US4010140A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Age resistant resin compositions and admixtures useful as adhesives
Assignee: Goodyear Tire and Rubber Co
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Filing: 1974-10-02
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Granted: 1977-03-01
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Expires: 1994-10-02
Abstract
Abstract Age resistant resin which comprises a composition selected from (A) a composition having a softening point in the range of 0° C to about 140° C comprising units derived from selected aliphatic diolefins and aliphatic monoolefins, which can be modified with units derived from dicyclopentadiene, and certain vinyl aromatic compounds, and selected phenol or amine type compounds and (B) a composition having a softening point in the range of about 60° C to about 110° C comprising units derived from monoolefins and vinyl aromatic compounds, which can be modified with aliphatic diolefins, and selected phenol and amine type compounds. Such age resistant resins have particular utility when admixed with various rubbery materials and thermoplastics to create pressure sensitive adhesives and hot melt adhesives.
Inventors
- 👤 Herbert L. Bullard
- 👤 Robert A. Osborn
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 01:50
CPC Classifications
C; C08; C08L; C08L19/00; C08L19/006; C08F; C08F210/00
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
188 words
An age resistant tackifying resin which comprises a composition having a softening point in the range of 0° C. to about 140° C. comprising (1) about 40 to about 80 weight percent units derived from aliphatic diolefins selected from piperylene, 1,3-butadiene and 2,3-dimethyl-1,3-butadiene, (2) about 60 to about 20 weight percent units derived from aliphatic monoolefins selected from isobutylene, 2-methyl-1-butene, 2-methyl-2-butene, 2,3-dimethyl-1-butene, 2,3-dimethyl-2-butene, 2-methyl-1-pentene, and 2-methyl-2-pentene, where the mole ratio of diolefin to monoolefin is about 0.7/1 to about 2:1, (3) about 0 to about 40 weight percent units derived from at least one of dicyclopentadiene and a vinyl aromatic compound selected from styrene and α-methyl styrene and (4) about 0.2 to about 2 weight percent units derived from at least one selected amine type compound, where said amine compounds are selected from an amine compound having the structure ##STR9##where R 14 is selected from hydrogen, methyl, ethyl and methoxy radicals, where X 2 is selected from the groups consisting of --NH, --N--CH(CH 3 )--CH 2 --CH 2 --CH 3 , and oxygen and where Y 2 is selected from the group consisting of --COCH=CH 2 , ##STR10##
Claim 2
Dependent Claim
188 words
An age resistant tackifying resin which comprises a composition having a softening point in the range of 0° C. to about 140° C. comprising (1) about 40 to about 80 weight percent units derived from aliphatic diolefins selected from piperylene, 1,3-butadiene and 2,3-dimethyl-1,3-butadiene, (2) about 60 to about 20 weight percent units derived from aliphatic monoolefins selected from isobutylene, 2-methyl-1-butene, 2-methyl-2-butene, 2,3-dimethyl-1-butene, 2,3-dimethyl-2-butene, 2-methyl-1-pentene, and 2-methyl-2-pentene, where the mole ratio of diolefin to monoolefin is about 0.7/1 to about 2:1, (3) about 0 to about 40 weight percent units derived from at least one of dicyclopentadiene and a vinyl aromatic compound selected from styrene and α-methyl styrene and (4) about 0.2 to about 2 weight percent units derived from at least one selected amine type compound, where said amine compounds are selected from an amine compound having the structure ##STR9##where R 14 is selected from hydrogen, methyl, ethyl and methoxy radicals, where X 2 is selected from the groups consisting of --NH, --N--CH(CH 3 )--CH 2 --CH 2 --CH 3 , and oxygen and where Y 2 is selected from the group consisting of --COCH=CH 2 , ##STR10##
Claim 3
Dependent Claim
24 words
The age resistant composition of claim 1 where said aliphatic diolefin is piperylene and where said monoolefin is primarily selected from 2-methyl-1-butene and 2-methyl-2-butene.
Claim 4
Dependent Claim
83 words
The age resistant composition of claim 1 having a softening point in the range of about 80° C to about 110° C which comprises about 40 to about 80 weight percent units derived from piperylene, about 60 to about 20 weight percent units derived from monoolefins selected primarily from 2-methyl-1-butene and 2-methyl-2-butene and about 0.2 to about 2 weight percent units derived from at least one of said selected amine type compounds, when such materials are polymerized in the presence of aluminum chloride.
Claim 5
Dependent Claim
86 words
The age resistant resin composition of claim 1 having a softening point in the range of about 0° C to about 30° C which comprises about 40 to about 80 weight percent units derived from piperylene, about 60 to about 20 weight percent units derived from monoolefins selected from 2-methyl-1-butene and 2-methyl-2-butene and about 0.2 to about 2 weight percent units derived from at least one of said amine type compounds, when such materials are polymerized in the presence of boron trifluoride or boron trifluoride etherate.
Claim 6
Dependent Claim
52 words
An age resistant resin composition according to claim 3 having a softening point in the range of about 70° C to about 110° C prepared by polymerizing said materials after the addition of up to about 20 weight percent of at least one vinyl aromatic compound selected from styrene and α-methyl styrene.
Claim 7
Dependent Claim
47 words
The age resistant resin of claim 1 where said amine compounds are selected from N-(4-anilino phenyl)acrylamide N-(4-anilino phenyl)methacrylamide N-(4-anilino phenyl)crotonamide N-(4-anilino phenyl)cinnamamide N-(4-toluidino phenyl)acrylamide N-(4-toluidino phenyl)methacrylamide N-(4-toluidino phenyl)crotonamide N-(4-toluidino phenyl)cinnamamide N-[4-(p-methoxy)anilinophenyl]acrylamide N-[4-(p-methoxy)anilinophenyl]methacrylamide N-[4-(p-methoxy)anilinophenyl]crotonamide N-[4-(p-methoxy)anilinophenyl]cinnamamide 4-anilinophenyl acrylate 4-anilinophenyl methacrylate 4-anilinophenyl crotonate 4-anilinophenyl cinnamate N-(4-anilinoanilinomethyl)maleimide N-(4-anilinoanilinomethyl)acrylamide and N-(4-anilinophenyl)maleamic acid.
References Cited (Backward Citations)
US3441545A
Cited
US3658769A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-02-29 | 1980-08-30 | 1981-03-01 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-02-29 | 1984-08-30 | 1985-03-01 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-02-29 | 1988-08-30 | 1989-03-01 | $7700.00 | Window Closed / Lapsed |