or 5 terminal ring position in the case of (e) and (f) and at the 5 or 6 terminal ring position in the case of (g) and (h), and where X is a monovalent blocking substituent which is not fused to the adjacent aromatic radical so as to ensure the linear, noncondensed, molecular structure.

Claim 7

An electro-optical composition comprising a host liquid crystal admixed with a linear, noncondensed aromatic guest dichroic dye of the formula: ##STR16## were Ar 1 and Ar 2 can be the same or different mono or polycylic aromatic radical selected from: ##STR17## or (i) combinations of two or more of (a)-(h) joined together in a linear, noncondensed structure, with the proviso that when Ar 1 or Ar 2 comprise only one of (a)-(h), the radical is joined to the quinonoid ring at a 1(para) type ring position in the case of (a) and at 2 ring position in the of (b)-(h) and that when Ar 1 or Ar 2 comprise the combination of two or more of (a)-(h), radical (a) is linked to adjacent radicals at 1,4 type ring positions, radicals (b), (c) and (d) at 2,5 type ring positions and radicals (e)-(h), when present, are terminal radicals at the end of the dye molecule and are linked to adjacent (a), (b), (c) or (d) radicals at a 2 ring position, and with the further proviso that the terminal radical of the dye molecule may include a generally linear, nonionic substituent at a 4-type terminal ring position in the case of (a), at a 5-type terminal ring position in the case of (b), (c) and (d), at the 4 or 5 terminal ring position in the case of (e) and (f) and at the 5 or 6 terminal ring position in the case of (g) and (h), and where X is a monovalent blocking substituent which is not fused to the adjacent aromatic radical so as to ensure the linear, noncondensed, molecular structure.

Claim 8

The composition of claim 5 wherein the aromatic radicals can also include: ##STR18## where X is as defined in said claim, when the radical is joined to a 3,6 substituted quinonoid ring at a 1 ring position in the case of (a1), at 1 and 4 ring positions in the case of (b1) and at a 2 ring position in the case of (c1)-(d1).

Claim 9

The composition of claim 5 wherein X can be H, Cl, Br, F, alkyl, alkoxy or acyloxy.

Claim 10

The composition of claim 5 wherein the generally linear substituent can be from alkyl, alkoxy, alkyl amino, alkylsulfono, 4-alkylpiperidyl, 4-(trans-4-alkylcyclohexyl)piperidyl or nitro.

Claim 11

An electro-optical composition comprising a host liquid crystal admixed with a linear, noncondensed aromatic guest dichroic dye of the formula: ##STR19## where Ar 1 and Ar 2 can be the same or a different mono or polycyclic aromatic radical selected from: ##STR20## or (i) combinations of two or more (a)-(h) joined together in a linear, noncondensed structure, with the proviso that when Ar 1 or Ar 2 comprise only one of (a)-(h), the radical is joined to the quinonoid ring at a 1 (para) type ring position in the case of (a) and at a 2 ring position in the case of (b)-(h) and that when Ar 1 or Ar 2 comprise the combination of two or more of (a)-(h), radical (a) is linked to adjacent radicals at 1, 4 type ring positions, radicals (b), (c) or (d) at 2, 5 type ring positions and radicals (e)-(h), when present, are terminal radicals at the end of the dye molecule and are linked to adjacent (a), (b), (c) or (d) radicals at a 2 ring position, and with the further proviso that the terminal radical of the dye molecule may include a generally linear, nonionic substituent at a 4 type terminal ring position in the case of (a), at a 5 type terminal position in the case of (b), (c) or (d) at the 4 or 5 terminal ring positions in the case of (e) and (f) and at the 5 or 6 terminal ring positions in the case of (g) and (h), and where X is monovalent blocking substituent which is not fused to the adjacent aromatic radical so as to ensure that linear, noncondensed molecular structure.

