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Norbornene polymers containing bound phenolic antioxidant

Assignee: Goodrich Corp
•
Filing: 1980-09-18
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Granted: 1982-10-19
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Expires: 2000-09-18
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Abstract

Abstract A polymeric composition of matter formed by ring opening polymerization using a metathesis catalyst comprising bound antioxidant which is a reaction product of a norbornene-type monomer and a norbornenyl phenolic antioxidant.

Inventors

  • 👤 Robert W. Layer
  • 👤 Linwood P. Tenney

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 11:57
CPC Classifications
C; C08; C08L; C08L65/00; C08G; C08G61/00; C08G61/02; C08G61/04; C08G61/06; C08G61/08

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 161 words
A polymeric composition of matter comprising a reaction product obtained by ring opening polymerization using a metathesis catalyst of a norbornene-type monomer and 0.05 to 10 parts by weight per 100 parts of said norbornene-type monomers of a norbornenyl phenolic antioxidant defined as follows: ##STR6## where R 1 , R 2 , and R 3 are individually selected from hydrogen and alkyl groups of 1 and 3 carbon atoms; R 4 is selected from hydrogen, alkyl groups containing 1 to 12 carbon atoms, and alicyclic groups of 4 to 8 carbon atoms; R 5 is selected from alkyl groups of 1 to 6 carbon atoms, and alicyclic groups of 4 to 8 carbon atoms; R 6 is selcted from alkylene and alkenylene groups containing 1 to 8 carbon atoms; and R 7 is selected from hydrogen, alkyl and alkenyl groups of 1 to 8 carbon atoms, amount of said norbornenyl phenolic being sufficient to improve antioxidant properties of said reaction product.
Claim 2
Dependent Claim 161 words
A polymeric composition of matter comprising a reaction product obtained by ring opening polymerization using a metathesis catalyst of a norbornene-type monomer and 0.05 to 10 parts by weight per 100 parts of said norbornene-type monomers of a norbornenyl phenolic antioxidant defined as follows: ##STR6## where R 1 , R 2 , and R 3 are individually selected from hydrogen and alkyl groups of 1 and 3 carbon atoms; R 4 is selected from hydrogen, alkyl groups containing 1 to 12 carbon atoms, and alicyclic groups of 4 to 8 carbon atoms; R 5 is selected from alkyl groups of 1 to 6 carbon atoms, and alicyclic groups of 4 to 8 carbon atoms; R 6 is selcted from alkylene and alkenylene groups containing 1 to 8 carbon atoms; and R 7 is selected from hydrogen, alkyl and alkenyl groups of 1 to 8 carbon atoms, amount of said norbornenyl phenolic being sufficient to improve antioxidant properties of said reaction product.
Claim 3
Dependent Claim 76 words
Composition of claim 1 wherein R 1 , R 2 and R 3 are individually selected from hydrogen and methyl groups, R 4 is selected from alkyl groups of 1 to 6 carbon atoms, R 5 is selected from alkyl groups of 1 to 6 carbon atoms, R 6 is selected from alkylene and alkenylene groups of 1 to 4 carbon atoms, and R 7 is selected from alkyl groups of 1 to 4 carbon atoms.
Claim 4
Dependent Claim 25 words
Composition of claim 2 wherein said norbornene type monomers are selected from norbornenes, dicyclopentadienes, dihydrodicyclopentadienes, tetracyclododecenes and symmetrical and unsymmetrical trimers and tetramers of cyclopentadiene.
Claim 5
Dependent Claim 27 words
Composition of claim 3 wherein said norbornene-type monomers are selected from substituted and unsubstituted monomers, wherein said substituents are selected from ester, nitrile, phenyl, and halogen groups.
Claim 6
Dependent Claim 17 words
Composition of claim 2 wherein R 4 is in the open ortho position to the hydroxyl group.

References Cited (Backward Citations)

US4017669A Cited
US3974092A Cited
US3962187A Cited
US4022954A Cited
US4010140A Cited
US4129557A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-10-18 1986-04-19 1986-10-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-10-18 1990-04-19 1990-10-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-10-18 1994-04-19 1994-10-19 $7700.00 Window Closed / Lapsed

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