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US4357180A Expired / Lapsed US ⏱️ 0.0 years remaining

Annealing of ion-implanted GaAs and InP semiconductors

Assignee: United States Department of the Navy
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Filing: 1981-01-26
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Granted: 1982-11-02
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Expires: 2001-01-26
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Abstract

Abstract A method of annealing both N and P-type ion-implanted GaAs and InP semiconductors by using a close-contact capping technique. A flat polished ion-implanted surface on a gallium arsenide (GaAs) or indium phosphide (InP) semiconductor is placed in face-to-face contact with a non-reactive flat surface such as Si 3 N 4 , SiO 2 , AlN, or identical semiconductor material, and annealed at selected elevated temperatures and time dependent upon ion concentration. The annealed semiconductor material, usually in the form of a wafer, is allowed to cool to room temperature for further processing.

Inventors

  • 👤 Bela Molnar

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 01:12
CPC Classifications
H; H10; H10P; H10P30/00; H10P30/20; H10P30/202; H10P30/206; H10D; H10D84/00; H10D84/01; H10D84/02; H10D84/05; H10P30/208; H10P95/00; H10P95/90; H10P95/904; Y; Y10; Y10S; Y10S148/00; Y10S148/003; Y10S148/012; Y10S148/015; Y10S148/056; Y10S148/072; Y10S148/084

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 85 words
A process of annealing ion-implanted semiconductor material comprising the steps of: selecting an unannealed semiconductor material having an ion-implanted polished surface; selecting a like semiconductor material having a polished surface larger than that of the first-mentioned surface; positioning the unannealed semiconductor material in surface-to-surface contact with the larger surface which extends beyond the periphery of the smaller surface; maintaining the surfaces in contact; and annealing the ion-implanted semiconductor material substantially in the absence of oxygen whereby evaporation of material from the implanted surface is minimized.
Claim 2
Dependent Claim 85 words
A process of annealing ion-implanted semiconductor material comprising the steps of: selecting an unannealed semiconductor material having an ion-implanted polished surface; selecting a like semiconductor material having a polished surface larger than that of the first-mentioned surface; positioning the unannealed semiconductor material in surface-to-surface contact with the larger surface which extends beyond the periphery of the smaller surface; maintaining the surfaces in contact; and annealing the ion-implanted semiconductor material substantially in the absence of oxygen whereby evaporation of material from the implanted surface is minimized.
Claim 3
Dependent Claim 144 words
A process of annealing an ion-implanted semiconductor material comprising: selecting an unannealed semiconductor material from the group consisting of GaAs and InP having a polished surface implanted with ions selected from the group consisting of Be + , 29Si + and Se + ; selecting a like semiconductor material having a surface area greater than the area of the ion-implanted surface and provided with a coating of dielectric material on the surface selected from the group consisting of Si 3 N 4 , SiO 2 and AlN polished to a smoothness substantially matching that of the first mentioned surface; positioning the surfaces in face-to-face contact with peripherial portions of the larger surface surrounding the, smaller surface; maintaining the surfaces in contact; and annealing the ion-implanted semiconductor material in an atmosphere of nitrogen and hydrogen whereby evaporation of material from the implanted surface is minimized.
Claim 4
Dependent Claim 144 words
A process of annealing an ion-implanted semiconductor material comprising: selecting an unannealed semiconductor material from the group consisting of GaAs and InP having a polished surface implanted with ions selected from the group consisting of Be + , 29Si + and Se + ; selecting a like semiconductor material having a surface area greater than the area of the ion-implanted surface and provided with a coating of dielectric material on the surface selected from the group consisting of Si 3 N 4 , SiO 2 and AlN polished to a smoothness substantially matching that of the first mentioned surface; positioning the surfaces in face-to-face contact with peripherial portions of the larger surface surrounding the, smaller surface; maintaining the surfaces in contact; and annealing the ion-implanted semiconductor material in an atmosphere of nitrogen and hydrogen whereby evaporation of material from the implanted surface is minimized.
Claim 5
Dependent Claim 25 words
The process according to claim 2 comprising a further step of selecting an annealing atmosphere of approximately 15% H 2 and 85% N 2 .
Claim 6
Dependent Claim 30 words
The process according to claim 2 or 3 comprising annealing the ion-implanted semiconductor material at a temperature of about 800°-1000° C. for about 15-20 minutes when the material is GaAs.
Claim 7
Dependent Claim 30 words
The process according to claim 2 or 3 comprising annealing the ion-implanted semiconductor material to a temperature of about 700°-800° C. for about 15-20 minutes when the material is InP.
Claim 8
Dependent Claim 201 words
A process of annealing a wafer of ion-implanted semiconductor material comprising the steps of: selecting an unannealed semiconductor wafer selected from the group consisting of GaAs and InP having a polished planar surface implanted with ions selected from the group consisting of Be + , 29Si + and Se + ; coating a Si matrix with a layer of dielectric material selected from the group consisting of Si 3 N 4 , SiO 2 and AlN; providing a polished planar surface on the dielectric material having an area larger than the area of the planar surface on the semiconductor wafer; positioning the polished surfaces together in face-to-face contact with excess area of the larger planar surface extending beyond the outer periphery of the smaller planar surface; maintaining the surfaces in face-to-face contact; planning the positioned materials into a container; purging the container to have an embient environment gas of approximately 15% H 2 and 85% N 2 ; placing the container in a furnace at an elevated temperature for a predetermined time; removing the container from the furnace and allowing the materials to cool to substantially room temperature; changing the ambient gas to N 2 ; and removing the annealed semiconductor.
Claim 9
Dependent Claim 201 words
A process of annealing a wafer of ion-implanted semiconductor material comprising the steps of: selecting an unannealed semiconductor wafer selected from the group consisting of GaAs and InP having a polished planar surface implanted with ions selected from the group consisting of Be + , 29Si + and Se + ; coating a Si matrix with a layer of dielectric material selected from the group consisting of Si 3 N 4 , SiO 2 and AlN; providing a polished planar surface on the dielectric material having an area larger than the area of the planar surface on the semiconductor wafer; positioning the polished surfaces together in face-to-face contact with excess area of the larger planar surface extending beyond the outer periphery of the smaller planar surface; maintaining the surfaces in face-to-face contact; planning the positioned materials into a container; purging the container to have an embient environment gas of approximately 15% H 2 and 85% N 2 ; placing the container in a furnace at an elevated temperature for a predetermined time; removing the container from the furnace and allowing the materials to cool to substantially room temperature; changing the ambient gas to N 2 ; and removing the annealed semiconductor.
Claim 10
Dependent Claim 26 words
The process according to claim 6 comprising the step of maintaining a GaAs ion-implanted semiconductor wafer at a temperature of 800°-1000° C. for about 15-20 minutes.
Claim 11
Dependent Claim 26 words
The process according to claim 6 comprising the step of maintaining an InP ion-implanted semiconductor wafer at a temperature of 700°-800° C. for about 15-20 minutes.

References Cited (Backward Citations)

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US3737282A Cited
US3720515A Cited
US3762945A Cited
US3984263A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-11-01 1986-05-03 1986-11-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-11-01 1990-05-03 1990-11-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-11-01 1994-05-03 1994-11-02 $7700.00 Window Closed / Lapsed

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