Claim 12

An electro-optical composition comprising a host liquid crystal admixed with a linear, noncondensed aromatic guest dichroic dye of the formula: ##STR19## where Ar 1 and Ar 2 can be the same or a different mono or polycyclic aromatic radical selected from: ##STR20## or (i) combinations of two or more (a)-(h) joined together in a linear, noncondensed structure, with the proviso that when Ar 1 or Ar 2 comprise only one of (a)-(h), the radical is joined to the quinonoid ring at a 1 (para) type ring position in the case of (a) and at a 2 ring position in the case of (b)-(h) and that when Ar 1 or Ar 2 comprise the combination of two or more of (a)-(h), radical (a) is linked to adjacent radicals at 1, 4 type ring positions, radicals (b), (c) or (d) at 2, 5 type ring positions and radicals (e)-(h), when present, are terminal radicals at the end of the dye molecule and are linked to adjacent (a), (b), (c) or (d) radicals at a 2 ring position, and with the further proviso that the terminal radical of the dye molecule may include a generally linear, nonionic substituent at a 4 type terminal ring position in the case of (a), at a 5 type terminal position in the case of (b), (c) or (d) at the 4 or 5 terminal ring positions in the case of (e) and (f) and at the 5 or 6 terminal ring positions in the case of (g) and (h), and where X is monovalent blocking substituent which is not fused to the adjacent aromatic radical so as to ensure that linear, noncondensed molecular structure.

Claim 13

The composition of claim 9 wherein the central benzene ring between the substituted quinonoid rings is: ##STR21## where X is as defined in said claim.

Claim 14

The composition of claim 9 wherein X can be H, Cl, Br, F. alkyl, alkoxy or acyloxy.

Claim 15

The composition of claim 9 wherein the aromatic radicals can also include: ##STR22## where X is as defined in said claims, when the radical is joined to a 3,6 substituted quinonoid ring at a 1 ring position in the case of (a1), at 1 and 4 ring positions in the case of (b1) and a 2 ring position in the case of (c1)-(e1).

Claim 16

The composition of claim 9 wherein the generally linear substituent can be alkyl, alkoxy, alkyl amino, alkylsulfono, 4-alkylpiperidyl, 4-(trans-4-alkylcyclohexyl)piperidyl or nitro.

Claim 17

In an electro-optical display device comprising two spaced transparent substrates whose facing surfaces have been coated with transparent electrodes, the improvement comprising an electro-optical composition disposed between the substrates comprising a host liquid crystal admixed with a linear, non-condensed aromatic guest dichroic dye of the formula: ##STR23## where Ar 1 and Ar 2 can be the same or a different mono or polycyclic aromatic radical selected from: ##STR24## or (j) combinations of two or more of (a)-(i) joined together in a linear, noncondensed structure, with the proviso that when Ar 1 or Ar 2 comprise only one of (a)-(i), the radical is joined to the quinonoid ring at a 1 (para) type ring position in the case of (a) and at a 2 type ring position in the case of (b)-(i) and that when Ar 1 or Ar 2 comprise the combination of two or more of (a)-(i), radical (a) is linked to adjacent radicals at 1, 4 type ring positions, radicals (b), (c), (d) and (e) are linked to adjacent radicals at 2, 5 type ring positions and radicals (f)-(i), when present, are terminal radicals at the end of the dye molecule and are linked to adjacent (a), (b), (c), (d), or (e) radical at a 2 ring position, and with further proviso that the terminal radical of the dye molecule may include a generally linear, nonionic substituent at a 4 type terminal ring position in the case of (a), at a 5 type terminal ring position in the case (b), (c), (d) and (e) at a 4 or 5 terminal ring position in the case (f) and (g) and at 5 or 6 terminal ring position in the case of (h) and (i), and where X is a monovalent blocking substituent which is not fused to the adjacent aromatic radical so as to ensure the linear, noncondensed molecular structure.

Claim 18

In an electro-optical display device comprising two spaced transparent substrates whose facing surfaces have been coated with transparent electrodes, the improvement comprising an electro-optical composition disposed between the substrates comprising a host liquid crystal admixed with a linear, non-condensed aromatic guest dichroic dye of the formula: ##STR23## where Ar 1 and Ar 2 can be the same or a different mono or polycyclic aromatic radical selected from: ##STR24## or (j) combinations of two or more of (a)-(i) joined together in a linear, noncondensed structure, with the proviso that when Ar 1 or Ar 2 comprise only one of (a)-(i), the radical is joined to the quinonoid ring at a 1 (para) type ring position in the case of (a) and at a 2 type ring position in the case of (b)-(i) and that when Ar 1 or Ar 2 comprise the combination of two or more of (a)-(i), radical (a) is linked to adjacent radicals at 1, 4 type ring positions, radicals (b), (c), (d) and (e) are linked to adjacent radicals at 2, 5 type ring positions and radicals (f)-(i), when present, are terminal radicals at the end of the dye molecule and are linked to adjacent (a), (b), (c), (d), or (e) radical at a 2 ring position, and with further proviso that the terminal radical of the dye molecule may include a generally linear, nonionic substituent at a 4 type terminal ring position in the case of (a), at a 5 type terminal ring position in the case (b), (c), (d) and (e) at a 4 or 5 terminal ring position in the case (f) and (g) and at 5 or 6 terminal ring position in the case of (h) and (i), and where X is a monovalent blocking substituent which is not fused to the adjacent aromatic radical so as to ensure the linear, noncondensed molecular structure.

Claim 19

The display of claim 14 wherein the dichroic dye is represented by the chemical formula: ##STR25## where Ar 1 and Ar 2 can be the same or a different mono or polycyclic aromatic radical selected from: ##STR26## or (i) combinations of two or more of (a)-(i) joined together in a linear, noncondensed structure with the proviso that when Ar 1 or Ar 2 comprise only one of (a)-(h), the radical is joined to the quinonoid ring at a 1 (para) type ring position in the case of (a) and at a 2 ring position in the case of (b)-(h) and that when Ar 1 or Ar 2 comprise the combination of two or more of (a)-(h), radical (a) is linked to adjacent radicals at 1,4 type positions, radicals (b), (c) and (d) at 2, 5 type ring positions and radicals (e)-(h), when present, are terminal radicals at the end of the dye molecule and are linked to adjacent (a), (b), (c) or (d) radicals at a 2 ring position, and with the further proviso that the terminal radical of the dye molecule may include a generally linear, nonionic substituent at a 4 type ring position in the case of (a), at a 5 type position in the case of (b), (c) and (d) at the 4 or 5 type terminal position in the case of (e) and (f) and at the 5 or 6 type terminal position in the case of (g) and (h), and where X is a monovalent blocking substituent which is not fused to the adjacent aromatic radical so as to ensure the linear, noncondensed molecular structure.

Claim 20

The display of claim 14 wherein the dichroic dye is represented by the chemical formula: ##STR27## where Ar 1 and Ar 2 can be the same or a different mono or polycyclic aromatic radical selected from: ##STR28## or (i) combinations of two or more of (a)-(h) joined together in a linear, noncondensed structure, with the proviso that when Ar 1 or Ar 2 comprise only one of (a)-(h), the radical is joined to the quinonoid ring at a 1 (para) type ring position in the case of (a) and at a 2 ring position in the case of (b)-(h) and that when Ar 1 or Ar 2 comprise the combination of two or more of (a)-(h), radical (a) is linked to adjacent radicals at 1, 4 type ring positions, radicals (b), (c) and (d) at 2,5 type ring positions and radicals (e)-(h), when present, are terminal radicals at the end of the dye molecule and are linked to adjacent (a), (b), (c) or (d) radicals at a 2 ring position, and with the further proviso that the terminal radical of the dye molecule may include a generally linear, nonionic substituent at a 4 type terminal ring position in the case of (a), at a 5 type terminal position in the case of (b), (c) and (d) at the 4 or 5 type terminal positions in the case of (e) and (f) and at the 5 or 6 type terminal position in the case of (g) and (h), and where X is a monovalent blocking substituent which is not fused to the adjacent aromatic radical so as to ensure the linear, noncondensed molecular structure.